Patent classifications
H01M4/043
Method for producing porous electrodes for electrochemical cells
The invention relates to a method for producing an electrochemical cell comprising at least one porous electrode (2′), the method comprising at least the following method steps: (a) providing an electrode composition in the form of a homogeneous mixture comprising (i) at least one particulate active material (3); (ii) at least one particulate binder (5); (iii) at least one particulate pore-forming agent (4); and (iv) optionally at least one conducting additive (6); (b) forming a mouldable mass from the electrode composition; (c) applying the electrode composition to at least one surface of a substrate (1) to obtain a compact electrode (2); (d) producing an electrochemical cell comprising at least one compact electrode (2) which comprises the electrode composition according to method step (a); and (e) heating the at least one compact electrode (2) to liquefy the at least one particulate pore-forming agent (4); and/or (f) bringing the compact electrode (2) into contact with at least one liquid electrolyte composition or at least one liquid constituent of an electrolyte composition for an electrochemical cell which is capable of at least partially dissolving the at least one particulate pore-forming agent (4) to obtain a porous electrode (2), wherein method steps (a), (b), (c), (d) and (e) are carried out substantially without solvents.
LITHIUM METAL COMPOSITE OXIDE, POSITIVE ELECTRODE ACTIVE SUBSTANCE FOR LITHIUM SECONDARY BATTERY, POSITIVE ELECTRODE FOR LITHIUM SECONDARY BATTERY, LITHIUM SECONDARY BATTERY, AND METHOD FOR PRODUCING LITHIUM METAL COMPOSITE OXIDE
A lithium metal composite oxide having a layered structure, including at least lithium and an element X, wherein:the element X is at least one element selected from the group consisting of Co, Mn, Fe, Cu, Ti, Mg, Al, W, Mo, Nb, Zn, Sn, Zr, Ga, V, B, Si, S and P; the lithium metal composite oxide contains single particles and satisfies all of requirements (1) to (5):(1): a volume-based 50% cumulative particle size D.sub.50 of the lithium metal composite oxide is 2 μm or more and 10 μm or less; (2): the single particles have, on at least a part of surfaces thereof, adhered fine particles, with the proviso that a maximum particle size of the adhered fine particles is smaller than a particle size of the single particles; (3): the particle size of the single particles is 0.2 to 1.5 times D.sub.50 of the lithium metal composite oxide; (4): a particle size of the adhered fine particles is 0.01 to 0.1 times the D.sub.50 of the lithium metal composite oxide; and (5): an average number of the adhered fine particles adhered per particle of the single particles is 1 or more and 30 or less as measured with respect to a range observable in an image obtained by scanning electron microscope.
NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY AND METHOD FOR MANUFACTURING SAME
This non-aqueous electrolyte secondary battery comprises an electrode body in which a first separator, a positive electrode plate, a second separator, and a negative electrode plate are layered and coiled for 10 or more turns. The electrode body includes: a flat section in which the outer peripheral surface is flat; and two curved surface sections which are disposed at both ends in a first direction of the flat section and in which the outer peripheral surface is curved. The non-aqueous electrolyte secondary battery includes: a winding-end tape that is adhered to the outermost peripheral surface of the electrode body; and a positive electrode protective tape that is adhered to a winding-start-side end section on the inner peripheral side of the positive electrode plate. The winding-end tape is disposed on one of the two curved surface sections.
MULTI-POROUS LEAD-CARBON ELECTRODE SHEETS AND METHOD FOR MAKING THEREOF AND LEAD-CARBON BATTERIES
The present invention discloses a method for making lead-carbon electrode sheets, lead-carbon electrode sheets and lead-carbon battery. The method consists of steps of oxidizing lead under low-temperature atmosphere and the oxidized lead is used as interface layer of lead-carbon coupling, and using a specialized ventilation method for the carbon to coat the lead. The interface layer of oxidized lead forms a stable interface between the carbon and the lead. Meanwhile, through controlling pressure and temperature, a multi-porous metal composite is formed and the porosity can be penetration paths for air and liquid when the multi-porous metal composite is applied. The lead-carbon composite is applied as a lead-carbon electrode sheet and is further welded as a lead-carbon electrode sheet of a lead-carbon battery. The lead-carbon battery carrying the lead-carbon electrode demonstrates Coulomb efficiency of 100% without heat loss on an unsaturated charge-discharge condition of high-efficiency charging and high-efficiency discharging.
METHOD OF MANUFACTURING A SOLID-STATE LITHIUM BATTERY AND A BATTERY MANUFACTURED BY THE METHOD
The propose method of manufacturing a solid-state lithium battery consists of preparing an anode coated with a solid-state electrolyte precursor and a cathode unit coated with solid-state electrolyte, both precursors containing a predetermined amount of a redundant water. The thus prepared anode unit and cathode unit are pressed to each other through their respective electrolyte precursor layers in a closed chamber at a predetermined elevated temperature and under a predetermined mechanical pressure, whereby an integral pre-final solid-state battery unit is formed. The manufacture of the battery is completed by inserting the prefinal product into a casing that leaves parts of the metal current collectors of the prefinal product exposed for use as a battery anode and a battery cathode.
Lithium-ion conductor
A process of synthesizing a solid state lithium ion conductor includes mechanically milling at least two precursors so as to form crystalline Li.sub.6MgBr.sub.8. For instance, the mechanical milling can be carried out using a planetary mill. Moreover, in a practical application, the precursors include LiBr and MgBr.sub.2.
Electrode mixture manufacturing method and electrode mixture
The present invention provides: an electrode mixture manufacturing method comprising the processes of introducing a first binder, an electrode active material, and a conductive material into an extruder, performing a first mixing of the first binder, the electrode active material, and the conductive material in the extruder, additionally introducing a second binder into the extruder and performing a second mixing, and yielding an electrode mixture resulting from the first mixing and the second mixing; an electrode mixture manufactured thereby; and an electrode manufacturing method using the electrode mixture.
Positive-electrode materials: methods for their preparation and use in lithium secondary batteries
A positive-electrode material for a lithium secondary battery is provided. The material includes a lithium oxide compound or a complex oxide as reactive substance. The material also includes at least one type of carbon material, and optionally a binder. A first type of carbon material is provided as a coating on the reactive substance particles surface. A second type of carbon material is carbon black. And a third type of carbon material is a fibrous carbon material provided as a mixture of at least two types of fibrous carbon material different in fiber diameter and/or fiber length. Also, a method for preparing the material as well as lithium secondary batteries including the material is provided.
ELECTROCHEMICAL BATTERY DEVICE WITH IMPROVED LIFETIME, COMPRISING IMPROVED SEALING AND ELECTRICAL CONDUCTION MEANS, AND MANUFACTURING METHOD THEREOF
A battery including a stack alternating between at least one anode and at least one cathode, a primary encapsulation system covering some of the faces of the stack, at least one anode contact member operable to make electrical contact between the stack and an external conductive element, and at least one cathode contact member operable to make an electrical contact between the stack and an external conductive element. An additional encapsulation system includes two frontal regions respectively covering a respective frontal region of the primary encapsulation system and two lateral regions which cover a respective lateral region devoid of any contact member of the primary encapsulation system. Each of the two frontal regions of the additional encapsulation system further cover the frontal ends respectively of the anode contact members and the cathode contact members. The frontal regions of the additional encapsulation system form a surface continuity with the lateral regions of the additional encapsulation system.
BATTERY HAVING AN ENCAPSULATION SYSTEM THAT IS REINFORCED AT THE CONTACT MEMBERS
Thin-film batteries having a novel encapsulation system.