A clad porous metal substrate for use in a metal-supported electrochemical cell, wherein a metal support layer of defined porosity is clad on top and bottom sides with a layer containing a metal and/or a metal oxide. A metal-supported electrochemical half-cell and a metal-supported electrochemical cell are also described.

An electrochemical cell comprises a first electrode, a second electrode, and a proton-conducting membrane between the first electrode and the second electrode. The first electrode comprises Pr(Co.sub.1-x-y-z, Ni.sub.x, Mn.sub.y, Fe.sub.z)O.sub.3-δ, wherein 0≤x≤0.9, 0≤y≤0.9, 0≤z≤0.9, and δ is an oxygen deficit. The second electrode comprises a cermet material including at least one metal and at least one perovskite. Related structures, apparatuses, systems, and methods are also described.

A solid oxide fuel cell includes a support of which a main component is a metal, a mixed layer that is provided on the support and includes a metallic material and a ceramics material, an intermediate layer that is provided on the mixed layer and includes an electron conductive ceramics material, and an anode that is provided on the intermediate layer and includes an oxygen ion conductive ceramics material and Ni. A ratio of a metal component in the intermediate layer is smaller than a ratio of the metallic material in the mixed layer.

A fuel cell with high productivity, high power generation performance and high durability is described, along with a gas diffusion electrode base material having a microporous layer on one side of an electrically conductive porous base material, where the electrically conductive porous base material contains carbon fiber and resin carbide and has a density of 0.25 to 0.39 g/cm.sup.3 and a pore mode diameter in a range of 30 to 50 μm. The microporous layer contains a carbonaceous powder and a fluororesin and has a surface roughness of 2.0 to 6.0 μm, a porosity of 50 to 95%, and a pore mode diameter of 0.050 to 0.100 μm.

This anode catalyst layer for a fuel cell contains electrode catalyst particles, a carbon carrier on which the electrode catalyst particles are loaded, water electrolysis catalyst particles, a proton-conducting binder, and graphitized carbon. The graphitized carbon has a bulk density of 0.50/cm.sup.3 or less.

A method for operating a fuel cell assembly, the fuel cell assembly including a fuel cell stack having a solid oxide fuel cell, the solid oxide fuel cell having an anode, a cathode, and an electrolyte, the method including: determining a temperature setpoint for the fuel cell stack, for output products of the fuel cell stack, or both; and controlling a volume of oxidant provided to the anode in response to the determined temperature setpoint to control a temperature of the fuel cell stack, a temperature of the output products of the fuel cell stack, or both.

The present invention provides a method of preparing a catalyst material, said catalyst material comprising a support material and an electrocatalyst dispersed on the support material; said method comprising the steps: i) providing a support material; then ii) 10 depositing a silicon oxide precursor on the support material; then iii) carrying out a heat treatment step to convert the silicon oxide precursor to silicon oxide; then iv) depositing said electrocatalyst or a precursor of said electrocatalyst on the support material; then v) removal of at least some of the silicon oxide.

An energy conversion device for conversion of chemical energy into electricity. The energy conversion device has a first and second electrode. A substrate is present that has a porous semiconductor or dielectric layer placed thereover. The porous semiconductor or dielectric layer can be a nano-engineered structure. A porous catalyst material is placed on at least a portion of the porous semiconductor or dielectric layer such that at least some of the porous catalyst material enters the nano-engineered structure of the porous semiconductor or dielectric layer, thereby forming an intertwining region.

A porous body including a framework having a three-dimensional network structure, the framework having a body including nickel, cobalt, a first element and a second element as constituent elements, the cobalt having a proportion in mass of 0.2 or more and 0.8 or less relative to a total mass of the nickel and the cobalt, the first element including of at least one element selected from the group including of boron, iron and calcium, the second element including of at least one element selected from the group consisting of sodium, magnesium, aluminum, silicon, potassium, titanium, chromium, copper, zinc and tin, the first and second elements together having a proportion in mass of 5 ppm or more and 50,000 ppm or less in total relative to the body of the framework.

A hydrogen electrode includes: a first layer; and a second layer located on the side of the electrolyte membrane relative to the first layer. The first layer is formed of a sintered body of a first metal and a first oxide. The second layer is formed of a sintered body of a second metal and a second oxide different from the first oxide. The first metal and the second metal each are a single metal of at least one element selected from the group consisting of Fe, Co, Ni, and Cu or an alloy of the element. The first oxide is zirconia stabilized with an oxide of at least one element selected from the group consisting of Y, Sc, Ca, and Mg. The second oxide is ceria doped with an oxide of at least one element selected from the group consisting of Sm, Gd, and Y.