A method of fabricating and using a zinc negative electrode and systems thereof are described. A zinc electroplated electrode including a layer of zinc metal bonded to a surface of an electrically conductive current collector is fabricated by an electroplating process using a zinc electroplating system. The zinc electroplating system includes: a zinc metal anode, a cathode including the current collector for plating zinc thereon, and an electrolyte bath comprising zinc ions. The electroplating process bonds the zinc metal to the surface of the current collector to create the electroplated zinc electrode. The electroplated zinc electrode is used as a negative electrode in a zinc metal cell. The zinc metal cell may be a primary cell or a secondary cell.

A negative electrode for an alkaline battery cell which includes zinc-based particles, wherein less than 20% of the zinc-based particles, by weight relative to the total zinc in the electrode, have a particle size of greater than about 150 micrometers, is provided. An alkaline electrochemical cell that includes the negative electrode and a method for reducing the gassing of the electrochemical cell is also provided.

Disclosed is an electrolyte for a redox flow battery including at least one additive selected from the group consisting of a taurine compound and an amino acid compound. Thus, it is possible to provide an electrolyte for a redox flow battery which may have high solubility of active materials, be stable at high temperature or high pH, and show excellent electrochemical properties. In addition, when the electrolyte for a redox flow battery includes a nitrogen (N)-containing organic molecule having high redox activity as an active material, it is possible to realize a high-efficiency demetallized redox flow battery capable of solving the problems of dendrite formation or irreversible precipitation fundamentally.

A method of fabricating and using a zinc negative electrode and systems thereof are described. A zinc electroplated electrode including a layer of zinc metal bonded to a surface of an electrically conductive current collector is fabricated by an electroplating process using a zinc electroplating system. The zinc electroplating system includes: a zinc metal anode, a cathode including the current collector for plating zinc thereon, and an electrolyte bath comprising zinc ions. The electroplating process bonds the zinc metal to the surface of the current collector to create the electroplated zinc electrode. The electroplated zinc electrode is used as a negative electrode in a zinc metal cell. The zinc metal cell may be a primary cell or a secondary cell.

Nickelate cathode materials are provided, wherein said cathode material has an X-ray diffraction (XRD) pattern comprising a first peak from about 40.0-41.6 2Θ, and a second peak from about 62.6-63.0 2Θ. Methods of preparing such cathode materials are also provided. Alkaline electrochemical cells comprising said cathode materials are also provided.

An all-solid battery includes a multilayer structure that includes pairs of positive electrode layers and pairs of negative electrode layers, first solid electrolyte layers, second solid electrolyte layers, and third solid electrolyte layers, the pairs of positive electrode layers and the pairs of negative electrode layers being alternately stacked, each of the first solid electrolyte layers being interposed between each of the pairs of positive electrode layers, each of the second solid electrolyte layers being interposed between each of the pairs of negative electrode layers, each of the third solid electrolyte layers being interposed between the positive electrode layer and the negative electrode layer, wherein a thickness of the third solid electrolyte layer is different from at least one of a thickness of the first electrolyte layer and a thickness of the second electrolyte layer.

Alkaline electrochemical cells are provided, wherein an organic additive is included in at least one component of the cell in order to increase electron discharge of the cathode, so as to improve the specific capacity of the cell. Methods for preparing such cells are also provided.

An electrochemical battery cell comprising an anode having a primary anode active material, a cathode, and an ion-conducting electrolyte, wherein the cell has an initial output voltage, Vi, measured at 10% depth of discharge (DoD), selected from a range from 0.3 volts to 0.8 volts, and a final output voltage Vf measured at a DoD no greater than 90%, wherein a voltage variation, (Vi−Vf)/Vi, is no greater than ±10% and the specific capacity between Vi and Vf is no less than 100 mAh/g or 200 mAh/cm.sup.3 based on the cathode active material weight or volume, and wherein the primary anode active material is selected from lithium (Li), sodium (Na), potassium (K), magnesium (Mg), aluminum (Al), zinc (Zn), titanium (Ti), manganese (Mn), iron (Fe), vanadium (V), cobalt (Co), nickel (Ni), a mixture thereof, an alloy thereof, or a combination thereof.

An electrochemical battery cell comprising an anode having a primary anode active material, a cathode, and an ion-conducting electrolyte, wherein the cell has an initial output voltage, Vi, measured at 10% depth of discharge (DoD), selected from a range from 0.3 volts to 0.8 volts, and a final output voltage Vf measured at a DoD no greater than 90%, wherein a voltage variation, (Vi−Vf)/Vi, is no greater than ±10% and the specific capacity between Vi and Vf is no less than 100 mAh/g or 200 mAh/cm.sup.3 based on the cathode active material weight or volume, and wherein the primary anode active material is selected from lithium (Li), sodium (Na), potassium (K), magnesium (Mg), aluminum (Al), zinc (Zn), titanium (Ti), manganese (Mn), iron (Fe), vanadium (V), cobalt (Co), nickel (Ni), a mixture thereof, an alloy thereof, or a combination thereof.

An alkaline electrochemical cell has a central cathode having a corresponding cathode current collector electrically connected with a positive terminal of the electrochemical cell. The cathode current collector has a tubular shape, such as a cylindrical shape or rectangular shape, extending parallel with the length of the central cathode. The cathode current collector is embedded within the central cathode, such as at a medial point of a radius of the central cathode, thereby minimizing the distance between the cathode current collector and any portion of the central cathode, thereby increasing the mechanical strength of the cathode and facilitating charge transfer to the cathode current collector.