Compositions are provided which may comprise a plurality of organic additive particles, the particles comprising a polymerization product of reactants comprising a dioxane/dioxolane monomer and a vinyl co-monomer, wherein the dioxane/dioxolane monomer is an ester of (meth)acrylic acid with an alcohol comprising a dioxane moiety, an ester of (meth)acrylic acid with an alcohol comprising a dioxolane moiety, or both. Toner and additive manufacturing compositions comprising the organic additive particles are also provided.

Toners are provided which may comprise toner particles, a colorant, and optionally, a wax, wherein the toner particles comprise a resin comprising a polymerization product of reactants comprising a dioxane/dioxolane monomer and a vinyl co-monomer, wherein the dioxane/dioxolane monomer is an ester of (meth)acrylic acid with an alcohol comprising a dioxane moiety, an ester of (meth)acrylic acid with an alcohol comprising a dioxolane moiety, or both.

An image forming method includes a charging step, an image exposure step, a developing step, a transferring step, a cleaning step, and a fixing step. A toner contains toner particles, the toner particles contain a resin A including a unit A1 including an alkyl group having 18 to 36 carbon atoms in the side chain, and the electrophotographic photoreceptor includes a surface layer containing (i) fluorine-containing resin particles and (ii) a fluorine-based polymer B.

A toner comprising a toner particle containing a binder resin and an inorganic fine particle, wherein the binder resin contains a crystalline resin, the crystalline resin has a first monomer unit represented by the following formula (1), the inorganic fine particle is at least one inorganic fine particle selected from the group consisting of a particle containing CaCO.sub.3, a particle containing BaSO.sub.4, a particle containing Mg.sub.3Si.sub.4O.sub.10(OH).sub.2, and a particle containing Al.sub.2Si.sub.2O.sub.5(OH).sub.4, the inorganic fine particle is treated with a fatty acid, and a content B of the inorganic fine particle in the toner particle is 1.0 mass % or more to 15.0 mass % or less,

##STR00001##

wherein R.sub.Z1 represents a hydrogen atom or a methyl group, and R.sup.1 represents an alkyl group having 18 to 36 carbon atoms.

A toner comprising a toner particle comprising a binder resin, wherein the binder resin comprises a resin A and a resin B, in a differential scanning calorimetric measurement, a peak top temperature of the largest endothermic peak is present within a specific temperature range and an endothermic amount of an endothermic peak derived from the resin A is 30 to 70 J/g per 1 g of the toner, a ratio of content of the resin A in the toner particle is 60.0 to 90.0 mass %, the resin A comprises 40.0 to 70.0 mass % of a monomer unit (a) represented by formula (1) below, and the resin B comprises 5.0 to 30.0 mass % of a monomer unit (b) represented by formula (2) below:

##STR00001## in formulae (1) and (2), R.sup.1 and R.sup.2 denote a hydrogen atom or a methyl group, n and m denote a specific integer.

A toner comprising a toner particle comprising a binder resin and a release agent, wherein the binder resin comprises a crystalline resin A, the crystalline resin A comprises a monomer unit derived from a monomer (a), the monomer (a) is at least one selected from the group consisting of (meth)acrylic acid esters having an alkyl group with 18 to 36 carbon atoms, the peak temperature and endothermic quantity at an endothermic peak derived from the crystalline resin A in DSC measurements using the toner satisfy specific relationships, and the release agent is at least one selected from the group consisting of hydrocarbon-based waxes and ester waxes.

A toner comprising a toner particle comprising a binder resin, wherein the binder resin comprises a first resin and a second resin, the first resin is a crystalline resin, the second resin is an amorphous resin, and in observations of cross sections of 100 toner particles using a transmission electron microscope, (i) when an area ratio A (area %) denotes a ratio of an area occupied by the first resin in each of cross sections of the toner particles, an average value of the area ratio A is 30 to 75 area %, and (ii) when X denotes the number of cross sections of the toner particle for which the area ratio A is 90 area % or more and Z denotes the total number of cross sections of observed toner particles, then a value of X/Z is 0.15 or more.

A toner is provided, which has a toner particle containing a binder resin including a first resin and a second resin, wherein the first resin is a crystalline resin, the second resin is an amorphous resin, the first resin contains a specific amount of a first monomer unit having a specific structure, an acid value of the first resin and an acid value of the second resin are within specific ranges, a domain-matrix structure formed of a matrix containing the first resin and domains containing the second resin appears in cross-sectional observation of the toner, the toner particle contains a multivalent metal element, the multivalent metal element is at least one metal element selected from the group consisting of Mg, Ca, Al, Fe and Zn, and a total content of the multivalent metal element is within a specific range.

Provided is a positive-charging toner having a toner particle that contains a binder resin, the binder resin contains a polymer A having a first monomer unit derived from a first polymerizable monomer, and a second monomer unit derived from a second polymerizable monomer, the first polymerizable monomer is at least one selected from the group consisting of (meth)acrylic acid esters having a C18 to C36 alkyl group, the content of the first monomer unit in the polymer A is 5.0 to 60.0 mol % and the content of the second monomer unit is 20.0 to 95.0 mol %, SP.sub.11 of the first monomer unit and SP.sub.21 of the second monomer unit satisfy 3.00≤(SP.sub.21−SP.sub.11)≤25.00, and the work function of the toner is 5.0 to 5.4 V.

A toner includes a toner particle containing a resin component. The resin component contains an ester group-containing olefin copolymer and an acid group-containing olefin copolymer. For example, the ester group-containing olefin copolymer is an ethylene-vinyl acetate copolymer, and the acid group-containing olefin copolymer is an ethylene-methacrylic acid copolymer. The acid group-containing olefin copolymer has an acid value of 50 to 300 mg KOH/g. The content of the ester group-containing olefin copolymer in the resin component is 50 mass % or more based on the total mass of the resin component. The content of the unit derived from the vinyl acetate is 3 mass % or more and 35 mass % or less based on the total mass of the ester group-containing olefin copolymer.