In a first aspect, the present invention relates to a perovskite material comprising negatively charged layers alternated with and neutralized by positively charged layers; the negatively charged layers having a general formula selected from the list consisting of: L.sub.n−1M.sub.nX.sub.3n+1, L.sub.nM.sub.nX.sub.3n+2, and L.sub.n−1M′.sub.nX.sub.3n+3, and the positively charged layers comprising: one or more organic ammonium cations independently selected from monovalent cations Q and divalent cations Q′, or a polyvalent cationic conjugated organic polymer Z, wherein Q, Q′ and Z comprise each a π-conjugated system in which at least 8 and preferably at least 10 atoms participate, L is a monovalent cation, M.sub.n are n independently selected metal cations averaging a valence of two, M′.sub.n are n independently selected metal cations averaging a valence equal to 2+2/n, X is a monovalent anion, and n is larger than 1.

A method of manufacturing a solid electrolytic capacitor, including: a step (A) of providing a conjugated conductive polymer-containing dispersion by polymerizing, in a dispersion medium containing seed particles turned into protective colloid by a polyanion or in a dispersion medium containing the polyanion, a monomer for obtaining a conjugated conductive polymer; a step (B) of preparing a dispersion containing a morpholine compound and the conjugated conductive polymer by adding the morpholine compound to the conjugated conductive polymer-containing dispersion; a step (C) of causing the dispersion to adhere to a porous anode body formed of a valve metal having a dielectric film on a surface thereof; and a step (D) of forming a solid electrolyte layer by removing the dispersion medium from the dispersion containing the morpholine compound and the conjugated conductive polymer, the dispersion adhering to the porous anode body.

An electrolytic capacitor includes an anode body, a first conductive polymer layer, and a second conductive polymer layer. The anode body includes a dielectric layer. The first conductive polymer layer covers at least a part of the dielectric layer. The second conductive polymer layer covers at least a part of the first conductive polymer layer. The first conductive polymer layer includes a first conductive polymer. The second conductive polymer layer includes a second conductive polymer. At least one of the first conductive polymer layer and the second conductive polymer layer further includes a hydroxy compound. The hydroxy compound has two or more alcoholic hydroxy groups or two or more phenolic hydroxy groups, and has a melting point ranging from 40° C. to 150° C., inclusive.

Methods of passivating surfaces, composite materials, and electronic devices including the composite materials. The composite materials can include a passivated film, such as a metal halide perovskite passivated with an organic dye. The electronic devices may include solar cells.

A solid electrolytic capacitor according to one aspect of the present disclosure includes: an anode body made of a valve metal; a dielectric layer formed on the anode body; and a solid electrolyte layer formed on the dielectric layer. The solid electrolyte layer includes: a first conductive polymer layer formed on the dielectric layer and heterogeneously doped with a monomolecular dopant; a block layer formed on the first conductive polymer layer; and a second conductive polymer layer formed on the block layer and composed of a self-doped-type conductive polymer containing a plurality of side chains containing a functional group that can be doped. The block layer blocks a migration of the self-doped-type conductive polymer from the second conductive polymer layer into the first conductive polymer layer and/or a migration of the self-doped-type conductive polymer from the second conductive polymer layer into pores of the porous anode body.

Provided is a hybrid electrolytic capacitor having large capacitance, low ESR, and superior high-frequency characteristics and high-temperature endurance. The hybrid electrolytic capacitor 1 is provided with: a cathode 10 having a cathode substrate 11 made of a valve metal, an oxide layer 12 provided on a surface of the cathode substrate 11, an inorganic conductive layer 13 provided on a surface of the oxide layer 12 and including an inorganic conductive material, and an organic conductive layer 14 provided on a surface of the inorganic conductive layer 13 and including a conductive polymer; an anode 20 having an anode substrate 21 made of a valve metal and a dielectric layer 22 provided on a surface of the anode substrate 21; and a composite electrolyte layer 30 having a solid electrolyte layer 31 containing conductive polymer particles 31a which is provided between and in contact with the organic conductive layer 14 of the cathode 10 and the dielectric layer 22 of the anode 20, and an electrolytic solution 32 filled between the conductive polymer particles 31a in the solid electrolyte layer 31.

Provided is a method for preparing a perovskite electronic device including steps of: forming an electron transport layer and a second light absorption layer including a perovskite material each independently on a first substrate and a second substrate; forming a first light absorption layer including a perovskite material on the electron transport layer; coating a solvent on the surface of the first light absorption layer and the second light absorption layer; bonding the second light absorption layer on the first light absorption layer; removing the second substrate; forming a hole transport layer on the second light absorption layer; and forming an electrode on the hole transport layer.

A solid electrolytic capacitor element includes an anode body that includes a porous part in at least a surface layer of the anode body, a dielectric layer, and a cathode part. The cathode part includes a solid electrolyte layer that covers the at least a part of the dielectric layer. The anode body includes a first part and a second part. The first part is a cathode forming part on which the solid electrolyte layer is formed, and the second part is a part on which the solid electrolyte layer is not formed. The second part includes at least an anode part including an end of the anode body opposite to the first part. The first part is sectionalized into a plurality of regions, and the first part has a groove at a boundary between adjacent regions among the plurality of regions.

A tantalum capacitor includes a tantalum body comprising a tantalum sintered body containing tantalum powder, a conductive polymer layer disposed on the tantalum sintered body and including a first filler as a non-conductive particle, and a tantalum wire. The first filler includes a core including at least one metal oxide among BaTiO.sub.3, Al.sub.2O.sub.3, SiO.sub.2 and ZrO.sub.2, and a coating film disposed on a surface of the core.

An improved electrolytic capacitor, and method of making the electrolytic capacitor, is provided. The electrolytic capacitor comprises an anode comprising a dielectric layer on the anode. A primary conductive polymer layer is on dielectric and a mordant layer on the primary conductive layer wherein the mordant layer comprises a mordant compound of Formula A; ##STR00001##
wherein:
each of R.sup.1-R.sup.6 is independently selected from H and —PO(OR.sup.7).sub.2 wherein each R.sup.7 is independently selected from H, substituted or unsubstituted alkyl of 1-20 carbons, substituted or unsubstituted aryl of 6-20 carbons or an alkylaryl of 7-21 carbons; with the proviso that at least one of R.sup.1-R.sup.6 is —PO(OH).sub.2. A secondary conductive polymer layer is on the mordant layer.