A solid electrolyte capacitor includes a sintered body formed by sintering a molded body containing metal powder; and a conductive polymer layer disposed above the sintered body. A ratio (t2/t1) of a thickness (t2) of the conductive polymer layer in an edge portion of the sintered body to a thickness (t1) of the conductive polymer layer in a central portion of the sintered body satisfies 0.35≤t2/t1≤0.9.

A capacitor that comprises a capacitor element that includes an anode that contains a dielectric formed on a sintered porous body, a solid electrolyte overlying the anode, and a cathode coating is provided. The cathode coating includes a noble metal layer (e.g., gold) overlying the solid electrolyte and a layer overlying the noble metal layer that includes sintered metal particles (e.g., silver particles).

A capacitor that comprises a capacitor element that includes an anode that contains a dielectric formed on a sintered porous body, a solid electrolyte overlying the anode, and a cathode coating is provided. The cathode coating includes a noble metal layer (e.g., gold) overlying the solid electrolyte and a layer overlying the noble metal layer that includes sintered metal particles (e.g., silver particles).

A solid electrolytic capacitor and method for making the capacitor are provided. The capacitor includes a porous anode body, an anode foil, a dielectric, a cathode, and anode and cathode terminations. The foil is disposed on a planar surface of the anode body, and both comprise a valve metal. Further, the dielectric overlies at least a portion of the anode body, and the dielectric is also formed within the anode body. The cathode overlies at least a portion of the dielectric that overlies the anode body and includes a solid electrolyte, where at least a portion of a lower surface of the foil is free of both the dielectric and the solid electrolyte. In addition, the anode termination is electrically connected to the portion of the lower surface of the foil that is free of both the dielectric and the solid electrolyte, and the cathode termination is electrically connected to the solid electrolyte.

A solid electrolytic capacitor and method for making the capacitor are provided. The capacitor includes a porous anode body, an anode foil, a dielectric, a cathode, and anode and cathode terminations. The foil is disposed on a planar surface of the anode body, and both comprise a valve metal. Further, the dielectric overlies at least a portion of the anode body, and the dielectric is also formed within the anode body. The cathode overlies at least a portion of the dielectric that overlies the anode body and includes a solid electrolyte, where at least a portion of a lower surface of the foil is free of both the dielectric and the solid electrolyte. In addition, the anode termination is electrically connected to the portion of the lower surface of the foil that is free of both the dielectric and the solid electrolyte, and the cathode termination is electrically connected to the solid electrolyte.

A solid electrolytic capacitor that contains an anode body, dielectric overlying the anode body, adhesion coating overlying the dielectric, and solid electrolyte overlying the adhesion coating. The solid electrolyte contains an inner conductive polymer layer and outer conductive polymer layer, at least one of which is formed from a plurality of pre-polymerized conductive polymer particles. Furthermore, the adhesion coating contains a discontinuous precoat layer containing a plurality of discrete nanoprojections of a manganese oxide (e.g., manganese dioxide).

A solid electrolytic capacitor that contains an anode body, dielectric overlying the anode body, adhesion coating overlying the dielectric, and solid electrolyte overlying the adhesion coating. The solid electrolyte contains an inner conductive polymer layer and outer conductive polymer layer, at least one of which is formed from a plurality of pre-polymerized conductive polymer particles. Furthermore, the adhesion coating contains a discontinuous precoat layer containing a plurality of discrete nanoprojections of a manganese oxide (e.g., manganese dioxide).

Na-rich electrolyte compositions provided herein can be used in a variety of devices, such as sodium ionic batteries, capacitors and other electrochemical devices. Na-rich electrolyte compositions provided herein can have a chemical formula of Na.sub.3OX, Na.sub.3SX, Na .sub.(3-δ) M.sub.δ/2OX and Na .sub.(3-δ) M.sub.δ/2SX wherein 0<δ<0.8, wherein X is a monovalent anion selected from fluoride, chloride, bromide, iodide, H.sup.−, CN.sup.−, BF.sub.4.sup.−, BH.sub.4.sup.−, ClO.sub.4.sup.−, CH.sub.3.sup.−, NO.sub.2.sup.−, NH.sub.2.sup.− and mixtures thereof, and wherein M is a divalent metal selected from the group consisting of magnesium, calcium, barium, strontium and mixtures thereof. Na-rich electrolyte compositions provided herein can have a chemical formula of Na .sub.(3-δ) M.sub.δ/3OX and/or Na .sub.(3-δ) M.sub.δ/3SX; wherein 0<δ<0.5, wherein M is a trivalent cation M.sup.3, and wherein X is selected from fluoride, chloride, bromide, iodide, H.sup.−, CN.sup.−, BF.sub.4.sup.−, BH.sub.4.sup.−, ClO.sub.4.sup.−, CH.sub.3.sup.−, NO.sub.2.sup.−, NH.sup.2− and mixtures thereof. Synthesis and processing methods of NaRAP compositions for battery, capacitor, and other electrochemical applications are also provided.

Na-rich electrolyte compositions provided herein can be used in a variety of devices, such as sodium ionic batteries, capacitors and other electrochemical devices. Na-rich electrolyte compositions provided herein can have a chemical formula of Na.sub.3OX, Na.sub.3SX, Na .sub.(3-δ) M.sub.δ/2OX and Na .sub.(3-δ) M.sub.δ/2SX wherein 0<δ<0.8, wherein X is a monovalent anion selected from fluoride, chloride, bromide, iodide, H.sup.−, CN.sup.−, BF.sub.4.sup.−, BH.sub.4.sup.−, ClO.sub.4.sup.−, CH.sub.3.sup.−, NO.sub.2.sup.−, NH.sub.2.sup.− and mixtures thereof, and wherein M is a divalent metal selected from the group consisting of magnesium, calcium, barium, strontium and mixtures thereof. Na-rich electrolyte compositions provided herein can have a chemical formula of Na .sub.(3-δ) M.sub.δ/3OX and/or Na .sub.(3-δ) M.sub.δ/3SX; wherein 0<δ<0.5, wherein M is a trivalent cation M.sup.3, and wherein X is selected from fluoride, chloride, bromide, iodide, H.sup.−, CN.sup.−, BF.sub.4.sup.−, BH.sub.4.sup.−, ClO.sub.4.sup.−, CH.sub.3.sup.−, NO.sub.2.sup.−, NH.sup.2− and mixtures thereof. Synthesis and processing methods of NaRAP compositions for battery, capacitor, and other electrochemical applications are also provided.

A capacitor that includes: a base material having: a substrate; a first conductive portion on at least one main surface of the substrate; and an insulating-resin layer on a surface of the first conductive portion; a plurality of fibrous conductive cores, a first end portion of each of the plurality of the fibrous conductive cores being in contact with the first conductive portion through the insulating-resin layer; a dielectric layer covering a portion of the plurality of the fibrous conductive cores exposed from the base material; a conductive polymer layer covering the dielectric layer such that gaps are provided in spaces between the plurality of the fibrous conductive cores; and a second conductive portion in contact with the conductive polymer layer at a second end portion of the plurality of the fibrous conductive cores.