An alkaline battery has a positive electrode mixture containing manganese dioxide and a conductive material filling a tubular positive electrode can that is closed at one end. A negative electrode mixture containing a zinc powder filling on an inner peripheral side of a separator is disposed on an inside of the positive electrode mixture. The negative electrode mixture contains zinc particles with a granularity of 75 μm or less at 25 to 40 mass %. The positive electrode mixture has a plurality of tubular pellets stacked inside the positive electrode can coaxially with the positive electrode can. A sum s of lengths of gaps between the pellets is set at 1 to 14% with respect to a sum d of lengths of the pellets. Thus, a sufficient amount of the electrolyte is held in the gaps and between the pellets in the positive electrode.

The present disclosure provides an electrochemical storage cell including a battery. The battery includes an alkali metal anode having an anode Fermi energy, an electronically insulating, amorphous, dried solid electrolyte able to conduct alkali metal, having the general formula A.sub.3-xH.sub.xOX, in which 0≦x≦1, A is the alkali metal, and X is at least one halide, and a cathode including a cathode current collector having a cathode Fermi energy lower than the anode Fermi energy. During operation of the electrochemical storage cell, the alkali metal plates dendrite-free from the solid electrolyte onto the alkali metal anode. Also during operation of the electrochemical storage cell, the alkali metal further plates on the cathode current collector.

An example composition is disclosed. For example, the composition includes a ultra-violet (UV) curable mixture of water, an acid, a phosphine oxide with one or more photoinitiators, a water miscible polymer, a salt, and a neutralizing agent. The composition can be used to form an electrolyte layer that can be cured in the presence of air when printing the thin-film battery.

A voltage source includes two electrically conductive terminals (101, 102) with an electrolyte (103) between them. Said electrolyte (103) is a mixture in which the main component is ash produced in a power plant or an incineration plant.

The disclosure relates to a metal electrode or current collector for an energy storage device. The surface of the electrode or the current collector includes multiple blind hole-like recesses spaced apart from each other. The surface structured in this way is coated with a solid polymer electrolyte. The recesses are filled with the solid polymer electrolyte, as well as a primary or secondary energy storage device including the same.

An electrochemical cell having a composite alkali ion-conductive electrolyte membrane. Generally, the cell includes a catholyte compartment and an anolyte compartment that are separated by the composite alkali ion-conductive electrolyte membrane. The composite electrolyte membrane includes a layer of alkali ion-conductive material and one or more layers of alkali intercalation compound which is chemically stable upon exposure to a chemically reactive anolyte solution or catholyte solution thereby protecting the layer of alkali ion-conductive material from unwanted chemical reaction. The layer of alkali intercalation compound conducts alkali ions. The cell may operate and protect the alkali ion-conductive material under conditions that would be adverse to the material if the intercalation compound were not present. The composite membrane may include a cation conductor layer having additional capability to protect the composite electrolyte membrane from adverse conditions.

An electrochemical device is claimed and disclosed, including a method of manufacturing the same, comprising an environmentally sensitive material, such as, for example, a lithium anode; and a plurality of alternating thin metallic and ceramic, blocking sub-layers. The multiple metallic and ceramic, blocking sub-layers encapsulate the environmentally sensitive material. The device may include a stress modulating layer, such as for example, a Lipon layer between the environmentally sensitive material and the encapsulation layer.

A multi-faceted zinc-air electrochemical cell design holistically leverages interactions between components, especially with respect to conductive carbons from differing sources, lamination and the resulting impact it has on the air electrode's surface and other additives that impact the relative hydrophilicity of the membrane and/or performance of the anode, to improve the overall reliability and performance of the resulting battery.

A method for the formation of lithium includes a layer on a substrate using an atomic layer deposition method. The method includes the sequential pulsing of a lithium precursor through a reaction chamber for deposition upon a substrate. Using further oxidizing pulses and or other metal containing precursor pulses, an electrolyte suitable for use in thin film batteries may be manufactured.

The present disclosure relates to a lithium ion-conducting glass ceramic which comprises a residual glass phase that is also ion-conducting, a process for the production thereof as well as its use in a battery. The glass ceramic according to the present disclosure comprises a main crystal phase which is isostructural to the NaSICon crystal phase, wherein the composition can be described with the following formula: Li.sub.1+x−yM.sub.y.sup.5+M.sub.x.sup.3+M.sub.2−x−y.sup.4+(PO.sub.4).sub.3, wherein x is greater than 0 and at most 1, as well as greater than y. Y may take values of between 0 and 1. Here, the following boundary condition has to be fulfilled: (1+x−y)>1. Here, M represents a cation with the valence of +3, +4 or +5. M.sup.3+ is selected from Al, Y, Sc or B, wherein at least Al as trivalent cation is present. Independently thereof, M.sup.4+ is selected from Ti, Si or Zr, wherein at least Ti as tetravalent cation is present. Independently thereof, M.sup.5+ is selected from Nb, Ta or La.