Provided is an electrode catalyst in which the contents of chlorine (Cl) species and bromine (Br) species are reduced to a predetermined level or lower, capable of exhibiting sufficient catalyst performance. The electrode catalyst has a core-shell structure including a support, a core part formed on the support and a shell part formed to cover at least a part of the surface of the core part. A concentration of bromine (Br) species of the electrode catalyst as measured by X-ray fluorescence (XRF) spectroscopy is 400 ppm or less, and a concentration of chlorine (Cl) species of the electrode catalyst as measured by X-ray fluorescence (XRF) spectroscopy is 900 ppm or less.

In a method of producing a membrane electrode assembly, a solid polymer electrolyte membrane and gas diffusion layers are stacked together in a stacking direction in a manner that electrode catalyst layers are interposed between at least parts of the solid polymer electrolyte membrane and the gas diffusion layers to form a stack body. A load is applied to the stack body in the stacking direction, and the temperature of the solid polymer electrolyte membrane is increased by high frequency dielectric heating. In this manner, the gas diffusion layers, the electrode catalyst layers, and the solid polymer electrolyte membrane are joined integrally to obtain the membrane electrode assembly.

Systems and methods are provided for maintaining and/or improving operating lifetime for molten carbonate fuel cells that contain reforming catalyst in the anode when processing cathode input flows that contain sulfur oxides. The systems and methods can include a serial arrangement of molten carbonate fuel cells, where a first fuel cell includes a reduced or minimized amount of reforming catalyst in the anode. A second molten carbonate fuel cell can include reforming catalyst in the anode.

Provided is an electrode catalyst in which the contents of chlorine (Cl) species and bromine (Br) species are reduced to a predetermined level or lower, capable of exhibiting sufficient catalyst performance. The electrode catalyst has a core-shell structure including a support, a core part formed on the support and a shell part formed to cover at least a part of the surface of the core part. A concentration of bromine (Br) species of the electrode catalyst as measured by X-ray fluorescence (XRF) spectroscopy is 400 ppm or less, and a concentration of chlorine (Cl) species of the electrode catalyst as measured by X-ray fluorescence (XRF) spectroscopy is 900 ppm or less.

In various aspects, systems and methods are provided for operating a molten carbonate fuel cell at increased fuel utilization and/or increased CO.sub.2 utilization. This can be accomplished in part by performing an effective amount of an endothermic reaction within the fuel cell stack in an integrated manner. This can allow for a desired temperature differential to be maintained within the fuel cell.

Example biosensor devices having wake-up batteries and associated methods are disclosed. One example device includes a biosensor that has a first electrode for insertion into a subcutaneous layer beneath a patient's skin, and a second electrode coupled to the first electrode for insertion into the subcutaneous layer, and a first battery to apply a voltage across the first and second electrodes, the first battery at least partially electrically decoupled from the electrodes. The device also includes a second battery having an anode material coupled to the first electrode for insertion into the subcutaneous layer, and a portion of the second electrode. The second battery is activatable upon immersion in an electrolytic fluid. The device also includes a wake-up circuit to receive a signal from the second battery and, in response, to electrically couple the first battery to the first and second electrodes to activate the biosensor.

A method of fabricating a three-dimensional (3D) architectured anode. The method comprises immersing a fabric textile in a precursor solution, the precursor solution comprising a nickel salt and gadolinium doped ceria (GDC). The nickel salt and GDC are absorbed to the fabric textile. The fabric textile comprising the absorbed nickel salt and GDC is removed from the precursor solution and calcined to form a 3D architectured anode comprising nickel oxide and GDC. Additional methods and a direct carbon fuel cell including the 3D architectured anode are also disclosed.

Membrane assemblies for electrochemical devices are provided, along with methods and system for fabricating them. Membrane assemblies comprise anode layer(s) and cathode layer(s), separated by membranous separation layer(s) and all embedded in continuous polymerized ionomer material. In production, during continuous deposition of ionomer material on a substrate (e.g., by electrospinning or electrospraying), consecutive deposition stages of catalyst material and optionally binder material are performed. For example, anode particles, binder material and cathode particles may be deposited (e.g., by electrospraying or electrospinning, respectively) consecutively during the continuous deposition o the ionomer material. Self-refueling power-generating system are provided, which include reversible anion exchange membrane devices with disclosed membrane assemblies.

In a manufacturing method for a gas diffusion sheet, when a first film is joined to a front end portion of a base material in a conveyance direction, a first joining material is made to penetrate a first overlapping portion where the first film and the base material are superimposed on each other, and the first film and the base material are thus joined to each other physically through the first joining material. When a second film is joined to a rear end portion of the base material in the conveyance direction, a second joining material is made to penetrate a second overlapping portion where the base material and the second film are superimposed on each other, and the base material and the second film are thus physically joined to each other through the second joining material.

A gas diffusion electrode comprising microporous layers on at least one side of an electrically conductive porous substrate, wherein said gas diffusion electrode has a thickness of 30 μm to 180 μm, said microporous layer has thickness of 10 μm to 100 μm, and when said surface of the microporous layer is observed for the area 0.25 mm.sup.2 for 4000 viewing areas, the number of the viewing areas having a maximal height Rz of not less than 50 μm is, among the 4000 viewing areas, 0 viewing areas to 5 viewing areas. A gas diffusion electrode which satisfies both the prevention of the damage to an electrolyte membrane by a gas diffusing layer and the gas diffusivity of the gas diffusing layer, and exhibits good performance as a fuel cell.