A computer implemented method for automatic peak integration of at least one chromatogram of at least one sample. The method comprises retrieving at least one chromatogram of the chemical related substance and at least one chromatogram of the analyte; evaluating the chromatogram of the chemical related substance, wherein the evaluating comprises determining at least one initial value for analyte retention time by determining retention time of the chemical related substance and adding the retention time of the chemical related substance with a pre-determined or pre-defined constant offset and/or multiplying the retention time of the chemical related substance with a pre-determined or pre-defined constant factor; evaluating the chromatogram of the analyte, wherein the evaluating comprises at least one position determining step; and at least one peak integration step, wherein analyte peak area and analyte peak shape are determined by applying at least one fitting analysis to the chromatogram of the analyte.

A conductive composition comprising a conductive polymer (A) having an acidic group, and a basic compound (B), wherein: an area ratio (X/Y) is 0.046 or less as calculated by an specific method, which is a ratio an area (X) of a region corresponding to molecular weight (M) ranging from 300 to 3300, relative to an area (Y) of an entire region ascribed to the conductive polymer (A); or a ratio, ZS/ZR, is 20 or less, wherein the ZS is a maximum value of fluorescence intensity in a wavelength region of 320 to 420 nm when a fluorescence spectrum is measured using a spectrofluorometer at an excitation wavelength of 230 nm with respect to a measurement solution obtained by diluting the conductive composition with water so as to adjust solids content of the conductive polymer (A) to 0.6% by mass, and the ZR is a maximum value of Raman scattering intensity in a wavelength region of 380 to 420 nm when a fluorescence spectrum of water is measured using a spectrofluorometer at an excitation wavelength of 350 nm.

Wavelength spectrums of peaks detected on a chromatogram based on observation data to be processed are extracted to create a spectrum set {S.sub.n} in which the intensity values of the spectrums are normalized (S10, S11). One wavelength spectrum is selected from the set, and a vector of the wavelength spectrum at each point in time of measurement based on the observation data is projected so as to be perpendicular to the vector of the selected spectrum (S12 to S14). The vectors of the wavelength spectrums in the set {S.sub.n } are also similarly projected (S15). Consequently, the selected spectrum is erased from the set {S.sub.n}. The processes from S12 to S16 are repeated until the set {S.sub.n } does not include a spectrum, and the obtained signals are added (S17). The signal resulting from the addition is a signal indicating the waveform shape of an unknown baseline. A baseline spectrum is obtained by fitting the signal to a chromatogram at each wavelength obtained from the observation data, and a baseline signal at each wavelength is calculated from the baseline spectrum and the baseline chromatogram. As a result, a baseline can be automatically estimated without setting of a parameter and the like by a user.

An embodiment of a method for real time material identification is described that comprises determining an approximate mass value for an unknown material from spectral information derived from mass spectral analysis of the unknown material; retrieving profile models that correspond to a known material from a data structure using the approximate mass value; fitting a sample profile for the unknown material from the spectral information to the profile models to generate a fit score for each fit, wherein the lowest fit score corresponds to the best fit; calculating a mass value from the best fitting profile model and the sample profile.

Wavelength spectrums of peaks detected on a chromatogram based on observation data to be processed are extracted to create a spectrum set in which the intensity values of the spectrums are normalized. One wavelength spectrum is selected from the set, and a vector of the wavelength spectrum at each point in time of measurement based on the observation data is projected so as to be perpendicular to the vector of the selected spectrum. The vectors of the wavelength spectrums in the set are also similarly projected. Consequently, the selected spectrum is erased from the set. The processes are repeated until the set does not include a spectrum, and the obtained signals are added. The signal resulting from the addition is a signal indicating the waveform shape of an unknown baseline.

An embodiment of a method for real time material identification is described that comprises determining an approximate mass value for an unknown material from spectral information derived from mass spectral analysis of the unknown material; retrieving profile models that correspond to a known material from a data structure using the approximate mass value; fitting a sample profile for the unknown material from the spectral information to the profile models to generate a fit score for each fit, wherein the lowest fit score corresponds to the best fit; calculating a mass value from the best fitting profile model and the sample profile.

A conductive composition may include a conductive polymer (A) having an acidic group, and a basic compound (B), wherein: an X/Y area ratio is 0.046 or less, which is a ratio an area (X) of a region corresponding to molecular weight (M) ranging from 300 to 3300, relative to an area (Y) of an entire region ascribed to the conductive polymer (A); or a ZS/ZR ratio is 20 or less. ZS is a maximum fluorescent intensity value in a range of 320 to 420 nm when a fluorescence spectrum is measured at 230 nm excitation wavelength in a solution obtained by diluting the conductive composition with water to adjust the conductive polymer (A) solids content to 0.6 wt. %. ZR is a maximum Raman scattering intensity value in a range of 380 to 420 nm when a fluorescence spectrum of water is measured at 350 nm excitation wavelength.