G21C21/04

Fully ceramic microencapsulated fuels containing tristructural-isotropic particles with a coating layer having higher shrinkage than matrix

The present invention relates to a method for preparing a fully ceramic capsulated nuclear fuel material containing three-layer-structured isotropic nuclear fuel particles coated with a ceramic having a composition which has a higher shrinkage than a matrix in order to prevent cracking of ceramic nuclear fuel, wherein the three-layer-structured nuclear fuel particles before coating is included in the range of between 5 and 40 fractions by volume based on after sintering. More specifically, the present invention provides a composition for preparing a fully ceramic capsulated nuclear fuel containing three-layer-structured isotropic particles coated with the substance which includes, as a main ingredient, a silicon carbine derived from a precursor of the silicon carbide wherein a condition of ΔL.sub.c>ΔL.sub.m at normal pressure sintering is created, where the sintering shrinkage of the coating layer of the three-layer-structured isotropic nuclear fuel particles is ΔL.sub.c and the sintering shrinkage of the silicon carbide matrix is ΔL.sub.m; material produced therefrom; and a method for manufacturing the material. The residual porosity of the fully ceramic capsulated nuclear fuel material is 4% or less.

Fully ceramic microencapsulated fuels containing tristructural-isotropic particles with a coating layer having higher shrinkage than matrix

The present invention relates to a method for preparing a fully ceramic capsulated nuclear fuel material containing three-layer-structured isotropic nuclear fuel particles coated with a ceramic having a composition which has a higher shrinkage than a matrix in order to prevent cracking of ceramic nuclear fuel, wherein the three-layer-structured nuclear fuel particles before coating is included in the range of between 5 and 40 fractions by volume based on after sintering. More specifically, the present invention provides a composition for preparing a fully ceramic capsulated nuclear fuel containing three-layer-structured isotropic particles coated with the substance which includes, as a main ingredient, a silicon carbine derived from a precursor of the silicon carbide wherein a condition of ΔL.sub.c>ΔL.sub.m at normal pressure sintering is created, where the sintering shrinkage of the coating layer of the three-layer-structured isotropic nuclear fuel particles is ΔL.sub.c and the sintering shrinkage of the silicon carbide matrix is ΔL.sub.m; material produced therefrom; and a method for manufacturing the material. The residual porosity of the fully ceramic capsulated nuclear fuel material is 4% or less.

Method for fabrication of oxide fuel pellets and the oxide fuel pellets thereby

Disclosed herein is a method for manufacturing oxide fuel pellets. The method for manufacturing the oxide fuel pellets includes (step 1) preparing nuclear fuel powder containing uranium dioxide (UO2+x, x=0 to 0.20), (step 2) compacting the nuclear fuel powder prepared in step 1 to manufacture green pellets, sintering the green pellets manufactured in step 2 at a temperature of about 1,200° C. to about 1,400° C. by using an atmosphere gas, and reducing the green pellets sintered in step 3 at a temperature of about 800° C. to about 1,000° C. by using a reducing atmosphere gas. The method for manufacturing the oxide fuel pellets according to the present invention performs the sintering at a low temperature of about 1,200° C. to 1,400° C. to manufacture economical and safe oxide fuel pellets that are adequate for the nuclear fuel specification.

Method for fabrication of oxide fuel pellets and the oxide fuel pellets thereby

Disclosed herein is a method for manufacturing oxide fuel pellets. The method for manufacturing the oxide fuel pellets includes (step 1) preparing nuclear fuel powder containing uranium dioxide (UO2+x, x=0 to 0.20), (step 2) compacting the nuclear fuel powder prepared in step 1 to manufacture green pellets, sintering the green pellets manufactured in step 2 at a temperature of about 1,200° C. to about 1,400° C. by using an atmosphere gas, and reducing the green pellets sintered in step 3 at a temperature of about 800° C. to about 1,000° C. by using a reducing atmosphere gas. The method for manufacturing the oxide fuel pellets according to the present invention performs the sintering at a low temperature of about 1,200° C. to 1,400° C. to manufacture economical and safe oxide fuel pellets that are adequate for the nuclear fuel specification.

POWDER-TRANSFER DEVICE WITH IMPROVED FLOW

A device for transferring a given powder or a mixture of given powders contained in a container including a side wall and at least one discharge opening, the container with axisymmetric shape having an axis of rotation being arranged in the transfer device such that the discharge opening thereof is located in a lower portion of the container, the transfer device including rotating the container about the axis thereof, on which the discharge opening is located and control for controlling the rotation such that the rotation impose on at least one portion of the side wall of the container, referred to as movable portion, a first moving phase wherein an acceleration no lower than a minimum acceleration is capable of causing the powder to slide relative to the movable portion.

