An object of the present disclosure is to provide a secondary battery system that functions at high voltage. The present disclosure attains the object by providing a secondary battery system comprising: a fluoride ion battery including a cathode active material layer, an anode active material layer, and an electrolyte layer formed between the cathode active material layer and the anode active material layer; and a controlling portion that controls charging and discharging of the fluoride ion battery; wherein the cathode active material layer contains a cathode active material with a crystal phase that has a Perovskite layered structure and is represented by A.sub.n+1B.sub.nO.sub.3n+1-αF.sub.x (A comprises at least one of an alkali earth metal element and a rare earth element; B comprises at least one of Mn, Co, Ti, Cr, Fe, Cu, Zn, V, Ni, Zr, Nb, Mo, Ru, Pd, W, Re, Bi, and Sb; “n” is 1 or 2; “α” satisfies 0≦α≦3.5; and “x” satisfies 0≦x≦5.5); and the controlling portion controls charging so that a value of F/B in the cathode active material becomes more than 2/n that is in an over-charged state.

The main object of the present invention is to provide an active material that has a favorable cycle property. The present invention achieves the object by providing an active material to be used for a fluoride ion battery comprising a crystal phase having a layered perovskite structure, and represented by A.sub.n+1B.sub.nO.sub.3n+1−αF.sub.x (A is composed of at least one of an alkaline earth metal element and a rare earth element; B is composed of at least one of Mn, Co, Ti, Cr, Fe, Cu, Zn, V, Ni, Zr, Nb, Mo, Ru, Pd, W, Re, Bi, and Sb; “n” is 1 or 2; “α” satisfies 0≦α≦2; and “x” satisfies 0≦x≦2.2).

A main object of the present disclosure is to provide a fluoride ion battery having a high charge-discharge potential. The present disclosure achieves the object by providing a fluoride ion battery comprising a cathode active material layer, an anode active material layer, and an electrolyte layer formed between the cathode active material layer and the anode active material layer, and the cathode active material layer includes a cathode active material having a composition represented by Cu.sub.xS, wherein 1x2.

A main object of the present disclosure is to provide a fluoride ion battery in which reduction decomposition of a solid electrolyte is inhibited. The present disclosure achieves the object by providing a fluoride ion battery, comprising a cathode layer, an anode layer, and a solid electrolyte layer formed between the cathode layer and the anode layer; wherein the anode layer contains an anode active material having a composition represented by La.sub.(1-x)Sn.sub.xF.sub.(3-x), in which 0.1x0.8; and the solid electrolyte layer contains a solid electrolyte including a crystal phase of a Tysonite structure.

The main object of the present invention is to provide an active material that has a favorable cycle property. The present invention achieves the object by providing an active material to be used for a fluoride ion battery comprising a crystal phase having a layered perovskite structure, and represented by A.sub.n+1B.sub.nO.sub.3n+1F.sub.x (A is composed of at least one of an alkaline earth metal element and a rare earth element; B is composed of at least one of Mn, Co, Ti, Cr, Fe, Cu, Zn, V, Ni, Zr, Nb, Mo, Ru, Pd, W, Re, Bi, and Sb; n is 1 or 2; satisfies 02; and x satisfies 0x2.2).

The invention concerns ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention is comprised of an amide or one of its salts, including an anionic portion combined with at least one cationic portion M.sup.+m in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO.sup.+, an ammonium NH.sub.4.sup.+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic portion matches the formula R.sub.FSO.sub.xN.sup.?Z, where R.sub.F is a perflourinated group, x is 1 or 3, and Z is an electroattractive substituent. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorants and the catalysis of various chemical reactions.

A main object of the present disclosure is to provide a fluoride ion battery in which reduction decomposition of a solid electrolyte is inhibited. The present disclosure achieves the object by providing a fluoride ion battery, comprising a cathode layer, an anode layer, and a solid electrolyte layer formed between the cathode layer and the anode layer; wherein the anode layer contains an anode active material having a composition represented by La.sub.(1-x)Sn.sub.xF.sub.(3-x), in which 0.1x0.8; and the solid electrolyte layer contains a solid electrolyte including a crystal phase of a Tysonite structure.

A main object of the present disclosure is to provide a fluoride ion battery having a high charge-discharge potential. The present disclosure achieves the object by providing a fluoride ion battery comprising a cathode active material layer, an anode active material layer, and an electrolyte layer formed between the cathode active material layer and the anode active material layer, and the cathode active material layer includes a cathode active material having a composition represented by Cu.sub.xS, wherein 1x2.

An object of the present disclosure is to provide a secondary battery system that functions at high voltage. The present disclosure attains the object by providing a secondary battery system comprising: a fluoride ion battery including a cathode active material layer, an anode active material layer, and an electrolyte layer formed between the cathode active material layer and the anode active material layer; and a controlling portion that controls charging and discharging of the fluoride ion battery; wherein the cathode active material layer contains a cathode active material with a crystal phase that has a Perovskite layered structure and is represented by A.sub.n+1B.sub.nO.sub.3n+1-F.sub.x (A comprises at least one of an alkali earth metal element and a rare earth element; B comprises at least one of Mn, Co, Ti, Cr, Fe, Cu, Zn, V, Ni, Zr, Nb, Mo, Ru, Pd, W, Re, Bi, and Sb; n is 1 or 2; satisfies 03.5; and x satisfies 0x5.5); and the controlling portion controls charging so that a value of F/B in the cathode active material becomes more than 2/n that is in an over-charged state.