A method of fabricating and using a zinc negative electrode and systems thereof are described. A zinc electroplated electrode including a layer of zinc metal bonded to a surface of an electrically conductive current collector is fabricated by an electroplating process using a zinc electroplating system. The zinc electroplating system includes: a zinc metal anode, a cathode including the current collector for plating zinc thereon, and an electrolyte bath comprising zinc ions. The electroplating process bonds the zinc metal to the surface of the current collector to create the electroplated zinc electrode. The electroplated zinc electrode is used as a negative electrode in a zinc metal cell. The zinc metal cell may be a primary cell or a secondary cell.

The present disclosure relates to a lithium secondary battery containing tellurium as an additive for a positive electrode and bis (2,2,2-trifluoroethyl)ether as an additive for an electrolyte solution, which has an effect of improving the lifetime characteristic of the lithium secondary battery.

The present disclosure relates to a lithium secondary battery containing tellurium as an additive for a positive electrode and bis (2,2,2-trifluoroethyl)ether as an additive for an electrolyte solution, which has an effect of improving the lifetime characteristic of the lithium secondary battery.

An aqueous secondary battery including: a positive electrode; a negative electrode; a separator; and an aqueous electrolytic solution including water and a metal salt represented by Chemical Formula 1 A.sub.xD.sub.y and having molality of about 5 M to about 40 M wherein in Chemical Formula 1, A is at least one metal ion selected from a sodium ion, a potassium ion, a magnesium ion, a calcium ion, a strontium ion, a zinc ion, or a barium ion, D is at least one type of atomic group ion selected from Cl.sup.−, SO.sub.4.sup.2−, NO.sub.3.sup.−, ClO.sub.4.sup.−, SCN.sup.−, CF.sub.3SO.sub.3.sup.−, C.sub.4F.sub.3SO.sub.3.sup.−, (CF.sub.3SO.sub.2).sub.2N.sup.−, AlO.sub.2.sup.−, AlCl.sub.4.sup.−, AsF.sub.6.sup.−, SbF.sub.6.sup.−, BR.sub.4.sup.−, and PO.sub.2F.sub.2.sup.−, and 0<x≤2, and 0<y≤2.

An aqueous secondary battery including: a positive electrode; a negative electrode; a separator; and an aqueous electrolytic solution including water and a metal salt represented by Chemical Formula 1 A.sub.xD.sub.y and having molality of about 5 M to about 40 M wherein in Chemical Formula 1, A is at least one metal ion selected from a sodium ion, a potassium ion, a magnesium ion, a calcium ion, a strontium ion, a zinc ion, or a barium ion, D is at least one type of atomic group ion selected from Cl.sup.−, SO.sub.4.sup.2−, NO.sub.3.sup.−, ClO.sub.4.sup.−, SCN.sup.−, CF.sub.3SO.sub.3.sup.−, C.sub.4F.sub.3SO.sub.3.sup.−, (CF.sub.3SO.sub.2).sub.2N.sup.−, AlO.sub.2.sup.−, AlCl.sub.4.sup.−, AsF.sub.6.sup.−, SbF.sub.6.sup.−, BR.sub.4.sup.−, and PO.sub.2F.sub.2.sup.−, and 0<x≤2, and 0<y≤2.

Disclosed herein are aqueous rechargeable zinc batteries and cathodic materials for preparing the same. The cathodic material of these batteries comprises a redox-active triangular phenanthrenequinone-based macrocycle.

Disclosed herein are aqueous rechargeable zinc batteries and cathodic materials for preparing the same. The cathodic material of these batteries comprises a redox-active triangular phenanthrenequinone-based macrocycle.

According to one embodiment, a secondary battery is provided. The secondary battery includes: a positive electrode containing a positive electrode active material; a negative electrode; a separator arranged between the positive electrode and the negative electrode; and a first aqueous electrolyte held in at least the positive electrode. pH of the first aqueous electrolyte is more than 7. The positive electrode active material contains a lithium-containing compound that exhibits an average operating potential of less than 4.0 V based on lithium metal.

A method for determining an average oxidation state (AOS) of a redox flow battery system includes measuring a charge capacity for a low potential charging period starting from a discharged state of the redox flow battery system to a turning point of a charge voltage; and determining the AOS using the measured charge capacity and volumes of anolyte and catholyte of the redox flow battery system. Other methods can be used to determine the AOS for a redox flow battery system or use discharge voltage instead of charging voltage.

A method for determining an average oxidation state (AOS) of a redox flow battery system includes measuring a charge capacity for a low potential charging period starting from a discharged state of the redox flow battery system to a turning point of a charge voltage; and determining the AOS using the measured charge capacity and volumes of anolyte and catholyte of the redox flow battery system. Other methods can be used to determine the AOS for a redox flow battery system or use discharge voltage instead of charging voltage.