Disclosed herein are embodiments of low temperature co-fireable dielectric materials which can be used in conjunction with high dielectric materials to form composite structures, in particular for isolators and circulators for radiofrequency components. Embodiments of the low temperature co-fireable dielectric materials can be scheelite or garnet structures, for example, bismuth vanadate. Adhesives and/or glue is not necessary for the formation of the isolators and circulators.

Disclosed herein are ceramic materials, such as bismuth substituted garnets, which can have high curie temperatures and high dielectric constants. In certain implementations, indium can be incorporated into the ceramic to improve certain properties and to avoid calcium compensation. The ceramic materials disclosed herein can be particular advantageous for below resonance applications.

A composite magnetic material has a plurality of grains having a magnetic ferrite phase, grain boundaries surrounding the grains, and a plurality of nanoparticles disposed at the grain boundaries. The nanoparticles of the composite material are both magnetic and electrically insulating, having a magnetic flux density of greater than about 100 mT and an electrical resistivity of at least about 10.sup.8 Ohm-cm. Also provided is a method of making the composite material. The material is useful for making inductor cores of electronic devices.

Disclosed are embodiments of synthetic garnet materials for use in radiofrequency applications. In some embodiments, increased amounts of gadolinium can be added into specific sites in the crystal structure of the synthetic garnet by incorporating indium, a trivalent element. By including both indium and increased amounts of gadolinium, the dielectric constant can be improved. Thus, embodiments of the disclosed material can be advantageous in both above and below resonance applications, such as for isolators and circulators.

A method for producing a solid composition according to the present disclosure is a method for producing a solid composition that is used for forming a functional ceramic having a first crystal phase. The method for producing a solid composition includes: producing an oxide composed of a second crystal phase different from the first crystal phase; and mixing the oxide and an oxo acid compound.

A method of forming a composite material for use as an isolator or circulator in a radiofrequency device comprises providing a low temperature fireable outer material, the low fireable outer material having a garnet or scheelite structure, inserting a high dielectric constant inner material having a dielectric constant above 30 within an aperture in the low temperature fireable outer material, and co-firing the lower temperature fireable outer material and the high dielectric constant inner material together at temperature between 650-900° C. to shrink the low temperature fireable outer material around an outer surface of the high dielectric constant inner material to form an integrated magnetic/dielectric assembly without the use of adhesive or glue.

Disclosed are embodiments of synthetic garnet materials for use in radiofrequency applications. In some embodiments, increased amounts of gadolinium can be added into specific sites in the crystal structure of the synthetic garnet by incorporating indium, a trivalent element. By including both indium and increased amounts of gadolinium, the dielectric constant can be improved. Thus, embodiments of the disclosed material can be advantageous in both above and below resonance applications, such as for isolators and circulators.

Disclosed herein are ceramic materials, such as bismuth substituted garnets, which can have high curie temperatures and high dielectric constants. In certain implementations, indium can be incorporated into the ceramic to improve certain properties and to avoid calcium compensation. The ceramic materials disclosed herein can be particular advantageous for below resonance applications.

A ferrite composition includes main-phase particles, first sub-phase particles, second sub-phase particles, and a grain boundary. At least 10% or more of the main-phase particles contain a portion whose Zn concentrations monotonously decrease from a particle surface toward a particle central part along a length of 50 nm or more. The first sub-phase particles contain Zn.sub.2SiO.sub.4. The second sub-phase particles contain SiO.sub.2. A total area ratio of the first sub-phase particles and the second sub-phase particles is 30.5% or more.

Disclosed herein is a nonreciprocal circuit element that includes a magnetic rotator disposed between first and second ground conductors, and a permanent magnet that applies a DC magnetic field to the magnetic rotator. The magnetic rotator includes a first ferrite core having a first surface covered with the first ground conductor, a second ferrite core having a second surface covered with the second ground conductor, a first center conductor directly fixed to a third surface of the first ferrite core positioned opposite to the first surface, and a second center conductor directly fixed to a fourth surface of the second ferrite core positioned opposite to the second surface.