Patent classifications
G03G9/1132
Carrier core material and electrophotographic development carrier using same and electrophotographic developer
According to the present invention, there is provided a carrier core material that is formed of ferrite particles in which 48 to 52 mass % of Fe, 16 to 22 mass % of Mn, 1.0 to 3.5 mass % of Mg and 0.05 to 0.5 mass % of Ca are included, and when an electrical resistance value with an applied voltage of 500 V in an environment (in an L/L environment) in which the temperature is 10° C. and the relative humidity is 35% is R.sub.L (Ω.Math.cm), and an electrical resistance value with an applied voltage of 500 V in an environment (in an H/H environment) in which the temperature is 30° C. and the relative humidity is 70% is R.sub.H (Ω.Math.cm), formula (1) below is satisfied.
0.1≤(log R.sub.L−log R.sub.H)≤0.3 (1)
FERRITE PARTICLE HAVING OUTER SHELL STRUCTURE
An object of the present invention is to provide a ferrite particle having a low apparent density, filling a specified volume with a low weight with various properties maintained in a controllable state, a ferrite carrier core material composed of the ferrite particle, and a ferrite carrier using the ferrite core material and an electrophotographic developer. To achieve the object, the ferrite particle having the outer shell structure containing the Ti oxide for the ferrite carrier core material, and the ferrite carrier using the ferrite particle as the ferrite carrier core material and the electrophotographic developer are employed.
TWO-COMPONENT DEVELOPER FOR ELECTROSTATIC CHARGE IMAGE DEVELOPMENT, ELECTROPHOTOGRAPHIC IMAGE FORMING METHOD AND ELECTROPHOTOGRAPHIC IMAGE FORMING APPARATUS
Provided is a two-component developer for electrostatic charge image development including: toner particles containing toner base particles and an external additive disposed on a surface of the toner base particles; and carrier particles having a core material particle and a shell portion disposed on a surface of the core material particle, wherein the external additive contains inorganic particles surface-modified with a surface modifier represented by the following Formula (1); and a value of an iron element content (atomic %) measured by X-ray photoelectron spectroscopy (XPS) on a surface of the carrier particles satisfies the following Expression (1),
(R.sub.1).sub.4-n—Si—(X).sub.n Formula (1):
4.0≤{A.sub.Fe/(A.sub.c+A.sub.o+A.sub.Fe)}×100≤15.0 Expression (1):
ELECTROSTATIC CHARGE IMAGE DEVELOPER, PROCESS CARTRIDGE, IMAGE FORMING APPARATUS, AND IMAGE FORMING METHOD
An electrostatic charge image developer contains: a toner containing a toner particle and an external additive; and a carrier containing a magnetic particle and a resin layer covering the magnetic particle; and the toner particle has a surface property index value of 1.0 or more and less than 2.0; and the carrier has a surface having a ratio B/A of a surface area B to a plane view area A of 1.020 or more and 1.100 or less, the plane view area A and the surface area B being obtained by three-dimensional analysis of the surface of the carrier.
ELECTROSTATIC IMAGE DEVELOPER, PROCESS CARTRIDGE, IMAGE FORMING APPARATUS, AND IMAGE FORMING METHOD
An electrostatic image developer includes a toner including toner particles and an external additive, wherein an amount of the external additive that is loose relative to a total mass of the external additive is 5 mass % or less, and a carrier including magnetic particles and resin cover layers covering the magnetic particles and including inorganic particles, wherein a fine-irregularity-structure surface roughness of surfaces three-dimensionally analyzed has, in an analysis region, a ratio B/A of an irregularity-surface area B to a plan-view area A of 1.020 or more and 1.100 or less.
FERRITE PARTICLES, ELECTROPHOTOGRAPHIC DEVELOPER CARRIER CORE MATERIAL, ELECTROPHOTOGRAPHIC DEVELOPER CARRIER, AND ELECTROPHOTOGRAPHIC DEVELOPER
The present invention relates to a ferrite particle containing a crystal phase component containing a perovskite crystal represented by a compositional formula: RZrO.sub.3 (provided that R represents an alkaline earth metal element), having a surface roughness Rz of 0.8 .Math.m or more and 3.5 .Math.m or less, and having a standard deviation Rzσ of the surface roughness Rz falling in a range represented by the following formula 0.15 × Rz ≤ Rzσ ≤ 0.60 × Rz. The ferrite particle can be used as an electrophotographic developer carrier core material. In addition, an electrophotographic developer carrier and an electrophotographic developer can be obtained.
FERRITE PARTICLES, ELECTROPHOTOGRAPHIC DEVELOPER CARRIER CORE MATERIAL, ELECTROPHOTOGRAPHIC DEVELOPER CARRIER, AND ELECTROPHOTOGRAPHIC DEVELOPER
The present invention relates to a ferrite particle containing a crystal phase component containing a perovskite crystal represented by a compositional formula: RZrO.sub.3 (provided that R represents an alkaline earth metal element), having a surface roughness Rz of 2.0 μm or more and 4.5 μm or less, and satisfying the following formulas: 6.5≤log H.sub.1000≤8.5 and 0.80≤log H.sub.1000/log H.sub.100≤1.00. The ferrite particle can be used as an electrophotographic developer carrier core material. In addition, an electrophotographic developer carrier and an electrophotographic developer can be obtained.
CARRIER FOR TWO-COMPONENT DEVELOPER, TWO-COMPONENT DEVELOPER, AND METHOD OF PREPARING CARRIER FOR TWO-COMPONENT DEVELOPER
A carrier for two-component developer includes a magnetic particle and a resin coating layer that covers the magnetic particle and contains a resin, wherein a weight average molecular weight of the resin contained in the resin coating layer is from 1,800,000 to 5,000,000.
Ferrite particles, carrier for electrophotographic development using same, and developer for electrophotography
Ferrite particles have, as a main component, a material represented by a composition formula M.sub.xFe.sub.3−xO.sub.4 (where M is at least one type of metal selected from a group made of Mg, Mn, Ca, Ti, Cu, Zn, Sr and Ni, 0<x<1), where the maximum height Rz of the particles falls within a range of 1.40 μm to 1.90 μm, and the degree of distortion Rsk of the particles falls within a range of −0.25 to −0.07. In this way, when the ferrite particles are used as the carrier of an electrophotographic image forming apparatus, even if an image formation speed is increased, the occurrence of a failure is reduced for a long period of time.
ELECTROSTATIC CHARGE IMAGE DEVELOPING CARRIER, ELECTROSTATIC CHARGE IMAGE DEVELOPER, PROCESS CARTRIDGE, IMAGE FORMING APPARATUS AND IMAGE FORMING METHOD
An electrostatic charge image developing carrier includes a magnetic particle and a coating resin layer that covers the magnetic particle and contains a silica particle, and a ratio of Si on a surface of the coating resin layer, determined by an X-ray photoelectron spectroscopy (XPS), is 6 atom % or more and 12 atom % or less.