Supplemental lithium can be used to stabilize lithium ion batteries with lithium rich metal oxides as the positive electrode active material. Dramatic improvements in the specific capacity at long cycling have been obtained. The supplemental lithium can be provided with the negative electrode, or alternatively as a sacrificial material that is subsequently driven into the negative electrode active material. The supplemental lithium can be provided to the negative electrode active material prior to assembly of the battery using electrochemical deposition. The positive electrode active materials can comprise a layered-layered structure comprising manganese as well as nickel and/or cobalt.

A lithium-ion cell includes two working electrodes which are located opposite one another and have different polarities and between which a separator which electrically insulates the working electrodes with respect to one another and is permeable to lithium ions is arranged in an electrolyte space. A lithium-containing reservoir electrode is in contact with the electrolyte space in such a way that electronic isolation is provided and lithium ions are exchanged, wherein by way of a measuring and control circuit which connects the reservoir electrode to at least one of the working electrodes a voltage can be measured between the reservoir electrode and the working electrode and a voltage can be applied between the reservoir electrode and the working electrode. The reservoir electrode is of porous design and is arranged between two insulation layers of the separator which provide electronic isolation and are permeable to lithium ions.

A lithium-ion battery cell includes at least two working electrodes, each including an active material, an inert material, an electrolyte and a current collector, a first separator region arranged between the at least two working electrodes to separate the at least two working electrodes so that none of the working electrodes are electronically connected within the cell, an auxiliary electrode including a lithium reservoir, and a second separator region arranged between the auxiliary electrode and the at least two working electrodes to separate the auxiliary electrode from the working electrodes so that none of the working electrodes is electronically connected to the auxiliary electrode within the cell.

Supplemental lithium can be used to stabilize lithium ion batteries with lithium rich metal oxides as the positive electrode active material. Dramatic improvements in the specific capacity at long cycling have been obtained. The supplemental lithium can be provided with the negative electrode, or alternatively as a sacrificial material that is subsequently driven into the negative electrode active material. The supplemental lithium can be provided to the negative electrode active material prior to assembly of the battery using electrochemical deposition. The positive electrode active materials can comprise a layered-layered structure comprising manganese as well as nickel and/or cobalt.

Battery designs are provided that exhibit commercially suitable cycling properties for consumer electronics with silicon based active materials in the electrodes. The batteries can have stacked or wound electrodes and suitable electrode designs.

Battery designs are provided that exhibit commercially suitable cycling properties for consumer electronics with silicon based active materials in the electrodes. The batteries can have stacked or wound electrodes and suitable electrode designs.

Supplemental lithium can be used to stabilize lithium ion batteries with lithium rich metal oxides as the positive electrode active material. Dramatic improvements in the specific capacity at long cycling have been obtained. The supplemental lithium can be provided with the negative electrode, or alternatively as a sacrificial material that is subsequently driven into the negative electrode active material. The supplemental lithium can be provided to the negative electrode active material prior to assembly of the battery using electrochemical deposition. The positive electrode active materials can comprise a layered-layered structure comprising manganese as well as nickel and/or cobalt.

A Li-ion battery cell, among other materials, components, and techniques, is provided that includes ion-permeable anode and cathode electrodes, an electrolyte ionically coupling the anode and the cathode, a separator electrically separating the anode and the cathode, and a sacrificial, high-capacity Li composition for providing Li to at least one of the electrodes.

The present invention relates to a method for controlling a regeneration procedure of a lithium battery cell (1) which comprises an anode (2), a cathode (3) and the regeneration electrode (4). The method comprises: detecting a current availability of cyclable lithium in the anode (2); detecting a current availability of cyclable lithium in the cathode (3); passing a first current (I.sub.1) between the anode (2) and the regeneration electrode (4) until the actual availability of cyclable lithium in the anode (2) corresponds to a targeted availability of cyclable lithium in the anode (2); and passing a second current (I2) between the cathode (3) and the regeneration electrode (4) until the current availability of cyclable lithium in the cathode (3) corresponds to a targeted availability of cyclable lithium in the cathode (3).

A Li-ion battery cell, among other materials, components, and techniques, is provided that includes ion-permeable anode and cathode electrodes, an electrolyte ionically coupling the anode and the cathode, a separator electrically separating the anode and the cathode, and a sacrificial, high-capacity Li composition for providing Li to at least one of the electrodes.