There are provided an aqueous electrolyte solution having an extended potential window, in particular, an aqueous electrolyte solution whose potential window is further wider than those exhibited by conventional concentrated aqueous electrolyte solutions, and an aqueous electrolyte solution in which the cycle characteristics can be improved. A non-aqueous electrolyte solution capable of achieving a higher energy density is provided, the non-aqueous electrolyte solution containing easily available and inexpensive materials and having further improved characteristics. One aqueous electrolyte solution of the present embodiment contains a salt of at least one selected from the group consisting of sodium, magnesium, potassium and lithium, and a chaotropic additive. One other non-aqueous electrolyte solution of the present embodiment contains a salt of at least one selected from the group consisting of sodium, magnesium, potassium and lithium, and a chaotropic additive.

There are provided an aqueous electrolyte solution having an extended potential window, in particular, an aqueous electrolyte solution whose potential window is further wider than those exhibited by conventional concentrated aqueous electrolyte solutions, and an aqueous electrolyte solution in which the cycle characteristics can be improved. A non-aqueous electrolyte solution capable of achieving a higher energy density is provided, the non-aqueous electrolyte solution containing easily available and inexpensive materials and having further improved characteristics. One aqueous electrolyte solution of the present embodiment contains a salt of at least one selected from the group consisting of sodium, magnesium, potassium and lithium, and a chaotropic additive. One other non-aqueous electrolyte solution of the present embodiment contains a salt of at least one selected from the group consisting of sodium, magnesium, potassium and lithium, and a chaotropic additive.

The present disclosure relates to fluoride ion batteries and structures of metal based electrode materials for various fluoride ion batteries. The structures of the metal based electrode materials comprise one or more shells or interfaces, enabling the electrodes to operate at room temperature with a liquid electrolyte.

The present disclosure relates to fluoride ion batteries and structures of metal based electrode materials for various fluoride ion batteries. The structures of the metal based electrode materials comprise one or more shells or interfaces, enabling the electrodes to operate at room temperature with a liquid electrolyte.

A method of fabricating and using a zinc negative electrode and systems thereof are described. A zinc electroplated electrode including a layer of zinc metal bonded to a surface of an electrically conductive current collector is fabricated by an electroplating process using a zinc electroplating system. The zinc electroplating system includes: a zinc metal anode, a cathode including the current collector for plating zinc thereon, and an electrolyte bath comprising zinc ions. The electroplating process bonds the zinc metal to the surface of the current collector to create the electroplated zinc electrode. The electroplated zinc electrode is used as a negative electrode in a zinc metal cell. The zinc metal cell may be a primary cell or a secondary cell.

A zinc ion battery includes a cathode; an anode; a separator; and an electrolyte sandwiched between the cathode and the anode. The electrolyte includes a mixture of zinc perchlorate and sodium perchlorate, and a ratio of the sodium perchlorate to zinc perchlorate is at least 30.

An electrolyte composition including: i) at least one lithium salt; ii) at least one nonaqueous solvent; and iii) at least one product from reaction of a mixture including: a) at least one diamine selected from: a1) a linear aliphatic C2 to C24 diamine; and/or a2) a cycloaliphatic C6 to C18 diamine; and/or a3) an aromatic, preferably C6 to C24, diamine; b) at least one saturated hydroxylated C3-C36 carboxylic acid; c) at least one monoacid selected from saturated linear and non-hydroxylated C2 to C18 carboxylic acids;

the composition having a viscosity measured at 23° C. ranging from 101 to 107 mPa.Math.s.

An electrolyte composition including: i) at least one lithium salt; ii) at least one nonaqueous solvent; and iii) at least one product from reaction of a mixture including: a) at least one diamine selected from: a1) a linear aliphatic C2 to C24 diamine; and/or a2) a cycloaliphatic C6 to C18 diamine; and/or a3) an aromatic, preferably C6 to C24, diamine; b) at least one saturated hydroxylated C3-C36 carboxylic acid; c) at least one monoacid selected from saturated linear and non-hydroxylated C2 to C18 carboxylic acids;

the composition having a viscosity measured at 23° C. ranging from 101 to 107 mPa.Math.s.

The present invention provides an aqueous electrolyte for use in rechargeable zinc-halide storage batteries that possesses improved stability and durability and improves zinc-halide battery performance. One aspect of the present invention provides an electrolyte for use in a secondary zinc bromine electrochemical cell comprising from about 30 wt % to about 40 wt % of ZnBr.sub.2 by weight of the electrolyte; from about 5 wt % to about 15 wt % of KBr; from about 5 wt % to about 15 wt % of KCl; and one or more quaternary ammonium agents, wherein the electrolyte comprises from about 0.5 wt % to about 10 wt % of the one or more quaternary ammonium agents.

Low-cost electrochemical energy storage devices having electrochemical cells containing zinc electrodes in aqueous electrolytes, which exhibit superior cycle performance, preferably comprise the following elements: (a) a cathode formed of manganese dioxide particles, preferably doped with at least one of magnesium, strontium, barium, calcium, and lanthanum, wherein the manganese dioxide particles preferably form at least one of (1) a delta manganese dioxide structure and (2) a todokorite manganese dioxide structure; (b) an anode formed of particles comprising zinc, wherein the particles are preferably treated with at least one of bismuth, indium, gallium, antimony, and tin; (c) a mixed ion electrolyte solution with a pH greater than or equal to three and less than or equal to seven, wherein the solution preferably comprises at least one monovalent salt and at least one divalent salt; and (d) a mesh as cathode current collector comprising at least one of titanium, stainless steel, tantalum, and niobium, wherein the mesh is preferably coated by an electrically conductive and yet oxidation resistant material comprising but not limited to carbon.