Disclosed herein is a method for manufacturing a fluorinated structured organic film (FSOF) composition for a photoreceptor. The method includes combining a fluorinated diol, an electroactive segment and a solvent in a round bottom reactor. The reacted is heated, without mixing dissolve the fluorinated diol composition. The dissolved fluorinated diol composition is mixed to dissolve the electroactive segment while maintaining the reactor at a temperature of between 80 and 85° C. A catalyst and a leveling agent are added to the solution to initiate a pre-cure reaction. The pre-cure reaction proceeds for at least 2 hours at a temperature of between 80 and 85° C. The solution is cooled to room temperature and filtered.

An electrophotographic photoreceptor includes a conductive substrate and a photosensitive layer on the conductive substrate. The outermost surface layer of the electrophotographic photoreceptor contains fluorine-containing resin particles, a fluorine graft polymer, and an acidic compound having an acid dissociation constant (pKa) of 3 or less in water at 25° C. The amount of the acidic compound relative to the outermost surface layer is 100 ppm or more and 10000 ppm or less.

An electrophotographic photosensitive member includes a conductive substrate and an at-least-one-layer photosensitive layer including a specific photosensitive layer. The specific photosensitive layer contains a charge generating material, a binder resin, an electron transport material, and a hole transport material. The binder resin includes a polyarylate resin. The polyarylate resin includes repeating units (1), (2), (3), and (4).

##STR00001##

A percentage of the number of repeats of the repeating unit (3) relative to a total number of repeats of the repeating units (1) and (3) is greater than 0% and less than 50%. A percentage of the number of repeats of the repeating unit (4) relative to a total number of repeats of the repeating units (2) and (4) is at least 35% and less than 70%. The electron transport material includes a compound represented by formula (11), (12), (13), (14), (15), (16), or (17):

##STR00002##

An electrophotographic photoreceptor includes a conductive substrate, and a lamination type photosensitive layer disposed on the conductive substrate and including a charge generation layer and a charge transport layer, in which the charge transport layer contains a polyester resin (1) having a dicarboxylic acid unit (A) represented by Formula (A) and a diol unit (B) represented by Formula (B), and a charge transport material, and in a case where a weight-average molecular weight Mw of the polyester resin (1) contained in the charge transport layer is defined as A (10,000), a value of a ratio M1/M2 of a mass M1 of the charge transport material contained in the charge transport layer to a mass M2 of the charge transport layer is defined as Cs, and an average thickness of the charge transport layer is defined as Ds (μm), expressions of 5≤A≤40, 0.28≤Cs≤0.55, 27≤Ds≤50, and 2.5≤(A×Ds)/(Cs×100)≤70.0 are satisfied.

##STR00001##

In Formula (A), n.sup.1 represents 1, 2, or 3, n.sup.1 number of m.sup.1's each independently represent 0, 1, 2, 3, or 4, m.sup.1 number of Ra.sup.1's each independently represent an alkyl group having 1 or more and 10 or less carbon atoms, an aryl group having 6 or more and 12 or less carbon atoms, or an alkoxy group having 1 or more and 6 or less carbon atoms.

In Formula (B), Rb.sup.1 and Rb.sup.2 each independently represent a hydrogen atom, an alkyl group having 1 or more and 20 or less carbon atoms, an aryl group having 6 or more and 12 or less carbon atoms, or an aralkyl group having 7 or more and 20 or less carbon atoms, Rb.sup.3, Rb.sup.4, Rb.sup.5, Rb.sup.6, Rb.sup.7, Rb.sup.8, Rb.sup.9, and Rb.sup.10 each independently represent a hydrogen atom, an alkyl group having 1 or more and 10 or less carbon atoms, an aryl group having 6 or more and 12 or less carbon atoms, an aralkyl group having 7 or more and 20 or less carbon atoms, or an alkoxy group having 1 or more and 6 or less carbon atoms, and Rb.sup.1 and Rb.sup.2 may be bonded to each other to form a cyclic alkyl group.

An electrophotographic photosensitive member, in which occurrences of image defects are suppressed, and a method for manufacturing the electrophotographic photosensitive member are provided. In addition, a process cartridge and an electrophotographic apparatus, which include the electrophotographic photosensitive member, are provided. The surface layer of the electrophotographic photosensitive member contains a cured material, and the cured material is a copolymer of a hole transport compound having a chain-polymerizable functional group and a vinyl ester compound containing a long-chain alkyl group.

The present invention relates to an electrophotographic photoreceptor comprising a conductive support and a photosensitive layer disposed thereover, wherein the photosensitive layer comprises a compound represented by general formula (1) and palladium, the photosensitive layer having a palladium content of 0.01-50 ppm. ##STR00001##

The present disclosure provides an electrophotographic photosensitive member having a surface layer that is excellent in dispersibility of a fluorine atom-containing resin particle and suppresses a potential fluctuation at the time of repeated use. The electrophotographic photosensitive member having the surface layer, wherein the surface layer includes the fluorine atom-containing resin particle, a binder material, and a polymer A having a specific structural unit.

The present disclosure provides an electrophotographic photosensitive member having a surface layer in which an occurrence of the image deletion is suppressed; a process cartridge equipped with the electrophotographic photosensitive member; and an electrophotographic apparatus provided with the process cartridge. An electrophotographic photosensitive member has a surface layer that includes a copolymerized product of a composition including a metal oxide particle having a polymerizable functional group on a surface thereof and a polymerizable compound having a particular structure.

Provided is an electrophotographic photosensitive drum that achieves both of a reduction in torque of the electrophotographic photosensitive drum at the time of its cleaning and an improvement in image transferability. The electrophotographic photosensitive drum includes: a support; and a photosensitive layer arranged on the support, the electrophotographic photosensitive drum having arranged on an outer surface thereof at least two structure groups having different appearance periods, wherein when, out of the two structure groups, a group including structures having a smaller appearance period is defined as a first structure group, and a group including structures having a larger appearance period is defined as a second structure group, a height of the first structure group is lower than a height of the second structure group.

Disclosed is a cylindrical electrophotographic photosensitive member having a region A along an outer surface and a region B along the outer surface. In this electrophotographic photosensitive member, the region A is located on an end side in an axial direction of the electrophotographic photosensitive member relative to the region B, the region A has a specific groove provided on the outer surface of the electrophotographic photosensitive member, an area ratio a1 of the groove is 65% to 100%, the region B has specific concave portions provided on the outer surface of the electrophotographic photosensitive member, and an area ratio a2 of the concave portion is 5% to 65%.