A method for the preparation of an electrode comprising a substrate made of an aluminium based material, vertically aligned carbon nanotubes and an electrically conductive polymer matrix, the method comprising the following successive steps: (a) synthesising, on a substrate made of an aluminium based material, a carpet of vertically aligned carbon nanotubes according to the technique of CVD (Chemical Vapour Deposition) at a temperature less than or equal to 650° C.; (b) electrochemically depositing the polymer matrix on the carbon nanotubes from an electrolyte solution including at least one precursor monomer of the matrix, at least one ionic liquid and at least one protic or aprotic solvent. Further disclosed is the prepared electrode and a device for storing and returning electricity such as a supercapacitor comprising the electrode.

Hybrid electrodes for batteries are disclosed having a protective electrochemically active layer on a metal layer. Other hybrid electrodes include a silicon salt on a metal electrode. The protective layer can be formed directly from the reaction between the metal electrode and a metal salt in a pre-treatment solution and/or from a reaction of the metal salt added in an electrolyte so that the protective layer can be formed in situ during battery formation cycles.

Nanoparticle compositions, electrospun nonwoven material compositions, and methods of making the same are disclosed. The nanoparticles may be made by electrospinning a composition including a sacrificial polymer and first and second ion species into fibers, and decomposing at least a portion of the sacrificial polymer. The nanoparticles may include an electroactive compound. The nanoparticles may include a catalytically active compound. The nanoparticles may further be included in a composition prepared into a nonwoven material. The nonwoven material may be used to prepare battery compositions. The battery compositions may include an electrode that includes the nanoparticles.

The present invention relates to a binder composition for lithium-ion secondary battery electrodes. Recently, there is a need for a lithium-ion secondary battery which has the excellent property of accommodating an abnormal situation so that in cases when the battery has heated up abnormally or is in an abnormally high-temperature environment, the battery can lower the charge/discharge performance thereof. The present invention solves the above-mentioned problem by using, as a binder for electrodes, composite polymer particles obtained by polymerizing, in an aqueous medium, a monomer solution containing a polymer.

Methods for forming polymeric protective layers on magnesium anodes for magnesium batteries include placing a solution of electropolymerizable monomers onto all exposed surfaces of a magnesium anode, and electropolymerizing the monomers in the solution. The monomers can be glycidyl methacrylate, a salt of 3-sulfopropyl methacrylate, or a mixture of the two. Protected magnesium foam anodes for 3-D magnesium batteries have a magnesium foam electrolyte, and a polymeric coating covering all exposed surfaces of the magnesium foam electrolyte. The polymeric protective coating formed of (poly)glycidyl methacrylate, poly(3-sulfopropyl methacrylate), or a copolymer of the two.

Methods and systems for scalable production of lithium metal through electrodeposition.

This application relates to nanostructures, such as nanoparticles, having covalently cross-linked, conductive polymer shells, such as those that may be used as electrode materials for secondary batteries or other energy storage devices, and methods of making same.

Provided is method of producing graphene-embraced anode particulates for a lithium battery, the method comprising: (A) providing anode active material-decorated carbon or graphite particles, wherein the carbon or graphite particles have a diameter or thickness from 500 nm to 50 μm and the anode active material, in a form of particles or coating having a diameter or thickness from 0.5 nm to 2 μm, is bonded to surfaces of the carbon or graphite particles; and (B) embracing the anode active material-decorated carbon or graphite particles with a shell comprising multiple graphene sheets to produce the graphene-embraced anode particulates.

A positive electrode active material for an electrochemical device has a fiber shape or a grain-aggregate shape. The positive electrode active material includes an inner core part having a fiber shape or a grain-aggregate shape, and a superficial part covering at least part of the inner core part. The inner core part contains a first conductive polymer, and the superficial part contains a second conductive polymer that is different from the first conductive polymer.

Articles and methods involving electrochemical cells and/or electrochemical cell preproducts comprising passivating agents are generally provided. In certain embodiments, an electrochemical cell includes first and second passivating agents. In some embodiments, an electrochemical cell may include a first electrode comprising a first surface, a second electrode (e.g., a counter electrode with respect to the first electrode) comprising a second surface, a first passivating agent configured and arranged to passivate the first surface, and a second passivating agent configured and arranged to passivate the second surface.