Plated metallic substrates and methods of manufacture are provided. The method comprises depositing a first layer onto at least a portion of the metallic substrate to create a coated substrate utilizing physical vapor deposition. The method comprises electroplating a second layer comprising chromium, a chromium alloy, or a combination thereof onto at least a portion of the first layer to create a plated substrate.

Plated metallic substrates and methods of manufacture are provided. The method comprises depositing a first layer onto at least a portion of the metallic substrate to create a coated substrate utilizing physical vapor deposition. The method comprises electroplating a second layer comprising chromium, a chromium alloy, or a combination thereof onto at least a portion of the first layer to create a plated substrate.

This disclosure describes fuel-cladding chemical interaction (FCCI) resistant nuclear fuel elements and their manufacturing techniques. The nuclear fuel elements include two or more layers of different materials (i.e., adjacent barriers are of different base materials) provided on a steel cladding to reduce the effects of FCCI between the cladding and the nuclear material. Depending on the embodiment, a layer may be the structural element (i.e., a layer thick enough to provide more than 50% of the strength of the overall component consisting of the cladding and the barriers) or may be more appropriately described as a liner or coating that is applied in some fashion to a surface of the structural component (e.g., to the cladding, or to a structural form of the fuel).

This disclosure describes fuel-cladding chemical interaction (FCCI) resistant nuclear fuel elements and their manufacturing techniques. The nuclear fuel elements include two or more layers of different materials (i.e., adjacent barriers are of different base materials) provided on a steel cladding to reduce the effects of FCCI between the cladding and the nuclear material. Depending on the embodiment, a layer may be the structural element (i.e., a layer thick enough to provide more than 50% of the strength of the overall component consisting of the cladding and the barriers) or may be more appropriately described as a liner or coating that is applied in some fashion to a surface of the structural component (e.g., to the cladding, or to a structural form of the fuel).

A method of manufacturing nuclear fuel elements may include: forming a graphite base portion of the fuel element; depositing a first layer of graphite spheres on the base portion; depositing a first layer of fuel, burnable poison and/or breeder particles on the first layer of graphite spheres; forming a second layer of graphite spheres on the first layer of particles; depositing a second layer of fuel, burnable poison and/or breeder particles on the second layer of graphite spheres; and forming a graphite cap portion of the fuel element. Fuel, burnable poison and/or breeder particles of the first layer may be are spaced apart by substantially the same distance, and fuel, burnable poison and/or breeder particles of the second layer may be spaced apart by substantially the same distance. The fuel element may be a spherical fuel pebble. The fuel particles may be tri-structural-isotropic (TRISO) particles without an overcoat.

A method of manufacturing nuclear fuel elements may include: forming a graphite base portion of the fuel element; depositing a first layer of graphite spheres on the base portion; depositing a first layer of fuel, burnable poison and/or breeder particles on the first layer of graphite spheres; forming a second layer of graphite spheres on the first layer of particles; depositing a second layer of fuel, burnable poison and/or breeder particles on the second layer of graphite spheres; and forming a graphite cap portion of the fuel element. Fuel, burnable poison and/or breeder particles of the first layer may be are spaced apart by substantially the same distance, and fuel, burnable poison and/or breeder particles of the second layer may be spaced apart by substantially the same distance. The fuel element may be a spherical fuel pebble. The fuel particles may be tri-structural-isotropic (TRISO) particles without an overcoat.

A method of manufacturing nuclear fuel elements may include: forming a base portion of the fuel element by depositing a powdered matrix material including a mixture of a graphite material and a fibrous material; depositing particles on the base portion in a predetermined pattern to form a first particle layer, by controlling the position of each particle in the first particle layer; depositing the matrix material on the first particle layer to form a first matrix layer; depositing particles on the first matrix layer in a predetermined pattern to form a second particle layer by controlling positions of each particle in the second particle layer; depositing the matrix material on the second particle layer to form a second matrix layer; and forming a cap portion of the fuel pebble by depositing the matrix material. The particles in the first particle layer and the second particle layer include nuclear fuel particles.

Nuclear fuel elements may include: a fuel zone including fuel particles disposed in parallel layers in a matrix including graphite powder; and a shell comprising graphite and surrounding the fuel zone. The fuel particles may include fissile particles, burnable poison particles, breeder particles, or a combination thereof. The fuel zone may include a central region and a peripheral region surrounding the central region, and a fuel particle density of the peripheral region may be greater than a fuel particle density of the central region.

A method of manufacturing nuclear fuel elements may include: forming a base portion of the fuel element by depositing a powdered matrix material including a mixture of a graphite material and a fibrous material; depositing particles on the base portion in a predetermined pattern to form a first particle layer, by controlling the position of each particle in the first particle layer; depositing the matrix material on the first particle layer to form a first matrix layer; depositing particles on the first matrix layer in a predetermined pattern to form a second particle layer by controlling positions of each particle in the second particle layer; depositing the matrix material on the second particle layer to form a second matrix layer; and forming a cap portion of the fuel pebble by depositing the matrix material. The particles in the first particle layer and the second particle layer include nuclear fuel particles.

Pre-ceramic particle solutions can prepared by a Coordinated-PDC process, a Direct-PDC process or a Coordinated-Direct-PDC process. The pre-ceramic particle solution includes a polymer selected from the group consisting of (i) an organic polymer including a metal or metalloid cation, (ii) a first organometallic polymer and (iii) a second organometallic polymer including a metal or metalloid cation different from a metal in the second organometallic polymer, a plurality of particles selected from the group consisting of (a) a ceramic fuel particle and (b) a moderator particle, a dispersant, and a polymerization initiator. The pre-ceramic particle solution can be supplied to an additive manufacturing process, such as digital light projection, and made into a structure (which is pre-ceramic particle green body) that can then be debinded to form a polymer-derived ceramic sintered body. In some embodiments, the polymer-derived ceramic sintered body is a component or structure for fission reactors.