Disclosed is a carbon dioxide utilization system capable of recharging and undergoing reactions. The system includes a cathode unit provided with a first aqueous solution accommodated in a first accommodation space, and a cathode at least a part of which is submerged in the first aqueous solution; an anode unit provided with an alkaline second aqueous solution accommodated in a second accommodation space, and a metal anode at least a part of which is submerged in the second aqueous solution; and a connection unit provided with a connection channel connecting the first and second accommodation spaces in open communication, and a porous ion transfer member, disposed in the connection channel, for blocking the movement of the first and second aqueous solutions but allowing the movement of ions.

Membrane-based hydrogen purifiers having graphite frame members. The purifiers include a hydrogen-separation membrane module with at least one membrane cell containing at least one hydrogen-selective membrane, which includes a permeate face and an opposed mixed gas face, and a fluid-permeable support structure that physically contacts and supports at least a central region of the permeate face. The membrane cell further includes a permeate-side frame member and a mixed gas-side frame member. The permeate-side frame member is interposed between the hydrogen-selective membrane and the fluid-permeable support structure to physically contact a peripheral region of the permeate face and a peripheral region of the fluid-permeable support structure. The mixed gas-side frame member physically contacts a peripheral region of the mixed gas face. At least one of the permeate-side frame member and the mixed gas-side frame member is a graphite frame member.

Aspects of methods and systems to reduce degradation of a fuel cell (110) during start-up and shut-down cycles are disclosed. An anode exhaust stream (201′) is periodically directed via fluid communication through an oxygen capture media (86). After shut-down of the fuel cell and before or during start-up said media (86) removes oxygen in the anode exhaust stream. Periodically, heating the oxygen capture media (86) is employed to purge the oxygen collected and regenerate the media.

Aspects of methods and systems to reduce degradation of a fuel cell (110) during start-up and shut-down cycles are disclosed. An anode exhaust stream (201′) is periodically directed via fluid communication through an oxygen capture media (86). After shut-down of the fuel cell and before or during start-up said media (86) removes oxygen in the anode exhaust stream. Periodically, heating the oxygen capture media (86) is employed to purge the oxygen collected and regenerate the media.

Systems and methods are provided for capturing gas byproducts of a fuel cell system, such as nitrogen. Instead of dispelling the gas byproducts, a byproduct management system can engage in selective isolation, compression, and storage of the gas byproducts in various storage tanks. The compression and storage of the gas byproducts can be effectuated using excess energy, e.g., regenerative energy.

Systems and methods are provided for capturing gas byproducts of a fuel cell system, such as nitrogen. Instead of dispelling the gas byproducts, a byproduct management system can engage in selective isolation, compression, and storage of the gas byproducts in various storage tanks. The compression and storage of the gas byproducts can be effectuated using excess energy, e.g., regenerative energy.

An anode separator for use in an electrochemical hydrogen pump includes a first anode gas flow channel having a serpentine shape, a second anode gas flow channel having a serpentine shape, and an anode gas discharge manifold into which an anode gas discharged from each of the first anode gas flow channel and the second anode gas flow channel flow. The first anode gas flow channel and the second anode gas flow channel are provided in a first region and a second region, respectively, that are divided from each other by a predetermined line parallel to a direction of the anode gas that flows into the anode gas discharge manifold.

A fuel cell system includes a fuel cell stack, a fuel inlet conduit configured to provide a fuel to a fuel inlet of the fuel cell stack, an electrochemical pump separator containing an electrolyte, a cathode, and a carbon monoxide tolerant anode, a fuel exhaust conduit that operatively connects a fuel exhaust outlet of the fuel cell stack to an anode inlet of the electrochemical pump separator, and a product conduit which operatively connects a cathode outlet of the electrochemical pump separator to the fuel inlet conduit.

A system for generating electricity by pyrolyzing organic materials and feeding the pyrolysis fluid to a battery of fuel-cells. The system includes a pyrolysis reactor receiving organic materials and producing pyrolysis fluid. The fluid pyrolysis is then separated into a plurality of sub-mixtures, each provided via a respective separator output. A plurality of fuel-cell devices for generating electricity using different technologies are each coupled to a respective separator output. A controller controls the pyrolysis reactor, the separator device, and the plurality of fuel-cell devices according to a signal representing a demand for electric power, a signal representing cost of operating at least one of the pyrolysis reactor and the fuel-cell generator, and a signal representing minimum price of electric power.

A system for generating electricity by pyrolyzing organic materials and feeding the pyrolysis fluid to a battery of fuel-cells. The system includes a pyrolysis reactor receiving organic materials and producing pyrolysis fluid. The fluid pyrolysis is then separated into a plurality of sub-mixtures, each provided via a respective separator output. A plurality of fuel-cell devices for generating electricity using different technologies are each coupled to a respective separator output. A controller controls the pyrolysis reactor, the separator device, and the plurality of fuel-cell devices according to a signal representing a demand for electric power, a signal representing cost of operating at least one of the pyrolysis reactor and the fuel-cell generator, and a signal representing minimum price of electric power.