A lead-based alloy containing alloying additions of bismuth, antimony, arsenic, and tin is used for the production of doped leady oxides, lead-acid battery active materials, lead-acid battery electrodes, and lead-acid batteries.

This disclosure relates to compositions and methods for improving the performance of batteries, such as lead-acid batteries, including reviving or rejuvenating a partially or totally dead battery, by adding an amount of nonionic, ground state metal nanoparticles to the electrolyte of the battery, and optionally recharging the battery by applying a voltage. The metal nanoparticles may be gold and coral-shaped and are added to provide a concentration within the electrolyte of 100 ppb to 2 ppm or more (e.g., up to 5 ppm, 10 ppm, 25 ppm, 50 ppm, or 100 ppm). The metal nanoparticles may be added to battery electrode paste applied to the electrodes to enhance newly manufactured or remanufactured batteries.

The invention relates to a metal accumulation inhibiting and performance enhancing isolated or synthesized supplement for use in or in association with rechargeable electrochemical energy storage cells, and a system for delivering the supplement including articles of plastic, articles containing plastic, articles similar to plastic, plastic containers, apparatus, porous electrodes, liquids and electrolytes, in particular, articles, apparatus, electrodes, insolating sheets, liquids and electrolytes associated with rechargeable electrochemical energy storage cells incorporating one or more supplements. An effective amount of the supplement typically exhibits foaming of an electrolyte, providing a visual indicator of activity in attenuating metal deposition on, and thereby reducing metal accumulation on, various surfaces in the rechargeable electrochemical storage cell.

The present invention relates to a method of preparing a high-purity electrolyte solution for a vanadium redox flow battery using a catalytic reaction, and more specifically, to a method of preparing a high-purity electrolyte solution having a vanadium oxidation state of +3 to +5 from a mixture solution containing a vanadium precursor, a reducing agent, and an acidic solution, by using a catalyst. By using a catalyst and a reducing agent that does not leave impurities such as Zn.sup.2+, which are generated when preparing electrolyte solutions using an existing metal reducing agent, the high-purity electrolyte solution for a vanadium redox flow battery (VRFB) according to the present invention eliminates the need for an additional electrolysis process; does not form toxic substances during a reaction process, and thus is environmentally friendly; and is electrochemically desirable under milder process conditions than that of an existing process. In addition, the VRFB comprising the electrolyte solution prepared according to the present invention may be used to expand the utility of new renewable energy through price reduction of large-capacity energy storage devices.

[Problem to be Solved] To provide a vanadium active material solution which has a vanadium active material concentration of 2.5 M or more in a sulfuric acid solution including a dispersoid (suspensible material), can stably maintain high energy density based on the concentration, and can respond also to fast charge and discharge, and to provide a vanadium redox battery using the active material solution.

[Solution] The above problem is solved by a vanadium active material solution comprising a vanadium compound, which is an active material, as a solute and a dispersoid, wherein the total concentration of vanadium is 2.5 M or more. Here, in a negative electrolyte, the vanadium compound comprises one or both of bivalent and trivalent vanadium. In a positive electrolyte, the vanadium compound comprises one or both of quadrivalent and pentavalent vanadium. In an active material solution, the vanadium compound comprises one or both of trivalent and quadrivalent vanadium. The average diameter of the dispersoid is in the range of 1 nm or more and 100 μm or less.

A lead-based alloy containing alloying additions of bismuth, antimony, arsenic, and tin is used for the production of doped leady oxides, lead-acid battery active materials, lead-acid battery electrodes, and lead-acid batteries.

Disclosed herein is a redox flow battery (RFB). The battery generally includes: a positive electrolyte that is a first metal ion, a negative electrolyte that is a second metal ion, an ion exchange membrane positioned between the positive electrolyte and the negative electrolyte. The membrane is configured to restrict and/or prevent the passage of the first metal ion and/or the second metal ion therethrough, and is configured to maintain ionic conductivity between the positive electrolyte and the negative electrolyte.

Provided is a lead-acid battery including a negative electrode plate and a positive electrode plate. The negative electrode plate includes a negative electrode material containing graphite or carbon fiber, and the positive electrode plate includes a positive electrode material containing antimony.

The present invention relates to a redox flow battery and, more specifically, to a redox flow battery comprising an anolyte, a catholyte, and an ion exchange membrane, wherein the anolyte and the catholyte respectively comprise an electrolyte containing a Cl.sup.− ion and an active material containing a vanadium ion, and the electrolyte comprises at least one side reaction inhibitor selected from the group consisting of a metal phosphate, a metal hydrochloride and a metal sulfate.

On each negative plate (1), a non-woven fabric (2) composed of fibers of at least one material selected from a group of materials comprising glass, pulp and polyolefins comes into contact with the entire surface of the plate without being integrated with the plate. Each negative plate (1), which is in contact with the non-woven fabric (2), is contained in an envelope separator (3) comprising a microporous synthetic resin sheet, and is laminated with a positive plate (4). The non-woven fabric is manufactured through papermaking process in which glass fibers, pulp and silica powder are preferably used and dispersed in water as the main components.