A toner for developing an electrostatic charge image contains toner particles that contain binder resins including an amorphous resin and a crystalline resin and also contain an oligomer. The molecular weight distribution curve of the toner measured by gel permeation chromatography has its highest peak in a range of molecular weights from 5000 to 50000 and a peak or shoulder in a range of molecular weights from 500 to 5000. In a cross-sectional observation of the toner particles, domains of the crystalline resin have an average length of major axis of 100 nm or more and 1000 nm or less.

An object of the present invention is to provide an image forming method capable of coating a photocurable varnish without unevenness on a toner image formed using an electrostatic latent image developing toner, and further having good adhesion between a varnish layer and the toner image. The image forming method of the present invention comprises: forming a toner image on a recording medium using an electrostatic latent image developing toner containing a toner particle comprising a binder resin and a release agent; and forming a varnish layer on the toner image by applying and curing a photocurable varnish comprising a photocurable compound. The binder resin comprised in the electrostatic latent image developing toner contains a crystalline polyester resin. The photocurable compound comprised in the photocurable varnish comprises a diol di(meth)acrylate having a straight hydrocarbon chain.

Disclosed are methods and systems for solid phase transfer of a reagent to a substrate. In some embodiments, the method comprises providing at least a first composition comprising a solid phase, wherein the solid phase comprises a reagent; and dispensing a first sample from the first composition onto a first coordinate on a substrate, whereby the first reagent is transferred to the substrate from the solid phase.

An object of the present invention is to provide an image forming method capable of coating a photocurable varnish without unevenness on a toner image formed using an electrostatic latent image developing toner, and further having good adhesion between a varnish layer and the toner image. The image forming method of the present invention comprises: forming a toner image on a recording medium using an electrostatic latent image developing toner containing a toner particle comprising a binder resin and a release agent; and forming a varnish layer on the toner image by applying and curing a photocurable varnish comprising a photocurable compound. The binder resin comprised in the electrostatic latent image developing toner contains a crystalline polyester resin. The photocurable compound comprised in the photocurable varnish comprises a diol di(meth)acrylate having a straight hydrocarbon chain.

Methods of using a toner as a printable adhesive are provided. In embodiments, a method of adhering substrates is provided which comprises disposing a cold pressure fix toner comprising a phase change material on a first substrate via xerography to form an unfused layer of the cold pressure fix toner on the first substrate; placing a second substrate on the unfused layer of the cold pressure fix toner; and subjecting the cold pressure fix toner to a pressure to form a bonded article comprising the first substrate, an adhesive layer formed from the cold pressure fix toner, and the second substrate. Methods of applying an adhesive to a substrate and bonded articles are also provided.

The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In particular, the crash cooling process involves the addition of a toner slurry having a temperature between 70 C. and 90 C. to an equivalent amount of cold water having a temperature between 5 C. and 20 C. Polyester and styrene acrylic toners as well as polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this cooling process results in an improvement to the amount of toner waste, thereby achieving a higher toner usage efficiency for an electrophotographic printing system.

A support material toner particle for use in xerographic additive manufacturing includes a .Iadd.PVA polymer blend including a .Iaddend.polyvinyl alcohol (PVA) polymer and blend-additives including a chitosan and a polyvinylpyrrolidone (PVP), the amount of blend-additives is selected to adjust the T.sub.g of the PVA polymer .Iadd.blend .Iaddend.to be within about 1 C. to about 20 C. of a desired build material toner T.sub.g. A xerographic toner system includes a build toner material and a support toner material, the support toner material includes .Iadd.a PVA polymer blend including .Iaddend.a polyvinyl alcohol (PVA) polymer and blend-additives including a chitosan and a polyvinylpyrrolidone (PVP), the amount of blend-additives is selected to adjust the T.sub.g of the PVA polymer .Iadd.blend .Iaddend.to be within about 1 C. to about 20 C. of the build material toner T.sub.g. A method of making a support toner material includes blending polyvinyl alcohol with blend additives including a chitosan and polyvinylpyrrolidone and forming support toner particles after the blending step.

The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In the crash cooling process, hot toner slurry is added to an external reactor containing a coolant comprised of previously cooled toner slurry in combination with cooled de-ionized water. The previously cooled toner slurry found in the coolant has the same toner composition as the incoming hot toner slurry. Also, the amount of the coolant in the external reactor is equivalent to the amount of incoming hot toner slurry. Polyester toners and polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this crash cooling process results in an improvement to the toner performance especially a decrease in the overall toner usage.

The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In the crash cooling process, an amount of hot toner slurry is added to an external reactor holding an amount of chilled cooling water, wherein the temperature of the chilled cooling water in the external reactor is from about 8 C. to about 25 C. The amount of the chilled cooling water in the external reactor is about 10% to about 40% lower compared to the amount of the added hot toner slurry. Toner prepared using this crash cooling method is cooled at a rate of less than 0.8 C./min. Polyester toners and polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this crash cooling processes using less water results in an improvement to the toner's print density and usage efficiency.

The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In the crash cooling process, an amount of hot toner slurry is added to an external reactor holding an amount of chilled cooling water, wherein the temperature of the chilled cooling water in the external reactor is from about 8 C. to about 25 C. The amount of the chilled cooling water in the external reactor is about 10% to about 40% lower compared to the amount of the added hot toner slurry. Toner prepared using this crash cooling method is cooled at a rate of less than 0.8 C./min. Polyester toners and polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this crash cooling processes using less water results in an improvement to the toner's print density and usage efficiency.