G03G15/0233

Electroconductive elastic body, electrophotographic member, process cartridge, and electrophotographic image-forming apparatus

An electroconductive elastic body includes: a cross-linked product of a first ionic electro-conductive rubber, a cross-linked product of a second ionic electro-conductive rubber, and at least one of a fatty acid and a fatty acid metal salt; wherein the electroconductive elastic body has a matrix that includes the cross-linked product of the first ionic electro-conductive rubber, and a domain that includes the cross-linked product of the second ionic electro-conductive rubber; the cross-linked product of the second ionic electro-conductive rubber includes a polyether skeleton; an electrical resistance of the domain is lower than an electrical resistance of the matrix; in a waveform separation profile of the elastic body as obtained by a small-angle X-ray scattering method, A2 and A1 satisfy a relationship expressed by the following expression (1):
0.005≤(AC2/AC1)≤0.030  (1).

CONDUCTIVE MEMBER FOR ELECTROPHOTOGRAPHIC APPARATUS

To provide a conductive roll for an electrophotographic apparatus that includes a conductive rubber elastic body layer having a lower hardness and lower settling properties than a conventional conductive rubber elastic body layer.

A conductive roll 10 for an electrophotographic apparatus includes a shaft body 12, and a conductive rubber elastic body layer 14 provided on the outer periphery of the shaft body 12, the conductive rubber elastic body layer 14 containing polar rubber, non-polar rubber, and a dispersing agent, wherein the polar rubber is at least one of nitrile rubber, hydrin rubber, and chloroprene rubber, wherein the non-polar rubber is at least one of isoprene rubber, hydrogenated isoprene rubber, and natural rubber, and wherein the dispersing agent is at least one of a polymer containing a block made of a nitrile rubber component and a block made of an isoprene rubber component, modified natural rubber, and modified isoprene rubber.

CHARGING MEMBER, PROCESS CARTRIDGE, AND IMAGE-FORMING APPARATUS

A charging member includes a support, a conductive elastic layer disposed on the support, and a surface layer disposed on the conductive elastic layer. Domains with current values of 2.5 pA or more have an average size of about 300 nm or less in a binary image created using a current value of 2.5 pA as a threshold from current measured by contacting a conical probe having a tip diameter of 20 nm with an outer surface of the surface layer and applying a voltage of 3 V between the conical probe and the support while moving the conical probe.

ELECTROPHOTOGRAPHIC MEMBER, PROCESS CARTRIDGE, AND ELECTROPHOTOGRAPHIC APPARATUS
20180011418 · 2018-01-11 ·

Provided is an electrophotographic member including an electro-conductive substrate and a surface layer on the substrate. The surface layer contains a urethane resin and a first polymer having a specific nitrogen-containing structure. The urethane resin has a structure derived from a second polymer containing a fluorine atom or a structure derived from a third polymer containing a fluorine atom and a silicon atom. The surface layer contains nitrogen atoms derived from the nitrogen-containing structure at a specific ratio in a region from the outer surface of the surface layer to a depth of 300 nm, and the atomic ratios of nitrogen atoms, fluorine atoms, and silicon atoms in a region from a depth of 100 nm from the outer surface of the surface layer to a depth of 300 nm and a region from the outer surface to a depth of 10 nm have specific relationships.

CHARGING MEMBER, CHARGING DEVICE, IMAGE FORMING APPARATUS, AND PROCESS CARTRIDGE

A charging member of a contact charging system that applies only a direct-current voltage to the charging member includes a conductive substrate, an elastic layer disposed on the conductive substrate, and a surface layer disposed on the elastic layer. When measured by an alternating-current impedance method within a range of 1 MHz to 1 mHz in an environment at a temperature of 28° C. and a humidity of 85%, a resistance component R of an impedance within a range of 1 Hz to 100 Hz is 4.0×10.sup.4Ω or more and 1.0×10.sup.6Ω or less and an impedance Z within a range of 1 Hz to 100 Hz is over 3.6×10.sup.4Ω and 3.5×10.sup.5Ω or less.

CONDUCTIVE ROLLER, TRANSFER DEVICE, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS

A conductive roller includes a support member, an elastic layer disposed on an outer peripheral surface of the support member, and a surface layer disposed on an outer peripheral surface of the elastic layer. The elastic layer includes a cylindrical elastic foam and a conductive covering layer covering an exposed surface of the elastic foam and has a volume resistance value of 10.sup.5Ω or less at an applied voltage of 10 V. The elastic foam has a conductive particle content of 1% by mass or less based on the total mass of the elastic foam.

ELECTROPHOTOGRAPHIC ROLLER, PROCESS CARTRIDGE AND ELECTROPHOTOGRAPHIC IMAGE FORMING APPARATUS

An electrophotographic roller includes: a mandrel and an elastic layer on the mandrel, and having a crown shape in which a diameter decreases from a central position O in a longitudinal direction of the mandrel toward an end portion. When a position of the end portion in the longitudinal direction of the elastic layer is defined as X2, a position between the O and the X2 is defined as Xl, a distance between the O and the X1 is defined as L1, and a distance between the X1 and the X2 is defined as L2, L1=0.6×(L1+L2). When outer diameters of the electrophotographic roller at O, X1 and X2 are defined as Do, DX1 and DX2, respectively, and Z1=(Do−DX1)/2 and Z2=(DX1−DX2)/2 are defined, Z1, Z2, L1 and L2 satisfy (Z2/L2)<1.931×(Z1/L1).

IMAGE FORMING APPARATUS

An image forming apparatus controls the number of rotations of a photosensitive drum based on information related to the use of the photosensitive drum and a suspension time in a rotation operation of rotating the photosensitive drum after a lapse of the suspension time between a first image forming operation of forming an image on a transfer material and a second image forming operation performed after the first image forming operation.

ELECTROPHOTOGRAPHIC ROLLER, PROCESS CARTRIDGE AND ELECTROPHOTOGRAPHIC IMAGE FORMING APPARATUS

An electrophotographic roller includes: a mandrel and an elastic layer on the mandrel, and having a crown shape in which a diameter decreases from a central position O in a longitudinal direction of the mandrel toward an end portion. When a position of the end portion in the longitudinal direction of the elastic layer is defined as X2, a position between the ) and the X2 is defined as X1, a distance between the O and the X1 is defined as L1, and a distance between the X1 and the X2 is defined as L2, L1=0.6×(L1+L2). When outer diameters of the electrophotographic roller at O, X1 and X2 are defined as Do, DX1 and DX2, respectively, and Z1=(Do−DX1)/2 and Z2=(DX1−DX2)/2 are defined, Z1, Z2, L1 and L2 satisfy (Z2/L2)<1.931×(Z1/L1).

Conductive roll, transfer device, process cartridge, and image forming apparatus for image transfer

A conductive roll includes a support member, an elastic layer disposed on an outer peripheral surface of the support member, a surface layer disposed on an outer peripheral surface of the elastic layer, and an intermediate layer disposed between the elastic layer and the surface layer, the intermediate layer having a Poisson ratio of 0.40 or less.