Patent classifications
G03G5/0631
SINGLE-LAYER TYPE ELECTROPHOTOGRAPHIC PHOTORECEPTOR FOR POSITIVE CHARGING, ELECTROPHOTOGRAPHIC PHOTORECEPTOR CARTRIDGE, AND IMAGE FORMING APPARATUS
The present invention relates to a single-layer type electrophotographic photoreceptor for positive charging, comprising: a conductive support; and a photosensitive layer disposed on the conductive support and comprising a binder resin, a charge generation material, a hole transport material and a specific electron transport material within the same layer, wherein the photosensitive layer contains a specific aromatic compound.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
A photosensitive layer of an electrophotographic photosensitive member is a single layer and contains a charge generating material, a hole transport material, a first electron transport material, a second electron transport material, and a binder resin. The binder resin includes a polyarylate resin. The polyarylate resin includes repeating units (1), (2), (3), and (4).
##STR00001##
A percentage of the number of repeats of the repeating unit (3) relative to the total of the number of repeats of the repeating units (1) and the number of repeats of the repeating unit (3) is greater than 0% and less than 20%. The first electron transport material includes a compound represented by formula (A15) or (A16).
##STR00002##
The second electron transport material includes a compound represented by formula (B10), (B11), (B12), (B13), or (B14)
##STR00003##
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
A single-layer photosensitive layer included in an electrophotographic photosensitive member contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The binder resin includes a polyarylate resin. The polyarylate resin includes repeating units represented by formulas (1), (2), (3), and (4).
##STR00001##
The percentage of the number of repeats of the repeating unit represented by formula (3) relative to a total of the number of repeats of the repeating unit represented by formula (1) and the number of repeats of the repeating unit represented by formula (3) is greater than 0% and less than 20%.
Electrophotographic photoconductor, method of manufacturing the same, and electrophotographic device
Provided are an electrophotographic photoconductor being resistant to abrasion even in long-term use, having highly sensitive electric characteristics, being capable of maintaining a high retention rate, and being capable of providing a stable image without filming, a method of manufacturing the same, and an electrophotographic device. The photoconductor includes an electroconductive substrate (1), a charge generation layer (3), and a charge transport layer (4); the charge transport layer contains a hole transport material, a resin binder, an electron transport material, and an inorganic oxide; the charge generation layer contains a charge generation material; the masses of the hole transport material, the resin binder, the electron transport material, and the inorganic oxide in the charge transport layer respectively denoted by a to d satisfy 1.5≤b/a≤5.7, 0.005≤c/a≤0.35, 0.05≤d/a≤0.70, a≥c+d, and c/d≥0.01; the hole transport material contains a compound expressed by formula (A-1); and the charge generation material contains titanyl phthalocyanine having an exothermic peak at 251±5° C., a half-value width of the exothermic peak equal to or less than 15° C., and a heating value equal to or greater than 1.0 mJ/mg when a temperature rise condition is 20° C./min in differential scanning calorimetry, and having an X-ray diffraction peak at 27.2±0.3°. ##STR00001##
PHOTOCONDUCTOR, IMAGE FORMING APPARATUS, AND PROCESS CARTRIDGE
A photoconductor is provided. The photoconductor includes a support, an undercoat layer overlying the support, and a photosensitive layer overlying the undercoat layer. The undercoat layer includes a binder resin and a zinc oxide particle. The photosensitive layer includes a compound represented by the following formula (1):
##STR00001##
where each of R.sup.1 and R.sup.2 independently represents an alkyl group or an aromatic hydrocarbon group.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single layer and contains a charge generating material, a hole transport material, an electron transport material, and a polyarylate resin. The polyarylate resin includes repeating units represented by formulas (1), (2), and (3).
##STR00001##
A ratio n.sub.1/n.sub.2 of the number n.sub.1 of repeats of the repeating unit represented by formula (1) to the number n.sub.2 of repeats of the repeating unit represented by formula (2) is at least 1.0.
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single layer, and contains a charge generating material, an electron transport material, a binder resin, and a hole transport material.
##STR00001##
The electron transport material includes a compound represented by general formula (1). The binder resin includes a polycarbonate resin having an end group and a main chain represented by general formula (10).
ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS
An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single layer and contains a charge generating material, an electron transport material, a binder resin, and a hole transport material. The electron transport material includes a compound represented by general formula (1):
##STR00001##
In general formula (1), R.sup.1 and R.sup.2 each represent, independently of one another, a hydrogen atom, an alkyl group, a heterocyclic group, an alkoxy group, an aralkyl group, an allyl group, or an aryl group optionally substituted with at least 1 and no more than 5 substituents selected from the group consisting of a halogen atom, an alkyl group, and alkoxy group.
UNDERCOAT LAYER, METHOD FOR MANUFACTURING UNDERCOAT LAYER, ELECTROPHOTOGRAPHIC PHOTORECEPTOR, AND IMAGE FORMING APPARATUS
The undercoat layer contains metal particles and a polyamide resin. The metal particle has a core and a coat layer covering at least a part of the core. The core contains titanium oxide. The coat layer contains at least a metal oxide different from titanium oxide. The metal oxide different from the titanium oxide is located on the outermost surface of the metal particles. The polyamide resin has an amide bond and an alkylene group. The absorption rate of the first peak derived from the amide bond to the second peak derived from the alkylene group to the first absorbance measured by infrared spectroscopy is ≥0.70.
ELECTROPHOTOGRAPHIC PHOTOCONDUCTOR, METHOD OF MANUFACTURING THE SAME, AND ELECTROPHOTOGRAPHIC DEVICE
Provided are an electrophotographic photoconductor being resistant to abrasion even in long-term use, having highly sensitive electric characteristics, being capable of maintaining a high retention rate, and being capable of providing a stable image without filming, a method of manufacturing the same, and an electrophotographic device. The photoconductor includes an electroconductive substrate (1), a charge generation layer (3), and a charge transport layer (4); the charge transport layer contains a hole transport material, a resin binder, an electron transport material, and an inorganic oxide; the charge generation layer contains a charge generation material; the masses of the hole transport material, the resin binder, the electron transport material, and the inorganic oxide in the charge transport layer respectively denoted by a to d satisfy 1.5≤b/a≤5.7, 0.005≤c/a≤0.35, 0.05≤d/a≤0.70, a≥c+d, and c/d≥0.01; the hole transport material contains a compound expressed by formula (A-1); and the charge generation material contains titanyl phthalocyanine having an exothermic peak at 251±5° C., a half-value width of the exothermic peak equal to or less than 15° C., and a heating value equal to or greater than 1.0 mJ/mg when a temperature rise condition is 20° C./min in differential scanning calorimetry, and having an X-ray diffraction peak at 27.2±0.3°.
##STR00001##