Provided is a grain-oriented electrical steel sheet having both low iron loss and good magnetostrictive properties, with which a transformer having excellent properties can be manufactured. The grain-oriented electrical steel sheet of the present disclosure has a linear strain region extending linearly in a direction intersecting the rolling direction, where the linear strain region has a region having compressive stress in the rolling direction, and a region adjacent in a rolling direction to the region having compressive stress has a region having tensile stress in the rolling direction.

Provided is a grain-oriented electrical steel sheet having both low iron loss and good magnetostrictive properties, with which a transformer having excellent properties can be manufactured. The grain-oriented electrical steel sheet of the present disclosure has a linear strain region extending linearly in a direction intersecting the rolling direction, where the linear strain region has a region having compressive stress in the rolling direction, and a region adjacent in a rolling direction to the region having compressive stress has a region having tensile stress in the rolling direction.

Disclosed are a magnetic coating material, a magnetic sheet, and a metal compatible tag that have excellent magnetic shielding characteristics against radio waves in the UHF band and do not interfere with a distribution process. A magnetic coating material includes a magnetic filler and a binder resin, wherein the magnetic filler is an Fe—Cr alloy, and wherein in a magnetic sheet formed from the magnetic coating material, complex relative permeability in 860 MHz to 960 MHz has a loss factor tan δ of 0.3 or less and a real part μ′ of 5 or more. Also, a magnetic coating material includes a magnetic filler and a binder resin, wherein the magnetic filler is an Fe—Cr alloy, and wherein a mass ratio of the magnetic filler to a solid content of the binder (mass of the magnetic filler/mass of the solid content of the binder) is from 70/30 to 95/5.

Disclosed are a magnetic coating material, a magnetic sheet, and a metal compatible tag that have excellent magnetic shielding characteristics against radio waves in the UHF band and do not interfere with a distribution process. A magnetic coating material includes a magnetic filler and a binder resin, wherein the magnetic filler is an Fe—Cr alloy, and wherein in a magnetic sheet formed from the magnetic coating material, complex relative permeability in 860 MHz to 960 MHz has a loss factor tan δ of 0.3 or less and a real part μ′ of 5 or more. Also, a magnetic coating material includes a magnetic filler and a binder resin, wherein the magnetic filler is an Fe—Cr alloy, and wherein a mass ratio of the magnetic filler to a solid content of the binder (mass of the magnetic filler/mass of the solid content of the binder) is from 70/30 to 95/5.

A method for manufacturing a grain-oriented electrical steel sheet, according to an embodiment of the present invention includes: heating a slab, based on 100 wt % of a total composition thereof, including N at 0.0005 wt % to 0.015 wt %, Ti at 0.0001 wt % to 0.020 wt %, V at 0.0001 wt % to 0.020 wt %, Nb at 0.0001 wt % to 0.020 wt %, B at 0.0001 wt % to 0.020 wt %, and the remaining portion including Fe and other impurities, and then hot rolling it to prepare a hot-rolled steel sheet; annealing the hot-rolled steel sheet; after the hot-rolled steel sheet is annealed, cooling the hot-rolled steel sheet, and then cold rolling it to prepare a cold-rolled steel sheet; decarburization-annealing the cold-rolled steel sheet and then nitriding-annealing it, or simultaneously performing the decarburization-annealing and the nitriding-annealing; and final-annealing the decarburization-annealed and nitriding-annealed steel sheet.

A grain-oriented electrical steel sheet that includes a base coating with a high TiN ratio advantageous for the application of tension to the steel sheet and has excellent magnetic property is provided. The grain-oriented electrical steel sheet includes: a base coating having a peak value PTiN of TiN in the form of osbornite, observed in a range of 42°<2θ<43° and a peak value PMg.sub.2SiO.sub.4 of Mg.sub.2SiO.sub.4 in the form of forsterite, observed in a range of 35°<2θ<36° of both more than 0 and satisfying a relationship PTiN≧PMg.sub.2SiO.sub.4, in thin-film X-ray diffraction analysis; and an iron loss W.sub.17/50 of 1.0 W/kg or less.

A grain-oriented electrical steel sheet that includes a base coating with a high TiN ratio advantageous for the application of tension to the steel sheet and has excellent magnetic property is provided. The grain-oriented electrical steel sheet includes: a base coating having a peak value PTiN of TiN in the form of osbornite, observed in a range of 42°<2θ<43° and a peak value PMg.sub.2SiO.sub.4 of Mg.sub.2SiO.sub.4 in the form of forsterite, observed in a range of 35°<2θ<36° of both more than 0 and satisfying a relationship PTiN≧PMg.sub.2SiO.sub.4, in thin-film X-ray diffraction analysis; and an iron loss W.sub.17/50 of 1.0 W/kg or less.

A punching method includes: punching out a plurality of electrical steel sheets in a stacked state by a mold, wherein sheet thicknesses of the electrical steel sheets are set to be 0.35 mm or less, a Vickers hardness (test force 1 kg) of the sheets is set to be 150 to 400, and an average crystal grain size of the sheets is set to be 50 to 250 μm, a clearance of the mold is set to be 7% or more of a minimum sheet thickness of the sheet thicknesses of the electrical steel sheets and equal to or lower than 7% of a total sheet thickness of the electrical steel sheets, and a pressure that a sheet presser of the mold applies to the electrical steel sheets is set to be 0.10 MPa or more.

When a non-oriented electrical steel sheet is produced by hot rolling a slab containing, by mass %, C: not more than 0.0050%, Si: 1.5-5.0%, Mn: 0.20-3.0%, sol. Al: not more than 0.0050%, P: not more than 0.2%, S: not more than 0.0050% and N: not more than 0.0040% to form a hot rolled sheet, cold rolling the hot rolled sheet without conducting a hot band annealing and then subjecting to a finish annealing, a compositional ratio of CaO in oxide-based inclusions existing in the slab defined by CaO/(SiO.sub.2+Al.sub.2O.sub.3+CaO) is set to not less than 0.4 and/or a compositional ratio of Al.sub.2O.sub.3 defined by Al.sub.2O.sub.3/(SiO.sub.2+Al.sub.2O.sub.3+CaO) is set to not less than 0.3, and a coiling temperature in the hot rolling is set to not lower than 650° C.

When a non-oriented electrical steel sheet is produced by hot rolling a slab containing, by mass %, C: not more than 0.0050%, Si: 1.5-5.0%, Mn: 0.20-3.0%, sol. Al: not more than 0.0050%, P: not more than 0.2%, S: not more than 0.0050% and N: not more than 0.0040% to form a hot rolled sheet, cold rolling the hot rolled sheet without conducting a hot band annealing and then subjecting to a finish annealing, a compositional ratio of CaO in oxide-based inclusions existing in the slab defined by CaO/(SiO.sub.2+Al.sub.2O.sub.3+CaO) is set to not less than 0.4 and/or a compositional ratio of Al.sub.2O.sub.3 defined by Al.sub.2O.sub.3/(SiO.sub.2+Al.sub.2O.sub.3+CaO) is set to not less than 0.3, and a coiling temperature in the hot rolling is set to not lower than 650° C.