A toner comprising a toner particle containing a binder resin and an inorganic fine particle, wherein the binder resin contains a crystalline resin, the crystalline resin has a first monomer unit represented by the following formula (1), the inorganic fine particle is at least one inorganic fine particle selected from the group consisting of a particle containing CaCO.sub.3, a particle containing BaSO.sub.4, a particle containing Mg.sub.3Si.sub.4O.sub.10(OH).sub.2, and a particle containing Al.sub.2Si.sub.2O.sub.5(OH).sub.4, the inorganic fine particle is treated with a fatty acid, and a content B of the inorganic fine particle in the toner particle is 1.0 mass % or more to 15.0 mass % or less,

##STR00001##

wherein R.sub.Z1 represents a hydrogen atom or a methyl group, and R.sup.1 represents an alkyl group having 18 to 36 carbon atoms.

A toner comprising a toner particle comprising a binder resin and a crystalline resin, wherein the binder resin comprises an amorphous resin, when the toner is measured with a temperature-modulated differential scanning calorimeter, at least one endothermic peak derived from the crystalline resin is present in a temperature range from 55.0° C. to 95.0° C. in a total heat flow; and a ratio of an endothermic quantity of the endothermic peak in a reversing heat flow to an endothermic quantity of the endothermic peak in the total heat flow is 50.0% or more, a glass transition temperature Tg1st obtained in the reversing heat flow in a first temperature rise and a glass transition temperature Tg2nd obtained in a reversing heat flow in a second temperature rise satisfy Tg1st−Tg2nd≥7.0° C.

Described herein is an electrophotographic ink composition comprising: a first resin comprising a copolymer of an alkylene monomer and a monomer selected from acrylic acid and methacrylic acid; and a second resin comprising a condensation product of polyvinyl alcohol with an aldehyde. Also described herein is a method of producing the electrophotographic ink composition and a printed substrate produced by printing the electrophotographic ink composition.

A toner comprising a toner particle comprising a binder resin and a crystalline resin, wherein the binder resin comprises an amorphous resin, when the toner is measured with a temperature-modulated differential scanning calorimeter, at least one endothermic peak derived from the crystalline resin is present in a temperature range from 55.0° C. to 95.0° C. in a total heat flow; and a ratio of an endothermic quantity of the endothermic peak in a reversing heat flow to an endothermic quantity of the endothermic peak in the total heat flow is 50.0% or more, a glass transition temperature Tg1st obtained in the reversing heat flow in a first temperature rise and a glass transition temperature Tg2nd obtained in a reversing heat flow in a second temperature rise satisfy Tg1st−Tg2nd≥7.0° C.

A method for printing a three-dimensional part with an electrophotography-based additive manufacturing system having an electrophotography engine, a transfer medium, and a layer transfusion assembly includes providing a part material to the electrophotography-based additive manufacturing system, the part material compositionally comprising a charge control agent, and a thermoplastic material having a heat deflection temperature greater than about 150° C., and has a powder form. The method includes triboelectrically charging the part material to a Q/M ratio having a negative charge or a positive charge, and a magnitude ranging from about 5 micro-Coulombs/gram to about 50 micro-Coulombs/gram and developing layers of the three-dimensional part from the charged part material with the electrophotography engine. The method includes electrostatically attracting the developed layers from the electrophotography engine to the transfer medium and moving the attracted layers to the layer transfusion assembly with the transfer medium, wherein the layer transfusion assembly comprises a nip roller. The method includes transfusing the moved layers to previously-printed layers of the three-dimensional part with by moving the attracted layers about a nip of a nip roller using heat and pressure over time.

A polymerized rosin compound includes a rosin dimer component (A) including a bifunctional rosin dimer component (a1) represented by formula (1): ROOCXCOOR. In this formula, X represents a rosin dimer residue derived from abietic acid, neoabietic acid, or palustric acid, which are resin acids having conjugated double bonds; and R represents hydrogen, an alkyl group of I to 5 carbon atoms, or a benzyl group. The rosin dimer component (A) contains a bifunctional rosin dimer component (a1) in the amount of 80% by weight or more and a rosin trimer or higher oligomer component (B) in the range from 1.5 to 3.7% by weight, wherein the rosin dimer component is free of a monofunctional rosin dimer component (a2) having one functional group represented by formula (2): ROOC, wherein R represents hydrogen, an alkyl group of 1 to 5 carbon atoms, or a benzyl group, and free from functional group containing rosin dimer component (a3), wherein the functional group represented by formula (2): ROOC, wherein R represents hydrogen, an alkyl group of 1 to 5 carbon atoms, or a benzyl group. The polymerized rosin compound contains a large amount of the bifunctional rosin dimer component that makes it possible to obtain linear polymer with a high molecular weight.

A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material including a composition having a high-performance thermoplastic material and a charge control agent. The part material is provided in a powder form having a controlled particle size, and is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.

The polymerized rosin compound of the invention includes a rosin dimer component (A) including a bifunctional rosin dimer component (a1) represented by formula (1): ROOCXCOOR, wherein X represents a rosin dimer residue, and R represents hydrogen, an alkyl group of 1 to 5 carbon atoms, or a benzyl group, wherein the rosin dimer component (A) contains a content of the bifunctional rosin dimer component (a1) of 80% by weight or more and the polymerized rosin compound contains a content of the rosin dimer component (A) of 80% by weight or more. The polymerized rosin compound contains a large amount of the bifunctional rosin dimer component and makes it possible to obtain linear polymer with a high molecular weight.

A toner comprising a toner particle containing a binder resin and an inorganic fine particle, wherein the binder resin contains a crystalline resin, the crystalline resin has a first monomer unit represented by the following formula (1), the inorganic fine particle is at least one inorganic fine particle selected from the group consisting of a particle containing CaCO.sub.3, a particle containing BaSO.sub.4, a particle containing Mg.sub.3Si.sub.4O.sub.10(OH).sub.2, and a particle containing Al.sub.2Si.sub.2O.sub.5(OH).sub.4, the inorganic fine particle is treated with a fatty acid, and a content B of the inorganic fine particle in the toner particle is 1.0 mass % or more to 15.0 mass % or less, ##STR00001##
wherein R.sub.Z1 represents a hydrogen atom or a methyl group, and R.sup.1 represents an alkyl group having 18 to 36 carbon atoms.