POWDER-TRANSFER DEVICE WITH IMPROVED FLOW

A device for transferring a given powder or a mixture of given powders contained in a container including a side wall and at least one discharge opening, the container with axisymmetric shape having an axis of rotation being arranged in the transfer device such that the discharge opening thereof is located in a lower portion of the container, the transfer device including rotating the container about the axis thereof, on which the discharge opening is located and control for controlling the rotation such that the rotation impose on at least one portion of the side wall of the container, referred to as movable portion, a first moving phase wherein an acceleration no lower than a minimum acceleration is capable of causing the powder to slide relative to the movable portion.

Method for process for producing fully ceramic microencapsulated fuels containing tristructural-isotropic particles with a coating layer having higher shrinkage than matrix

The present invention relates to a method for preparing a fully ceramic capsulated nuclear fuel material containing three-layer-structured isotropic nuclear fuel particles coated with a ceramic having a composition which has a higher shrinkage than a matrix in order to prevent cracking of ceramic nuclear fuel, wherein the three-layer-structured nuclear fuel particles before coating is included in the range of between 5 and 40 fractions by volume based on after sintering. More specifically, the present invention provides a composition for preparing a fully ceramic capsulated nuclear fuel containing three-layer-structured isotropic particles coated with the substance which includes, as a main ingredient, a silicon carbine derived from a precursor of the silicon carbide wherein a condition of ΔL.sub.c>ΔL.sub.m at normal pressure sintering is created, where the sintering shrinkage of the coating layer of the three-layer-structured isotropic nuclear fuel particles is ΔL.sub.c and the sintering shrinkage of the silicon carbide matrix is ΔL.sub.m; material produced therefrom; and a method for manufacturing the material. The residual porosity of the fully ceramic capsulated nuclear fuel material is 4% or less.

Method for process for producing fully ceramic microencapsulated fuels containing tristructural-isotropic particles with a coating layer having higher shrinkage than matrix

The present invention relates to a method for preparing a fully ceramic capsulated nuclear fuel material containing three-layer-structured isotropic nuclear fuel particles coated with a ceramic having a composition which has a higher shrinkage than a matrix in order to prevent cracking of ceramic nuclear fuel, wherein the three-layer-structured nuclear fuel particles before coating is included in the range of between 5 and 40 fractions by volume based on after sintering. More specifically, the present invention provides a composition for preparing a fully ceramic capsulated nuclear fuel containing three-layer-structured isotropic particles coated with the substance which includes, as a main ingredient, a silicon carbine derived from a precursor of the silicon carbide wherein a condition of ΔL.sub.c>ΔL.sub.m at normal pressure sintering is created, where the sintering shrinkage of the coating layer of the three-layer-structured isotropic nuclear fuel particles is ΔL.sub.c and the sintering shrinkage of the silicon carbide matrix is ΔL.sub.m; material produced therefrom; and a method for manufacturing the material. The residual porosity of the fully ceramic capsulated nuclear fuel material is 4% or less.

Additive Manufacturing of Complex Objects Using Refractory Matrix Materials
20220212363 · 2022-07-07 ·

A method for the manufacture of a three-dimensional object using a refractory matrix material is provided. The method includes the additive manufacture of a green body from a powder-based refractory matrix material followed by densification via chemical vapor infiltration (CVI). The refractory matrix material can be a refractory ceramic (e.g., silicon carbide, zirconium carbide, or graphite) or a refractory metal (e.g., molybdenum or tungsten). In one embodiment, the matrix material is deposited according to a binder-jet printing process to produce a green body having a complex geometry. The CVI process increases its density, provides a hermetic seal, and yields an object with mechanical integrity. The residual binder content dissociates and is removed from the green body prior to the start of the CVI process as temperatures increase in the CVI reactor. The CVI process selective deposits a fully dense coating on all internal and external surfaces of the finished object.

Additive manufacturing of complex objects using refractory matrix materials

A method for the manufacture of a three-dimensional object using a refractory matrix material is provided. The method includes the additive manufacture of a green body from a powder-based refractory matrix material followed by densification via chemical vapor infiltration (CVI). The refractory matrix material can be a refractory ceramic (e.g., silicon carbide, zirconium carbide, or graphite) or a refractory metal (e.g., molybdenum or tungsten). In one embodiment, the matrix material is deposited according to a binder-jet printing process to produce a green body having a complex geometry. The CVI process increases its density, provides a hermetic seal, and yields an object with mechanical integrity. The residual binder content dissociates and is removed from the green body prior to the start of the CVI process as temperatures increase in the CVI reactor. The CVI process selective deposits a fully dense coating on all internal and external surfaces of the finished object.