A battery includes: an electrode group including an air electrode and a negative electrode that are stacked with a separator interposed therebetween; and a container housing the electrode group together with an alkaline electrolyte liquid. The air electrode includes a catalyst for an air secondary battery, and this catalyst for an air secondary battery includes a pyrochlore bismuth-ruthenium composite oxide having a full width at half maximum of a diffraction peak corresponding to a (222) face obtained by a powder X-ray diffraction method using CuKα rays as X-rays, of 0.350 deg or larger and 0.713 deg or smaller.

There is provided a positive electrode for an alkaline secondary battery and an alkaline secondary battery having good output properties and cycle life. To that end, a positive electrode (10) for alkaline secondary battery is obtained by laminating a flexible metal substrate (11) having flexibility; a primer layer (12) having conductivity provided on one or both surfaces of the substrate (11); and a positive electrode composite material layer (13) provided on the primer layer (12) and containing a positive electrode active material, a binder resin, and a first conductive material.

An electrode for batteries that does not include a metal-film-type current collector is disclosed herein. In some embodiments, the electrode comprises a composite having a core-shell structure including a core having an electrode active material, and a metal material coated on or doped in the surface of the core. A secondary battery having the electrode has increased capacity and energy density and exhibits improved lifespan characteristics.

Disclosed is an anodeless-type all-solid-state battery. The all-solid-state battery includes a plurality of recesses formed in an electrolyte layer and to be depressed from a surface of the electrolyte layer contacting an anode collector and thus serve as spaces for lithium to reversibly precipitate.

A lithium ion battery according to the present invention comprises a positive electrode, a negative electrode, a positive electrode lead that is connected to the positive electrode, an insulation tape that covers the positive electrode lead, and an electrolyte solution. The insulation tape comprises a base material layer that is mainly composed of an organic material, and a filler layer that is provided on the base material layer; the filler layer contains an oxide compound of an alkaline earth metal; and the electrolyte solution contains fluorine.

To provide a secondary battery in which a side reaction does not easily occur at an interface between a positive electrode active material and a solid electrolyte, an interface between the positive electrode active material and a positive electrode current collector, or the like even when charge and discharge are repeated. In one embodiment of the present invention, a buffer layer or a protective layer is provided on a current collector surface or between a current collector layer and an active material layer to prevent deterioration such as oxidation of the current collector. As the buffer layer or the protective layer, it is possible to use a titanium compound such as titanium oxide, titanium oxide in which nitrogen is substituted for part of oxygen, titanium nitride, titanium nitride in which oxygen is substituted for part of nitrogen, or titanium oxynitride (TiO.sub.xN.sub.y, where 0<x<2 and 0<y<1). Titanium nitride is particularly preferable because it has high conductivity and has a high capability of inhibiting oxidation.

An all-solid-state battery is provided that includes a cathode layer, an anode layer, and a solid electrolyte layer, in which a porosity of the solid electrolyte layer is equal to or less than 10%. Moreover, the batter includes a surface roughness Rz1 of the cathode layer and a surface roughness Rz2 of the anode layer, such that Rz1+Rz2≤25.

Systems and methods for water based phenolic binders for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and a pyrolyzed water-based phenolic binder. The water-based phenolic binder may include phenolic/resol type polymers crosslinked with poly(methyl vinyl ether-alt-maleic anhydride), poly(methyl vinyl ether-alt-maleic acid), and/or Poly(acrylamide-co-diallyldimethylammonium chloride) (PDADAM). The electrode coating layer may further include conductive additives. The current collector may comprise one or more of a copper, tungsten, stainless steel, and nickel foil in electrical contact with the electrode coating layer. The electrode coating layer may include more than 70% silicon. The electrode may be in electrical and physical contact with an electrolyte, where the electrolyte includes a liquid, solid, or gel. The battery electrode may be in a lithium ion battery.

A solid-state battery that includes a positive electrode layer, a negative electrode layer, and a solid electrolyte layer interposed between the positive electrode layer and the negative electrode layer, where the negative electrode layer includes a conductive additive containing a metal material having an elongated shape in a section view at 7% to 28% in area ratio with respect to the negative electrode layer.

The present disclosure describes various types of batteries, including lithium-ion batteries having an anode assembly comprising: an anode comprising a first porous ceramic matrix having pores; and a ceramic separator layer affixed directly or indirectly to the anode; a cathode; an anode-side current collector contacting the anode; and anode active material comprising lithium located within the pores or cathode active material located within the cathode; wherein, the ceramic separator layer is located between the anode and the cathode, no electrically conductive coating on the pores contacts the separator layer, and in a fully charged state, lithium active material in the anode does not contact the separator layer. Also disclosed are methods of making and methods of using such batteries.