A clad porous metal substrate for use in a metal-supported electrochemical cell, wherein a metal support layer of defined porosity is clad on top and bottom sides with a layer containing a metal and/or a metal oxide. A metal-supported electrochemical half-cell and a metal-supported electrochemical cell are also described.

An electrochemical cell comprises a first electrode, a second electrode, and a proton-conducting membrane between the first electrode and the second electrode. The first electrode comprises Pr(Co.sub.1-x-y-z, Ni.sub.x, Mn.sub.y, Fe.sub.z)O.sub.3-δ, wherein 0≤x≤0.9, 0≤y≤0.9, 0≤z≤0.9, and δ is an oxygen deficit. The second electrode comprises a cermet material including at least one metal and at least one perovskite. Related structures, apparatuses, systems, and methods are also described.

A solid oxide fuel cell includes a support of which a main component is a metal, a mixed layer that is provided on the support and includes a metallic material and a ceramics material, an intermediate layer that is provided on the mixed layer and includes an electron conductive ceramics material, and an anode that is provided on the intermediate layer and includes an oxygen ion conductive ceramics material and Ni. A ratio of a metal component in the intermediate layer is smaller than a ratio of the metallic material in the mixed layer.

A proton conductor contains a metal oxide that has a perovskite structure and that is represented by formula (1): A.sub.xB.sub.1-yM.sub.yO.sub.3-δ, where an element A is at least one element selected from the group consisting of Ba, Ca, and Sr, an element B is at least one element selected from the group consisting of Ce and Zr, an element M is at least one element selected from the group consisting of Y, Yb, Er, Ho, Tm, Gd, In, and Sc, δ indicates an oxygen deficiency amount, and 0.95≤x≤1 and 0<y≤0.5 are satisfied.

Herein discussed is an electrode comprising a copper or copper oxide phase and a ceramic phase, wherein the copper or copper oxide phase and the ceramic phase are sintered and are inter-dispersed with one another. Further discussed herein is a method of making a copper-containing electrode comprising: (a) forming a dispersion comprising ceramic particles and copper or copper oxide particles; (b) depositing the dispersion onto a substrate to form a slice; and (c) sintering the slice using electromagnetic radiation.

A solid oxide fuel cell (SOFC) includes a ceramic electrolyte having a thickness of 100 microns or less, an anode laminated to a first side of the electrolyte, and a cathode located on a second side of the electrolyte opposite to the first side.

A membrane electrode assembly of an electrochemical device includes a proton conductive solid electrolyte membrane and an electrode including Ni and an electrolyte material which contains as a primary component, at least one of a first compound having a composition represented by BaZr.sub.1-x1M.sup.1.sub.x1O.sub.3 (M.sup.1 represents at least one element selected from trivalent elements each having an ion radius of more than 0.720 A° to less than 0.880 A°, and 0<x.sub.1<1 holds) and a second compound having a composition represented by BaZr.sub.1-x2Tm.sub.x2O.sub.3 (0<x.sub.2<0.3 holds).

Disclosed is a method of manufacturing a solid oxide fuel cell using a calendering process. The method includes preparing a stack including an anode support layer (ASL) and an anode functional layer (AFL), calendering the stack to obtain an anode, stacking an electrolyte layer on the anode to obtain an assembly, calendering the assembly to obtain an electrolyte substrate, sintering the electrolyte substrate, and forming a cathode on the electrolyte layer of the electrolyte substrate.

The present disclosure relates to the field of materials, and in particular, to a method for preparing anti-coking Ni-YSZ anode materials for SOFC. The present disclosure provides a method for preparing a SOFC anode material, including: (1) providing the mixed powder of NiO and YSZ; (2) subjecting the mixed powder provided in step (1) to two-phase mutual solid solution treatment; (3) adjusting the particle size of the product obtained in the solid solution treatment in step (2). The SOFC anode material provided by the present disclosure could prepare the SOFC anode with good carbon deposition resistance. The anode material as a whole has the advantages of low cost, good catalytic performance, desirable electronic conductivity and well chemical compatibility with YSZ, etc. The long-term stability of cell performance is strong, and the cell preparation method is also easy to achieve industrialization.

Modular pressurized hotbox for use and substitution in a variety of pressurized electrochemical applications to include reversible solid oxide electrolyzer and fuel cells, energy storage systems, renewable fuel production, solid-state hydrogen pumping and liquefaction, and oxygen transport membranes. This is enabled by mixed electronic and ionic conducting compositions of vanadia-yttria and vanadia-calcia stabilized zirconia and a dry powder method of manufacture for ceramic core stacks.