Provided is an optically anisotropic layer with which an image display device having suppressed occurrence of oblique light leakage can be manufactured; and an optical film, a polarizing plate, and an image display device, each having the optically anisotropic layer. The optically anisotropic layer is obtained by curing a polymerizable liquid crystal composition including a predetermined rod-like liquid crystal compound and a predetermined monofunctional compound, and immobilizing an alignment state of the rod-like liquid crystal compound, in which a number a1 of atoms of the rod-like liquid crystal compound and a number a2 of atoms of the monofunctional compound satisfy a relationship of Expression (1): 0.2<a2/a1≤0.68, and the rod-like liquid crystal compound is immobilized in a state of being vertically aligned with respect to the main surface of the optically anisotropic layer.

An electrically controlled birefringence liquid crystal display device performs a normally black display. The display device includes a liquid crystal display panel including a liquid crystal layer and a reflective portion to reflect light that is incident through a display surface of the liquid crystal display panel and that passes through the liquid crystal layer, a first polarizing plate on the display surface, and a half-wavelength plate between the liquid crystal display panel and the first polarizing plate. A phase difference Δnd−1 of the liquid crystal layer is less than a half of a phase difference Δnd−2 of the half-wavelength plate. The phase difference Δnd−2 of the half-wavelength plate indicates a positively dispersive wavelength, and a low axis of the half-wavelength plate intersects with an orientation axis of liquid crystal molecules in the liquid crystal layer under no electric field being applied. The liquid crystal layer has a birefringence index Δn indicating a positively dispersive wavelength.

An optical coating has a siloxane polymer and noble metal particles. The coating has an index of refraction that is different for in-plane and out-of-plane. The coating has reverse optical dispersion within the visible wavelength range, and preferably a maximum absorption peak between 400-1000 nm wavelength range is greater than 700 nm. In one example the metal particles are noble metal nanorods having an average particle width of less than 400 nm.

An optical coating has a siloxane polymer and noble metal particles. The coating has an index of refraction that is different for in-plane and out-of-plane. The coating has reverse optical dispersion within the visible wavelength range, and preferably a maximum absorption peak between 400-1000 nm wavelength range is greater than 700 nm. In one example the metal particles are noble metal nanorods having an average particle width of less than 400 nm.

An optical element includes a linear polarizer layer and a transparent optical layer. The linear polarizer layer includes surfaces waviness and the transparent optical layer smooths the surfaces waves of the linear polarizer layer.

A pretilt angle of a liquid crystal molecule on the side of an array substrate is formed such that the liquid crystal molecule goes away from the array substrate in a direction to the left when viewed from a position facing a display surface of a liquid crystal panel. The pretilt angle on the side of a counter substrate is formed such that the liquid crystal molecule goes away from the counter substrate in a direction to the right when viewed from a position facing the display surface. The directions to the left and the right define a direction X corresponding to a horizontal direction of the liquid crystal panel. A direction of a delay phase axis of a biaxial phase difference film is arranged in a position rotated anticlockwise in an angular range from over 0° to 1° from the direction X.

The present invention provides a polymerizable composition containing a specific polymerizable compound and a fluorosurfactant having a specific polyoxyalkylene skeleton and having specific molecular weight. The invention also provides an optically anisotropic body, a retardation film, an antireflective film, and a liquid crystal display device that are produced using the polymerizable composition of the present invention. The present invention is useful because, when an optically anisotropic body is produced by photo-polymerization of the polymerizable composition, three features including the leveling properties of the surface of the optically anisotropic body, offset onto the substrate, and liquid crystal alignment can be improved simultaneously.

The present invention provides a polymerizable composition containing a specific polymerizable compound and a fluorosurfactant having a specific polyoxyalkylene skeleton and having specific molecular weight. The invention also provides an optically anisotropic body, a retardation film, an antireflective film, and a liquid crystal display device that are produced using the polymerizable composition of the present invention. The present invention is useful because, when an optically anisotropic body is produced by photo-polymerization of the polymerizable composition, three features including the leveling properties of the surface of the optically anisotropic body, offset onto the substrate, and liquid crystal alignment can be improved simultaneously.

The polymerizable composition contains: a) a polymerizable compound having one or two or more polymerizable groups and satisfying formula (I):

Re(450 nm)/Re(550 nm)<1.0  (I);

b) at least one photopolymerization initiator selected from the group consisting of alkylphenone-based compounds, acylphosphine oxide-based compounds, and oxime ester-based compounds; and c) a polymerization inhibitor. The present invention also provides an optically anisotropic body, a retardation film, an antireflective film, and a liquid crystal display device that are produced using the polymerizable liquid crystal composition. The polymerizable composition of the present invention is excellent in solubility and has high storage stability, so that no precipitation of crystals etc. occurs. When a film-shaped polymer is produced by polymerizing the above composition, the unevenness of the surface of the coating film is small while the alignment of the liquid crystal is maintained, and high durability is obtained. Therefore, the polymerizable composition is useful.

The polymerizable composition contains: a) a polymerizable compound having one or two or more polymerizable groups and satisfying formula (I):

Re(450 nm)/Re(550 nm)<1.0  (I);

b) at least one photopolymerization initiator selected from the group consisting of alkylphenone-based compounds, acylphosphine oxide-based compounds, and oxime ester-based compounds; and c) a polymerization inhibitor. The present invention also provides an optically anisotropic body, a retardation film, an antireflective film, and a liquid crystal display device that are produced using the polymerizable liquid crystal composition. The polymerizable composition of the present invention is excellent in solubility and has high storage stability, so that no precipitation of crystals etc. occurs. When a film-shaped polymer is produced by polymerizing the above composition, the unevenness of the surface of the coating film is small while the alignment of the liquid crystal is maintained, and high durability is obtained. Therefore, the polymerizable composition is useful.