Articles and methods including layers for protection of electrodes in electrochemical cells are provided. As described herein, a layer, such as a protective layer for an electrode, may comprise a plurality of particles (e.g., crystalline inorganic particles, amorphous inorganic particles). In some aspects, at least a portion of the plurality of particles (e.g., inorganic particles) are fused to one another. For instance, in some aspects, the layer may be formed by aerosol deposition or another suitable process that involves subjecting the particles to a relatively high velocity such that fusion of particles occurs during deposition. In some cases, the protective layer may be porous.

Articles and methods including layers for protection of electrodes in electrochemical cells are provided. As described herein, a layer, such as a protective layer for an electrode, may comprise a plurality of particles (e.g., crystalline inorganic particles, amorphous inorganic particles). In some aspects, at least a portion of the plurality of particles (e.g., inorganic particles) are fused to one another. For instance, in some aspects, the layer may be formed by aerosol deposition or another suitable process that involves subjecting the particles to a relatively high velocity such that fusion of particles occurs during deposition. In some cases, the protective layer may be porous.

A separator for a lithium-sulfur battery and a lithium-sulfur battery including the same are provided. More particularly, a separator for a lithium-sulfur battery including a porous substrate; and a coating layer present on at least one surface of the porous substrate, wherein the coating layer includes a polymer including a main chain, with a functional group having a non-covalent electron pair present in the main chain and a side chain with an aromatic hydrocarbon group present in the side chain.

Set forth herein are compositions comprising A.(LiBH.sub.4).B.(LiX).C.(LiNH.sub.2), wherein X is fluorine, bromine, chloride, iodine, or a combination thereof, and wherein 0.1≤A≤3, 0.1≤B≤4, and 0≤C≤9 that are suitable for use as solid electrolyte separators in lithium electrochemical devices. Also set forth herein are methods of making A.(LiBH.sub.4).B.(LiX).C.(LiNH.sub.2) compositions. Also disclosed herein are electrochemical devices which incorporate A.(LiBH.sub.4).B.(LiX).C.(LiNH.sub.2) compositions and other materials.

An electrochemical device includes electrode plates and a separation layer formed on a surface of an electrode plate. The separation layer includes a porous layer formed on the surface of the electrode plate. The porous layer includes nanofibers. It takes 15 seconds or less for an electrolytic solution to infiltrate into the separation layer. The separation layer exhibits functions of a separator. Therefore, the electrochemical device achieves at least a relatively high energy density without using a stand-alone separator.

An electrochemical device includes electrode plates and a separation layer formed on a surface of an electrode plate. The separation layer includes a porous layer formed on the surface of the electrode plate. The porous layer includes nanofibers. It takes 15 seconds or less for an electrolytic solution to infiltrate into the separation layer. The separation layer exhibits functions of a separator. Therefore, the electrochemical device achieves at least a relatively high energy density without using a stand-alone separator.

An electrochemical device includes an electrode plate and a separation layer on at least one surface of the electrode plate. The separation layer includes a nanofibrous porous substrate including nanofibers and polymer particles distributed in the nanofibrous porous substrate including nanofibers. A melting temperature of the polymer particles is 70° C. to 150° C.

An electrochemical device includes an electrode plate and a separation layer on at least one surface of the electrode plate. The separation layer includes a nanofibrous porous substrate including nanofibers and polymer particles distributed in the nanofibrous porous substrate including nanofibers. A melting temperature of the polymer particles is 70° C. to 150° C.

There is provided an LDH separator including a porous substrate and a layered double hydroxide (LDH)-like compound that fills up pores of the porous substrate. The LDH-like compound is a hydroxide and/or an oxide with a layered crystal structure, containing (i) Ti, Y, and optionally Al and/or Mg, and (ii) at least one additive element M selected from the group consisting of In, Bi, Ca, Sr, and Ba.

There is provided an LDH separator including a porous substrate and a layered double hydroxide (LDH)-like compound that fills up pores of the porous substrate. The LDH-like compound is a hydroxide and/or an oxide with a layered crystal structure, containing (i) Ti, Y, and optionally Al and/or Mg, and (ii) at least one additive element M selected from the group consisting of In, Bi, Ca, Sr, and Ba.