Patent classifications
G03G9/08768
ELECTROPHOTOGRAPHIC TONER BINDER, AND TONER COMPOSITION
The present invention provides an electrophotographic toner binder containing, as a main component, a polymer whose constituent monomer is a monomer having an ethylenically unsaturated bond, the electrophotographic toner binder being excellent in low-temperature fixability, hot-offset resistance, and storage stability. The present invention provides an electrophotographic toner binder containing a polymer (A) containing a monomer (a) and a monomer (x) different from the monomer (a) as essential constituent monomers, wherein the monomer (a) is a (meth)acrylate having a C18-C36 acyclic hydrocarbon group, the polymer (A) has an acid value of 40 or less, and the polymer (A) satisfies the following relational expression (1):
1.1 (cal/cm.sup.3).sup.0.5|SP(x)SP(a)|8.0 (cal/cm.sup.3).sup.0.5relational expression (1):
wherein SP(a) is the SP value of a structural unit derived from the monomer (a) constituting the polymer (A); and
SP(x) is the SP value of a structural unit derived from the monomer (x) different from the monomer (a) constituting the polymer (A).
Electrostatic latent image developing toner
An electrostatic latent image developing toner includes a plurality of toner particles containing a binder resin. The binder resin has an amide bond and an ester bond. An area ratio of a peak originated from CO stretching of the amide bond to a peak originated from CO stretching of the ester bond is at least 0.00010 and no greater than 0.02000 in a FT-IR spectrum of the toner obtained by Fourier transform infrared spectroscopy analysis. The toner has a storage elastic modulus at 80 C. of at least 3.510.sup.4 Pa and no greater than 5.010.sup.4 Pa. The toner has a storage elastic modulus at 120 C. of at least 1.010.sup.3 Pa and no greater than 1010.sup.4 Pa. The toner has a storage elastic modulus at 150 C. of at least 1.010.sup.3 Pa and no greater than 1010.sup.4 Pa.
Toner
Toner particles each have a toner core, a shell layer covering a surface of the toner core, and first resin particles containing a melamine resin. A shell layer coverage is 60% to 80%. The first resin particles each have an embedded portion and a protrusion portion. The embedded portions are embedded beneath the surface of the toner core. The protrusion portions protrude outward from the surface of the toner core in a radial direction of the toner particle. An average value Wd of thicknesses b of the shell layers, a number average value Dp of embedment depths c of the first resin particles, and a number average value Pd of primary particle diameters d of the first resin particles satisfy relations (1) to (3) shown below.
0.2Dp/Pd0.8(1)
(PdDp)>Wd(2)
0.10 mPd1.00 m(3)
ELECTROSTATIC LATENT IMAGE DEVELOPING TONER
An electrostatic latent image developing toner includes a plurality of toner particles containing a binder resin. The binder resin has an amide bond and an ester bond. An area ratio of a peak originated from CO stretching of the amide bond to a peak originated from CO stretching of the ester bond is at least 0.00010 and no greater than 0.02000 in a FT-IR spectrum of the toner obtained by Fourier transform infrared spectroscopy analysis. The toner has a storage elastic modulus at 80 C. of at least 3.510.sup.4 Pa and no greater than 5.010.sup.4 Pa. The toner has a storage elastic modulus at 120 C. of at least 1.010.sup.3 Pa and no greater than 1010.sup.4 Pa. The toner has a storage elastic modulus at 150 C. of at least 1.010.sup.3 Pa and no greater than 1010.sup.4 Pa.
TONER
Toner particles each have a toner core, a shell layer covering a surface of the toner core, and first resin particles containing a melamine resin. A shell layer coverage is 60% to 80%. The first resin particles each have an embedded portion and a protrusion portion. The embedded portions are embedded beneath the surface of the toner core. The protrusion portions protrude outward from the surface of the toner core in a radial direction of the toner particle. An average value Wd of thicknesses b of the shell layers, a number average value Dp of embedment depths c of the first resin particles, and a number average value Pd of primary particle diameters d of the first resin particles satisfy relations (1) to (3) shown below.
0.2Dp/Pd0.8(1)
(PdDp)>Wd(2)
0.10 mPd1.00 m(3)
Part material for electrophotography-based additive manufacturing
A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material including a composition having a copolymer (including acrylonitrile units, butadiene units, and aromatic units), a charge control agent, and a heat absorber. The part material is provided in a powder form having a controlled particle size, and is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.
TONER
A toner includes a plurality of toner particles (10) each including a toner mother particle (11) and a plurality of external additive particles (12) attached to a surface of the toner mother particle (11). The external additive particles (12) each include a silica particles (12a), a metal hydroxide layer, and a coating layer (12b). The metal hydroxide layer is disposed on a surface of the silica particle (12a). At least a part of the coating layer (12b) is disposed on a surface of the metal hydroxide layer. The coating layer (12b) is made substantially from a nitrogen containing resin.
HIGH-PERFORMANCE CONSUMABLE MATERIALS FOR ELECTROPHOTOGRAPHY-BASED ADDITIVE MANUFACTURING SYSTEM
A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material including a composition having a high-performance thermoplastic material and a charge control agent. The part material is provided in a powder form having a controlled particle size, and is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.
Photoresponsive polymer
[Object] An object of the present invention is to provide a photoresponsive polymer that sufficiently secures photoresponsiveness to be fluidized by light irradiation and reversibly non-fluidized, improves fixability, and further has good color reproducibility. [Solution] Provided is a photoresponsive polymer containing a structural unit derived from an azomethine derivative represented by the following general formula (1), the photoresponsive polymer being fluidized by light irradiation and reversibly non-fluidized:
R.sub.1Z.sub.1Z.sub.2R.sub.2General formula (1): Z.sub.1 and Z.sub.2 are N or CH, while Z.sub.1Z.sub.2, R.sub.1 contains an aromatic hydrocarbon structure, R.sub.2 contains an aromatic heterocyclic structure, and a hydrogen atom is bonded to at least one carbon atom bonded adjacent to a carbon atom in the aromatic heterocyclic structure bonded to the Z.sub.2.
Liquid developer, method for controlling charging properties of toner, image forming apparatus, image forming method, process cartridge, and liquid developer cartridge
An image forming apparatus includes an image holding member, a first charging unit that charges a surface of the image holding member, a latent image forming unit that forms an electrostatic latent image on a charged surface of the image holding member, a second charging unit that charges a toner contained in a liquid developer, a developing unit that accommodates the liquid developer and develops the electrostatic latent image by using the liquid developer containing the toner charged by the second charging unit to form a toner image, a transfer unit that transfers the toner image to a recording medium, and a fixing unit that fixes the toner image to the recording medium. The liquid developer includes a toner in which a compound having a charge-accepting functional group has been bonded to a surface of toner particles, an ionization-controlling agent that ionizes the charge-accepting functional group, and a carrier liquid.