A doped electrode may be manufactured by doping an active material included in an electrode with an alkali metal in a dope solution containing a first aprotic solvent and an alkali metal salt. The doped electrode may be cleaned with a cleaning solution containing a second aprotic solvent that has a boiling point lower than that of the first aprotic solvent. The cleaning solution may be controlled such that a content ratio of the first aprotic solvent in the cleaning solution is 8 vol % or lower.

The present disclosure relates to a lithium-sulfur battery cathode. The lithium-sulfur battery cathode comprises a carbon nanotube sponge and a plurality of sulfur nanoparticles. Wherein the carbon nanotube sponge comprises a plurality of micropores. The plurality of sulfur nanoparticles are uniformly distributed in the plurality of micropores. The present disclosure also relates a method for making the lithium-sulfur battery cathode and a lithium-sulfur battery using the lithium-sulfur battery cathode.

Embodiments of the present invention relate to a cathode active material, a method for manufacturing the same, and a lithium secondary battery including the same.

According to an embodiment, a cathode active material can be provided, the cathode active material comprising: a lithium metal oxide including a core and a shell disposed on a surface of the core; and a coating layer disposed on a surface of the lithium metal oxide, wherein a c value that satisfies Equation 1 and is in a range of 0.3 to 0.7, and the core and the shell have a layered crystalline structure.

c=b/a  [Equation 1]

(in Equation 1, a is a peak at 530 to 533 eV and b is a peak at 528 to 531 eV in an XPS spectrum of the coating layer)

Disclosed is a method for manufacturing a dry electrode. The method allows determination of the micro-fibrilization degree of a binder resin from the crystallinity of the binder resin. Based on this, the processing conditions of mixed powder for electrode or an electrode film may be controlled. In this manner, it is possible to check and control the processing conditions easily and efficiently. In addition, the method for manufacturing a dry electrode includes a kneading step using a kneader under a low speed and high temperature and pulverization step. Therefore, there is no problem of blocking of a flow path caused by aggregation of the ingredients, which is favorable to mass production.

Disclosed herein are a multilayer electrode and a lithium secondary battery including the same. The multilayer electrode includes an electrode current collector for transmitting electrons between an external wire and an electrode active material and three or more electrode mixture layers sequentially applied to the electrode current collector, wherein each of the electrode mixture layers includes an electrode active material and a conducting agent, and wherein the content of the conducting agent of one of adjacent electrode mixture layers that is relatively close to the current collector in the direction in which the electrode mixture layers are formed is higher than that of the conducting agent of the other of the adjacent electrode mixture layers that is relatively distant from the current collector.

A method for manufacturing an electrode having a porosity of between 20% and 60% by volume and pores with an average diameter of less than 50 nm. In the method, provision is made of a substrate and a colloidal suspension of aggregates or agglomerates of monodisperse primary nanoparticles of an active electrode material, having an average primary diameter D.sub.50 of between 2 and 100 nm, the aggregates or agglomerates having an average diameter D.sub.50 of between 50 nm and 300 nm. A layer is deposited from said colloidal suspension on the substrate. The deposited layer is then dried and consolidated to obtain a mesoporous layer. A coating of an electronically conductive material is then deposited on and inside the pores of the porous layer. Such a porous electrode can be used in lithium-ion microbatteries.

Provided is a primer composition including a thickener that contains at least one functional group selected from the group consisting of a hydroxyl group and a carboxyl group. The primer composition includes a thickener undissolved residue of 0.05 wt % or less based on the total solid weight thereof; an anode and a secondary battery including the same. A method for manufacturing the anode is also provided.

A method for fabricating an electrode for an energy storage device is provided. The method includes heating a mixture of solvent and materials for use as energy storage media; adding active material to the mixture; adding dispersant to the mixture to provide a slurry; coating a current collector with the slurry; and calendering the coating of slurry on the current collector to provide the electrode.

An electrode sheet manufacturing method includes preparing a wet powder that contains an active material and a volatile liquid, and of which a BET specific surface area is 50 cm.sup.2/g or more, performing film formation of an active material sheet by spreading the wet powder, and manufacturing an electrode sheet by disposing the active material sheet on a surface of a backing material.

A method for modifying an electrode comprising an alkali metal is disclosed, the method comprising casting a salt solution comprising at least one salt comprising an alkaline ion and a solvent on the electrode; casting a fluoropolymer solution comprising at least one fluoropolymer and a solvent on the electrode; and drying the electrode.

Also disclosed is an electrode comprising an alkali metal at least partly covered by a solid electrolyte interphase, said solid electrolyte interphase having atomic ratios of carbon, fluorine and sulfur atoms of 1 C:0.15 to 0.80 F:0.02 to 0.30 S.