Disclosed herein is a method for manufacturing a fluorinated structured organic film (FSOF) composition for a photoreceptor. The method includes combining a fluorinated diol, an electroactive segment and a solvent in a round bottom reactor. The reacted is heated, without mixing dissolve the fluorinated diol composition. The dissolved fluorinated diol composition is mixed to dissolve the electroactive segment while maintaining the reactor at a temperature of between 80 and 85° C. A catalyst and a leveling agent are added to the solution to initiate a pre-cure reaction. The pre-cure reaction proceeds for at least 2 hours at a temperature of between 80 and 85° C. The solution is cooled to room temperature and filtered.

An electrophotographic photoreceptor includes a conductive substrate and a photosensitive layer on the conductive substrate. The outermost surface layer of the electrophotographic photoreceptor contains fluorine-containing resin particles, a fluorine graft polymer, and an acidic compound having an acid dissociation constant (pKa) of 3 or less in water at 25° C. The amount of the acidic compound relative to the outermost surface layer is 100 ppm or more and 10000 ppm or less.

An electrophotographic photosensitive member, which is suppressed in occurrence of fogging and is excellent in abrasion resistance. In the electrophotographic photosensitive member, an outermost surface layer of the electrophotographic photosensitive member comprises a polymerized product of a composition comprising at least a polyrotaxane and a monomer having a polymerizable reactive group, and a chain molecule of the polyrotaxane has two blocking groups at both terminals thereof, and a (meth)acryloyloxy group of a cyclic molecule of the polyrotaxane forms a bond.

An electrophotographic photosensitive member having a support and a photosensitive layer on the support, wherein the electrophotographic photosensitive member comprises a surface layer comprising a polymerization product of a composition containing polyrotaxane and a charge transporting substance, and the polymerization product including a bond between the polyrotaxane and the charge transporting substance.

An electrophotographic photoreceptor includes a conductive substrate, and a lamination type photosensitive layer disposed on the conductive substrate and including a charge generation layer and a charge transport layer, in which the charge transport layer contains a polyester resin (1) having a dicarboxylic acid unit (A) represented by Formula (A) and a diol unit (B) represented by Formula (B), and a charge transport material, and in a case where a weight-average molecular weight Mw of the polyester resin (1) contained in the charge transport layer is defined as A (10,000), a value of a ratio M1/M2 of a mass M1 of the charge transport material contained in the charge transport layer to a mass M2 of the charge transport layer is defined as Cs, and an average thickness of the charge transport layer is defined as Ds (μm), expressions of 5≤A≤40, 0.28≤Cs≤0.55, 27≤Ds≤50, and 2.5≤(A×Ds)/(Cs×100)≤70.0 are satisfied.

##STR00001##

In Formula (A), n.sup.1 represents 1, 2, or 3, n.sup.1 number of m.sup.1's each independently represent 0, 1, 2, 3, or 4, m.sup.1 number of Ra.sup.1's each independently represent an alkyl group having 1 or more and 10 or less carbon atoms, an aryl group having 6 or more and 12 or less carbon atoms, or an alkoxy group having 1 or more and 6 or less carbon atoms.

In Formula (B), Rb.sup.1 and Rb.sup.2 each independently represent a hydrogen atom, an alkyl group having 1 or more and 20 or less carbon atoms, an aryl group having 6 or more and 12 or less carbon atoms, or an aralkyl group having 7 or more and 20 or less carbon atoms, Rb.sup.3, Rb.sup.4, Rb.sup.5, Rb.sup.6, Rb.sup.7, Rb.sup.8, Rb.sup.9, and Rb.sup.10 each independently represent a hydrogen atom, an alkyl group having 1 or more and 10 or less carbon atoms, an aryl group having 6 or more and 12 or less carbon atoms, an aralkyl group having 7 or more and 20 or less carbon atoms, or an alkoxy group having 1 or more and 6 or less carbon atoms, and Rb.sup.1 and Rb.sup.2 may be bonded to each other to form a cyclic alkyl group.

The present invention provides a satisfactory electrophotographic photosensitive member which satisfies wear resistance and electrical properties and further, with which image defects do not occur, a process for producing an electrophotographic photosensitive member, and an electrophotographic apparatus and a process cartridge each including the electrophotographic photosensitive member. The electrophotographic photosensitive member the surface layer of which contains a copolymer of a polymerizable functional group-containing charge transporting substance and a particular polymerizable compound.

An electrophotographic photosensitive member, in which occurrences of image defects are suppressed, and a method for manufacturing the electrophotographic photosensitive member are provided. In addition, a process cartridge and an electrophotographic apparatus, which include the electrophotographic photosensitive member, are provided. The surface layer of the electrophotographic photosensitive member contains a cured material, and the cured material is a copolymer of a hole transport compound having a chain-polymerizable functional group and a vinyl ester compound containing a long-chain alkyl group.

Provided is an image bearing member for electrophotography, the image bearing member being excellent in abrasion resistance, scratch resistance, and toner releasability, and being capable of preventing the occurrence of image defects due to cleaning failure for a long period. The image bearing member for electrophotography according to the present invention includes a surface layer formed of a polymerization-cured product of a radical polymerizable composition. The radical polymerizable composition contains a radical polymerizable perfluoropolyether compound (radical polymerizable PFPE), and the ratio of the average number of fluorine atoms to the average number of radical polymerizable functional groups in the radical polymerizable PFPE is 2.0 to 20.0.

An electrophotographic photoreceptor includes: a conductive support; and a photosensitive layer which contains an electric charge generating material and an electric charge transport material, wherein a layer configuring a surface of the electrophotographic photoreceptor contains a resin binder, and conductive particles A and B dispersed in the resin binder, the conductive particles A have a single peak and volume resistance ρ1, the conductive particles B have a single peak and volume resistance ρ2, when a particle diameter of the conductive particles A is set to d1, and a particle diameter of the conductive particles B is set to d2, Expression (1) is satisfied, and when the volume resistance of the conductive particles A is set to ρ1, and the volume resistance of the conductive particles B is set to ρ2, Expression (2) is satisfied:

4×d2≦d1≦20×d2  (1)

10×ρ1<ρ2  (2)

An electrophotographic image support includes: a conductive support; a photosensitive layer disposed on the conductive support; and a protective layer disposed on the photosensitive layer, the protective layer being formed of a polymerized cured product of a radically polymerizable composition containing a radically polymerizable monomer and a perfluoropolyether compound having a radically polymerizable functional group, the perfluoropolyether compound having the radically polymerizable functional group being represented by the following formula (1):

[Chemical Formula 1]

(B).sub.l-A-CF.sub.2O(CF.sub.2CF.sub.2O).sub.m(CF.sub.2O).sub.nCF.sub.2-A-(B).sub.l  (1)

wherein A represents a linking group having a molecular weight of 100 or more and 400 or less, B represents a radically polymerizable functional group, l represents an integer of 2 or more, and m and n each represent an integer of 0 or more, wherein m+n≧1.