An objective is to improve the corrosion resistance of a positive electrode grid for lead acid batteries.

Provided is a positive electrode grid for lead acid batteries, and a lead acid battery including the grid. The grid includes a lead alloy containing calcium and tin. The lead alloy has a calcium content of 0.10 mass % or less, and a tin content of 2.3 mass % or less, and a lattice constant of 4.9470 Å or less.

A bipolar storage battery is described in which, even when growth occurs in a positive electrode due to corrosion caused by sulfuric acid contained in an electrolytic solution, the electrolytic solution has difficulty penetrating an interface between the positive electrode and an adhesive and battery performance is hard to decrease. The bipolar storage battery includes a bipolar electrode including a positive electrode, a negative electrode, and a bipolar plate in which the positive electrode is provided on one surface and the negative electrode is provided on the other surface. The bipolar electrode includes a covering member configured to cover a peripheral part of an opposite surface of the positive electrode in close contact with the peripheral part, the opposite surface being opposite to a surface, of the positive electrode, bonded to the bipolar plate.

Disclosed are electrode plates for a lead acid battery. The electrode plates are formed of an electrode plate having a face, the electrode plate comprising a lead or lead alloy grid coated with an active material and the electrode plates having a porous, non-woven mat comprised of polymer fibers coating on the face of the electrode plate, as well as a method for making the coated electrode plates and lead acid batteries containing the coated electrode plates.

A lead-acid battery includes a positive electrode plate, a negative electrode plate, and an electrolyte solution. The positive electrode plate includes a positive current collector and a positive electrode material. The negative electrode plate includes a negative current collector and a negative electrode material. The positive current collector contains a lead alloy containing Ca and Sn. The content of Ca in the positive current collector is 0.2% by mass or less, and the content of Sn is 0.5% by mass or more. The negative electrode material contains a first organic expander (excluding a lignin compound) containing at least one selected from the group consisting of a unit of a monocyclic aromatic compound and a unit of a bisphenol S compound.

On each negative plate (1), a non-woven fabric (2) composed of fibers of at least one material selected from a group of materials comprising glass, pulp and polyolefins comes into contact with the entire surface of the plate without being integrated with the plate. Each negative plate (1), which is in contact with the non-woven fabric (2), is contained in an envelope separator (3) comprising a microporous synthetic resin sheet, and is laminated with a positive plate (4). The non-woven fabric is manufactured through papermaking process in which glass fibers, pulp and silica powder are preferably used and dispersed in water as the main components.

A bipolar battery (1) comprising a stack of multiple bipolar plates (9) sandwiched between two monopolar plates (6, 8) is disclosed. The bipolar plates (9) each comprise a conductive polymer core (22) and an integrally formed non-conductive polymer surround (4), a layer of cathode material (16) on a first side of the bipolar plate (9), and a layer of anode material (28) on a second, opposite side of the bipolar plate (9). The integrally formed non-conductive polymer surround (4) extends from the conductive polymer core (22) further on one side than the other, such that on one side a first recess (19) is defined for accommodating electrolyte material of the battery (1). The layers of anode material (28) and cathode material (16) are contained within a casing formed at least in part by the integrally formed non-conductive polymer surrounds (4) of all of the bipolar plates (9).

Positive active material pastes for flooded deep discharge lead-acid batteries, methods of making the same and lead-acid batteries including the same are provided. The positive active material paste includes lead oxide, a sulfate additive, and an aqueous acid. The positive active material paste contains from about 0.1 to about 1.0 wt % of the sulfate additive. Batteries using such positive active material pastes exhibit greatly improved performance over batteries with conventional positive active material pastes.

A lead-acid battery includes an electrode plate assembly, a battery case, a positive electrode strap, a negative electrode strap, a positive electrode post, a negative electrode post, a cover, and an electrolyte solution. A negative electrode bushing provided in the cover and the negative electrode post together constitute a negative electrode terminal. A maximum value of a gap between an outer circumferential surface of the negative electrode post and an inner circumferential surface of the negative electrode bushing in the negative electrode terminal is 0.5 mm or more and 2.5 mm or less. A rib is provided in a lower part of the negative electrode bushing, and a minimum value of a protrusion height of the rib is 1.5 mm or more and 4.0 mm or less. A distance between a surface of the electrolyte solution and a lowermost portion of the negative electrode bushing is 15 mm or less.

The present disclosure discloses a method for forming a lead-carbon compound interface layer on a lead-based substrate, wherein the lead-based substrate has a surface, and the method includes steps of: causing an acidic solution to contact with a carbon material and a lead-containing material to form a carbon-containing plumbate precursor having an ionic lead; and reducing the ionic lead in the carbon-containing plumbate precursor to form the lead-carbon compound interface layer on the surface.

A liquid lead storage battery includes a grid-like substrate of a positive electrode current collector that includes a frame bone forming four sides of a rectangular shape. Intermediate bones are connected to and present inward of the frame bone. At least some vertical intermediate bones present in a range between the center between a pair of vertical frame bones and the first vertical frame bone, which is the vertical frame bone on the side where a lug is absent, are first vertical intermediate bones extending from the lower to the upper frame bone sides while obliquely expanding from each other, and directly reach an upper frame bone. Angles formed by the first vertical intermediate bones and the upper frame bone on the first vertical frame bone side are less than 90°. Connection points of the first vertical intermediate bones to the upper frame bone are present only in this range.