A method of manufacturing high capacitance anode and cathode films of capacitors is revealed. Perform sputter deposition on a cathode aluminum foil in a vacuum chamber to form a cathode metal layer which is a titanium layer on a surface of the cathode aluminum foil. Then titanium continuously reacts with nitrogen to form cathode columnar crystal deposition on a surface of the cathode metal layer and get a cathode film. Perform sputter deposition on an anode aluminum foil in a vacuum chamber to form an anode metal layer which is a titanium layer on a surface of the anode aluminum foil. Then titanium continuously reacts with oxygen and nitrogen to form anode columnar crystal deposition on a surface of the anode metal layer and get an anode film. Next use the cathode and anode films with high capacitance to form cathode and anode electrodes of the capacitor.

Provided is a hybrid electrolytic capacitor having large capacitance, low ESR, and superior high-frequency characteristics and high-temperature endurance. The hybrid electrolytic capacitor 1 is provided with: a cathode 10 having a cathode substrate 11 made of a valve metal, an oxide layer 12 provided on a surface of the cathode substrate 11, an inorganic conductive layer 13 provided on a surface of the oxide layer 12 and including an inorganic conductive material, and an organic conductive layer 14 provided on a surface of the inorganic conductive layer 13 and including a conductive polymer; an anode 20 having an anode substrate 21 made of a valve metal and a dielectric layer 22 provided on a surface of the anode substrate 21; and a composite electrolyte layer 30 having a solid electrolyte layer 31 containing conductive polymer particles 31a which is provided between and in contact with the organic conductive layer 14 of the cathode 10 and the dielectric layer 22 of the anode 20, and an electrolytic solution 32 filled between the conductive polymer particles 31a in the solid electrolyte layer 31.

Provided is a hybrid electrolytic capacitor having large capacitance, low ESR, and superior high-frequency characteristics and high-temperature endurance. The hybrid electrolytic capacitor 1 is provided with: a cathode 10 having a cathode substrate 11 made of a valve metal, an oxide layer 12 provided on a surface of the cathode substrate 11, an inorganic conductive layer 13 provided on a surface of the oxide layer 12 and including an inorganic conductive material, and an organic conductive layer 14 provided on a surface of the inorganic conductive layer 13 and including a conductive polymer; an anode 20 having an anode substrate 21 made of a valve metal and a dielectric layer 22 provided on a surface of the anode substrate 21; and a composite electrolyte layer 30 having a solid electrolyte layer 31 containing conductive polymer particles 31a which is provided between and in contact with the organic conductive layer 14 of the cathode 10 and the dielectric layer 22 of the anode 20, and an electrolytic solution 32 filled between the conductive polymer particles 31a in the solid electrolyte layer 31.

A solid electrolytic capacitor element includes an anode body that includes a porous part in at least a surface layer of the anode body, a dielectric layer, and a cathode part. The cathode part includes a solid electrolyte layer that covers the at least a part of the dielectric layer. The anode body includes a first part and a second part. The first part is a cathode forming part on which the solid electrolyte layer is formed, and the second part is a part on which the solid electrolyte layer is not formed. The second part includes at least an anode part including an end of the anode body opposite to the first part. The first part is sectionalized into a plurality of regions, and the first part has a groove at a boundary between adjacent regions among the plurality of regions.

An electrolytic capacitor includes a capacitor element, a solid electrolyte layer, an electrolyte solution. The capacitor element has an anode foil with a dielectric layer, and a cathode foil. The solid electrolyte layer is provided between the anode foil and the cathode foil. And the capacitor element is impregnated with the electrolyte solution. The cathode foil includes a covering layer that contains at least one metal selected from titanium and nickel or a compound of the at least one metal. And the solid electrolyte layer contains a conductive polymer, a polymer dopant, and a base component.

An electrolytic capacitor includes a capacitor element, a solid electrolyte layer, an electrolyte solution. The capacitor element has an anode foil with a dielectric layer, and a cathode foil. The solid electrolyte layer is provided between the anode foil and the cathode foil. And the capacitor element is impregnated with the electrolyte solution. The cathode foil includes a covering layer that contains at least one metal selected from titanium and nickel or a compound of the at least one metal. And the solid electrolyte layer contains a conductive polymer, a polymer dopant, and a base component.

Provide is an electrolytic capacitor for a middle-to-high voltage application that is equal to or higher than 100 V which suppresses the total amount of gas to be produced in the electrolytic capacitor. The anode foil of the electrolytic capacitor includes an enlarged surface portion provided with tunnel-shape pits formed from the foil surface in the thickness direction of the foil, and a dielectric oxide film formed on the surface of the enlarged surface portion. The cathode body of the electrolytic capacitor includes a cathode foil formed of a valve acting metal, and a carbon layer formed on the cathode foil.

Provide is an electrolytic capacitor for a middle-to-high voltage application that is equal to or higher than 100 V which suppresses the total amount of gas to be produced in the electrolytic capacitor. The anode foil of the electrolytic capacitor includes an enlarged surface portion provided with tunnel-shape pits formed from the foil surface in the thickness direction of the foil, and a dielectric oxide film formed on the surface of the enlarged surface portion. The cathode body of the electrolytic capacitor includes a cathode foil formed of a valve acting metal, and a carbon layer formed on the cathode foil.

An object of the present invention is to provide an aluminum foil and an aluminum member for electrodes having good adhesiveness to an electrode material and high conductivity with the electrode material. Provided is an aluminum foil having through holes including an aluminum oxide film having a thickness of 25 nm or less on a surface of the aluminum foil, and further a hydrophilic layer on a part of a surface of the aluminum oxide film.

A cathode and an electrolytic capacitor including the cathode which can suppress production of hydrogen gas are provided. The cathode of the electrolytic capacitor includes cathode foil formed of valve action metal and a conductive layer formed on a surface of the cathode foil. A natural immersion potential of the cathode foil when immersed in an electrolyte solution is at a higher side than a natural immersion potential of reference cathode foil formed of the valve action metal with purity of 99.9%.