A gas diffusion layer, a preparation method therefor, a membrane electrode assembly and a fuel cell. The gas diffusion layer comprises gas diffusion layer substrates (41, 42) and a microporous layer slurry coated on the gas diffusion layer substrates (41, 42). An additive that contains catechol or contains a catechol structure compound is specifically added into the microporous layer slurry, and the additive is specifically dopamine hydrochloride.

The present invention provides a micro-porous layer which provides a fuel battery having high productivity, high power generation performance, and high durability. The present invention provides a micro-porous layer including fibrous carbohydrate having a fiber diameter of 5 nm-10 μm and an aspect ratio of 10 or more. The carbohydrate has an oxygen/carbon element ratio of 0.02 or more.

A microporous layer for use in a fuel cell includes a first carbon black having carboxyl groups at a concentration less than 0.1 mmol per gram of carbon, a hydrophobic additive and a hydrophilic additive. A method for producing a membrane electrode assembly includes preparing a microporous layer ink, applying the microporous layer ink to a first side of a gas diffusion substrate, sintering the gas diffusion substrate to form a gas diffusion layer having a first side with a microporous layer, and thermally bonding the first side of the gas diffusion layer to an electrode layer. The microporous layer ink includes a suspension medium, a first carbon black having carboxyl groups at a concentration less than 0.1 mmol per gram of carbon, a hydrophobic additive and a hydrophilic additive.

A method of treating a carbon substrate, includes the successive steps of impregnating the carbon substrate with an aqueous solution containing an amorphous fluorinated copolymer of tetrafluoroethylene and of perfluoromethoxy dioxole, drying the carbon substrate at a pressure lower than the atmospheric pressure, and obtaining a carbon substrate impregnated with a fluorinated copolymer. Such a carbon substrate may be used as a gas diffusion layer in a fuel cell.

An electrode, in particular a gas diffusion electrode, for a metal-oxygen battery. To achieve an improved performance output, e.g., an improved energy density or an improved capacity, the electrode includes a porous carrier substrate on which a porous active material is situated, the electrode having a gradient of medium pore sizes between the carrier substrate and the active material. Also described is an energy store including the electrode as described.

A mixed reactant fuel cell (MRFC) including a MRFC-optimized electrocatalyst utilizing a combination of selective catalysts and selective fuel distributors.

Provided a gas diffusion layer for fuel cells, the gas diffusion layer including: a carbon substrate; and a microporous layer formed on the carbon substrate, wherein the microporous layer comprises first carbon particles having a partially graphitized structure and a water-repellent binder resin binding the first carbon particles, and the microporous layer further comprises a cerium compound, a nitrogen-doped cerium compound, nitrogen-doped second carbon particles having a partially graphitized or non-graphitized structure, or a mixture of two or more, as a radical scavenger capable of removing hydrogen peroxide generated at a fuel cell open circuit potential or a higher potential. In the membrane electrode assembly and the fuel cell each employing the gas diffusion layer having excellent durability according to one or more embodiments, chemical or electrochemical degradation may be effectively prevented over a long period of time, and thus excellent electrochemical performance may be obtained over a long period of time. This leads to an extended lifetime of the fuel cell.

The present invention provides a gas diffusion electrode including a microporous layer, characterized in that the microporous layer includes at least a first microporous layer and a second microporous layer, wherein the first microporous layer contains a first hydrophobic polymer and is located on the outermost surface on one side of the microporous layer; wherein the second microporous layer contains a second hydrophobic polymer and is located on the outermost surface of the microporous layer on the side opposite to the first microporous layer, and is located on an outermost surface of the gas diffusion electrode; and wherein the first hydrophobic polymer is a resin having a melting point lower than the melting point of the second hydrophobic polymer. The present invention provides a gas diffusion electrode for a fuel cell, in which both high performance and durability are achieved.

A multilayer structure, of use as composite diffusion layer in a proton-exchange membrane fuel cell, including at least one mat of carbon nanotubes having a unit diameter of less than or equal to 20 nm, defining at least one face of the structure, the mat of carbon nanotubes being superposed on a support based on carbon fibres. It also relates to a process for preparing such a multilayer structure and to the use thereof for an electrode of a PEMFC.

Provided are a method of forming a gas diffusion layer on carbon paper, the method being capable of balancing smoothness with air permeability and water drainage ability in the gas diffusion layer as an underlayer, as well as the carbon paper having the gas diffusion layer formed thereon used in fuel cells. The method of forming a gas diffusion layer (L2) on carbon paper (CP) used in fuel cells includes the steps of: forming a water-repellent layer (L1) on the surface of the carbon paper (CP), forming a crack (CR) in the water-repellent layer (L1), and forming the gas diffusion layer (L2) on the water-repellent layer (L1) having the crack (CR) formed therein.