Patent classifications
H01M4/364
POSITIVE ELECTRODE ACTIVE MATERIAL PARTICLE
A positive electrode active material particle with little deterioration is provided. A power storage device with little deterioration is provided. A highly safe power storage device is provided. The positive electrode active material particle includes a first crystal grain, a second crystal grain, and a crystal grain boundary positioned between the crystal grain and the second crystal grain; the first crystal grain and the second crystal grain include lithium, a transition metal, and oxygen; the crystal grain boundary includes magnesium and oxygen; and the positive electrode active material particle includes a region where the ratio of the atomic concentration of magnesium in the crystal grain boundary to the atomic concentration of the transition metal in first crystal grain and the second crystal grain is greater than or equal to 0.010 and less than or equal to 0.50.
NEGATIVE ELECTRODE MATERIAL, NEGATIVE ELECTRODE PLATE, ELECTROCHEMICAL APPARATUS, AND ELECTRONIC APPARATUS
A negative electrode material includes a silicon-based material, where a particle of the silicon-based material includes at least one recessed portion, and the recessed portion is 50 nm to 20 μm in width, and 50 nm to 10 μm in depth. The recessed structure leaves room for the silicon-based material to swell, thereby solving the problem of large volume swelling of the silicon-based material. In addition, when the silicon-based material with the recessed structure is composited with a carbon material, a conductive agent, and the like to form a negative electrode plate, small particles of the carbon material and the conductive agent are embedded into the recessed portion of the silicon-based material, solving the problem of low compacted density of the silicon-based negative electrode material with a recessed structure, and compensating for the low volumetric energy density of the recessed structure.
POSITIVE ELECTRODE MATERIAL AND PREPARATION METHOD THEREFOR, LITHIUM-ION BATTERY, AND ELECTRIC VEHICLE
A positive electrode material and a preparation method therefor, a lithium-ion battery, and an electric vehicle. The positive electrode material comprises: matrix particles, materials forming the matrix particles comprising at least one of a lithium-rich manganese-based material, lithium nickel cobalt manganese oxide, lithium nickel cobalt aluminum oxide, lithium iron phosphate, lithium manganate, lithium nickel cobalt manganese aluminate, and lithium nickel manganate; and a housing, the housing covering at least a portion of the outer surfaces of the matrix particles.
A CATHODE
Disclosed are a cathode materials suitable for an aluminium ion battery, wherein the cathode materials comprise a main group element nitride, and an oxide of a main group element or an oxide of a element in Group 1 to 13. The nitride is preferably a 2-dimensional layered material. Preferably, the ratio of the main group element nitride to the oxide is between 5:95 and 95:5 (by weight).
FLUORINE-CONTAINING POSITIVE ELECTRODE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY, AND LITHIUM SECONDARY BATTERY INCLUDING SAME
The present invention pertains to a positive electrode active material for a lithium secondary battery, the positive electrode active material having a layered structure and containing lithium, transition metals, fluorine (F), and oxygen, wherein the layered structure includes a lithium layer consisting solely of lithium and a transition metal layer consisting solely of transition metals including nickel, the nickel includes Ni.sup.3+ and Ni.sup.2+ in terms of oxidation number, and the ratio (Ni.sup.2+/Ni.sup.3+) of Ni.sup.2+ to Ni.sup.3+ increases as the fluorine content increases.
NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY
A non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and an electrolyte solution, wherein the positive electrode includes a composite oxide including lithium as a first metal, and a second metal X other than lithium; in the composite oxide, the second metal X includes Ni, Al, and Mn; the second metal X does not contain Co or the atomic ratio Co/X of Co to the second metal X is 0.02 or less; and the electrolyte solution contains a chain carboxylic acid ester having 2 to 4 carbon atoms, and a cyclic compound having a ring structure composed of 2 oxygen atoms and 3 to 5 carbon atoms.
SILICON-SILICON COMPOSITE OXIDE-CARBON COMPOSITE, METHOD FOR PREPARING SAME, AND NEGATIVE ELECTRODE ACTIVE MATERIAL COMPRISING SAME
The present invention provides a silicon-silicon composite oxide-carbon composite, a method for preparing same, and a negative electrode active material for a lithium secondary battery, comprising same. More particularly, the silicon-silicon composite oxide-carbon composite of the present invention has a core-shell structure wherein the core comprises silicon, a silicon oxide compound, and magnesium silicate, and the shell comprises a carbon layer. In addition, by having a specific range of span values through the adjustment of particle size distribution of the composite, when used as a negative electrode active material of a secondary battery, the composite can improve not only the capacity of the secondary battery but also the cycle characteristics and initial efficiency thereof.
POSITIVE ELECTRODE FOR SECONDARY BATTERY AND SECONDARY BATTERY
A positive electrode for a secondary battery including a positive electrode current collector, and a positive electrode mixture layer containing a positive electrode active material and disposed on a surface of the positive electrode current collector. The positive electrode mixture layer contains a first positive electrode active material having a compressive strength of 400 MPa or more, and a second positive electrode active material having a compressive strength of 250 MPa or less. When the positive electrode mixture layer is divided into a first region and a second region having the same thickness, the first positive electrode active material is contained more in the first region than in the second region, and the second positive electrode active material is contained more in the second region than in the first region.
POSITIVE ELECTRODE SLURRY, POSITIVE ELECTRODE MANUFACTURED USING SAME, AND LITHIUM-SULFUR BATTERY COMPRISING SAME
The present disclosure relates to a positive electrode slurry for a lithium-sulfur battery including a positive electrode active material, an electrically conductive material, a binder and a solvent, where the ratio of the average particle diameter (D.sub.50) of the positive electrode active material and the positive electrode slurry is 1.5 or less, and the phase angle at 1 Hz of the positive electrode slurry is 50° or more. The positive electrode slurry for the lithium-sulfur battery of the present disclosure exhibits excellent flowability even while having a high solid content, thereby making it possible to manufacture a positive electrode for a lithium-sulfur battery with excellent electrochemical properties and improving the productivity and economic feasibility of the manufacturing process of the positive electrode for the lithium-sulfur battery.
CATHODE STRUCTURE FOR A BATTERY AND METHOD OF FABRICATING THE SAME
A cathode structure for a battery includes a substrate having an electrically conductive surface and an electrode deposited onto the electrically conductive surface. The electrode is made of two or more electrode materials, including (i) one or more active materials, and (ii) specified weight percentage ranges of multi-walled carbon nanotubes (“MWCNTs”), or milled carbon fibers (“MCFs”), or a mixture of MWCNTs and MCFs. Using the specified weight percentage ranges, the electrode may be produced with a thickness of greater than 120 μm. Also disclosed are a slurry formulation for producing thick electrodes for a battery, and a method of fabricating a cathode structure for a battery.