A solid-state rechargeable 3D microbattery is provided that has improved power density, energy density, and cycle lifetimes. These improvements are afforded by providing a solid-state electrolyte that is composed of crystalline Li.sub.1+xAl.sub.xTi.sub.2x(PO.sub.4).sub.3, wherein x is from 0 to 2. The solid-state electrolyte that is composed of crystalline Li.sub.1+xAl.sub.xTi.sub.2x(PO.sub.4) has a high ionic conductivity (which is greater than 10.sup.4 Siemens/cm) as well as high chemical stability.

A main object of the present disclosure is to provide an all solid state battery wherein interface resistance between a current collector and an active material layer is low. In the present disclosure, the above object is achieved by providing an all solid state battery comprising: an electrode including a current collector, an electron conductive layer, and an active material layer, in this order, and a solid electrolyte layer formed on the active material layer side of the electrode, and the electron conductive layer is an agglutinate of metal particles or a metal foil, and electron conductivity of the electron conductive layer is 110.sup.3 S/cm or more at 25 C.

Semi-solid electrolyte compositions are disclosed. The semi-solid electrolyte compositions contain a glyme or mixture of glymes, a lithium salt(s), and a polymeric complexing agent(s).

A lithium battery as a secondary battery includes a positive electrode composite material containing a solid electrolyte and a positive electrode active material containing lithium, a negative electrode as an electrode provided at one face of the positive electrode composite material, and a current collector provided at another face of the positive electrode composite material, wherein the solid electrolyte is a garnet-type fluorine-containing lithium composite metal oxide that is represented by the following compositional formula (1) or (2) and that conducts lithium.

(Li.sub.73xGa.sub.x) (La.sub.3yNd.sub.y)Zr.sub.2O.sub.12zF.sub.z (1)

(Li.sub.73x+yGa.sub.x) (La.sub.3yCa.sub.y) Zr.sub.2O.sub.12zF.sub.z (2)

Provided that 0.1x1.0, 0<y0.2, and 0<z1.0.

A water-activated power generating device comprising a silicon slice having a cut, a first water storage element, and a fixing ring sandwiched by the silicon slice and the first water storage element and having an inner space. The water-activated power generating device further comprises a conductive rod penetrating the silicon slice, the fixing ring, and the first water storage element. The water-activated power generating device further comprises an electrode structure having a hollow cylinder shape and an isolation film disposed adjacent to an inner surface of the electrode structure. Electrolytic powder is disposed in a space between the isolation layer and the conductive rod; and a bottom conductive plate is disposed at the bottom of the electrode structure and electrically connected to the inner surface of the electrode structure.

A composition for forming a lithium reduction resistant layer includes a solvent, and a lithium compound, a lanthanum compound, a zirconium compound, and a compound containing a metal M, each of which shows solubility in the solvent, and in which with respect to the stoichiometric composition of a compound represented by the general formula (I), the lithium compound is contained in an amount 1.05 times or more and 2.50 times or less, the lanthanum compound and the zirconium compound are contained in an amount 0.70 times or more and 1.00 times or less, and the compound containing a metal M is contained in an equal amount.

Li.sub.7-xLa.sub.3(Zr.sub.2-x,M.sub.x)O.sub.12(I)

A lithium oxygen or air battery (80) is disclosed having two halves (81) that are joined together along their edges. Each battery half (81) has a carbon cloth or mesh cathode current collector (82), a cathode (83), a cathode terminal (84), an anode (85), an anode current collector, anode terminal (88) and a solid separator (87). The cathode includes randomly distributed carbon fibers throughout. The manufacturing of the cathode includes embedding a carbon cloth between two layers of cathode material in a slurry state

A lithium oxygen or air battery (80) is disclosed having two halves (81) that are joined together along their edges. Each battery half (81) has a carbon cloth or mesh cathode current collector (82), a cathode (83), a cathode terminal (84), an anode (85), an anode current collector, anode terminal (88) and a solid separator (87). The cathode includes randomly distributed carbon fibers throughout. The manufacturing of the cathode includes embedding a carbon cloth between two layers of cathode material in a slurry state.

A water-activated power generating device comprising a silicon slice having a cut, a first water storage element, and a fixing ring sandwiched by the silicon slice and the first water storage element and having an inner space. The water-activated power generating device further comprises a conductive rod penetrating the silicon slice, the fixing ring, and the first water storage element. The water-activated power generating device further comprises an electrode structure having a hollow cylinder shape and an isolation film disposed adjacent to an inner surface of the electrode structure. Electrolytic powder is disposed in a space between the isolation layer and the conductive rod; and a bottom conductive plate is disposed at the bottom of the electrode structure and electrically connected to the inner surface of the electrode structure.

A laminate-type power storage element is configured of an exterior body that is formed in a flat bag shape by welding a first laminated film and a second laminated film by thermocompression bonding, and an electrode body that is sealed inside the exterior body, the electrode body having a sheet-shaped positive electrode and a sheet-shaped negative electrode. The first laminated film and the second laminated film respectively includes a first resin layer that has a property of transmitting a laser beam, a metal foil that is layered to the first resin layer, and a second resin layer is layered to the metal foil and has a thermal weldability.