An individual solid oxide cell (SOC) constructed of a sandwich configuration including in the following order: an oxygen electrode, a solid oxide electrolyte, a fuel electrode, a fuel manifold, and at least one layer of mesh. In one embodiment, the mesh supports a reforming catalyst resulting in a solid oxide fuel cell (SOFC) having a reformer embedded therein. The reformer-modified SOFC functions internally to steam reform or partially oxidize a gaseous hydrocarbon, e.g. methane, to a gaseous reformate of hydrogen and carbon monoxide, which is converted in the SOC to water, carbon dioxide, or a mixture thereof, and an electrical current. In another embodiment, an electrical insulator is disposed between the fuel manifold and the mesh resulting in a solid oxide electrolysis cell (SOEC), which functions to electrolyze water and/or carbon dioxide.

An individual solid oxide cell (SOC) constructed of a sandwich configuration including in the following order: an oxygen electrode, a solid oxide electrolyte, a fuel electrode, a fuel manifold, and at least one layer of mesh. In one embodiment, the mesh supports a reforming catalyst resulting in a solid oxide fuel cell (SOFC) having a reformer embedded therein. The reformer-modified SOFC functions internally to steam reform or partially oxidize a gaseous hydrocarbon, e.g. methane, to a gaseous reformate of hydrogen and carbon monoxide, which is converted in the SOC to water, carbon dioxide, or a mixture thereof, and an electrical current. In another embodiment, an electrical insulator is disposed between the fuel manifold and the mesh resulting in a solid oxide electrolysis cell (SOEC), which functions to electrolyze water and/or carbon dioxide.

A cell includes an element portion including a first electrode layer, a solid electrolyte layer that contains Zr and that is located above the first electrode layer, an intermediate layer that contains CeO.sub.2 containing a rare earth element other than Ce and that is located above the solid electrolyte layer, and a second electrode layer located above the intermediate layer. The intermediate layer includes a first intermediate layer and a second intermediate layer that contains Zr and Ce and that is located at at least a portion between the first intermediate layer and the solid electrolyte layer. In a plan view from the second electrode layer, the second intermediate layer located at an outer peripheral portion of the intermediate layer includes a portion with a thickness greater than the second intermediate layer overlapping a center of the second electrode layer. A cell stack device, a module, and a module housing device include a plurality of the cells.

A fuel cell system including: a first fuel cell performing power generation using a fuel gas; a separation membrane separating at least one of carbon dioxide or water vapor from an anode off gas discharged from the first fuel cell; a second fuel cell disposed in the downstream of the separation membrane and performing power generation using the anode off gas, the anode off gas having at least one of carbon dioxide or water vapor separated therefrom; and a distribution channel disposed on a permeation side of the separation membrane and distributing any of the following: a raw material gas serving as the fuel gas to be reformed and used for the power generation of the first fuel cell, a cathode gas including oxygen to be used for the power generation of the first fuel cell, an anode off gas discharged from the second fuel cell, a cathode off gas discharged from the first fuel cell and to be supplied to the second fuel cell, or a cathode off gas discharged from the second fuel cell, in which at least one of permeability coefficient ratio α1 of the separation membrane or permeability coefficient ratio α2 of the separation membrane is 30 or higher.

Disclosed is a carbon dioxide utilization system capable of recharging and undergoing reactions. The system includes a cathode unit provided with a first aqueous solution accommodated in a first accommodation space, and a cathode at least a part of which is submerged in the first aqueous solution; an anode unit provided with an alkaline second aqueous solution accommodated in a second accommodation space, and a metal anode at least a part of which is submerged in the second aqueous solution; and a connection unit provided with a connection channel connecting the first and second accommodation spaces in open communication, and a porous ion transfer member, disposed in the connection channel, for blocking the movement of the first and second aqueous solutions but allowing the movement of ions.

Disclosed is a carbon dioxide utilization system capable of recharging and undergoing reactions. The system includes a cathode unit provided with a first aqueous solution accommodated in a first accommodation space, and a cathode at least a part of which is submerged in the first aqueous solution; an anode unit provided with an alkaline second aqueous solution accommodated in a second accommodation space, and a metal anode at least a part of which is submerged in the second aqueous solution; and a connection unit provided with a connection channel connecting the first and second accommodation spaces in open communication, and a porous ion transfer member, disposed in the connection channel, for blocking the movement of the first and second aqueous solutions but allowing the movement of ions.

A stack of rectangular, planar electrochemical cell units (200), each cell unit (200) comprising at least one first fluid mid-port (230, 235) that is disposed midway along its length within or between one or more active cell chemistry regions (210) and is in fluid communication with a first fluid volume of the cell unit (200). The first fluid mid-ports (230, 235) of the respective cell units (200) align to form at least one first fluid mid-passageway extending in the stack direction. The stack is configured such that, in each first fluid volume, first fluid flow paths (405, 410) extend across the one or more active cell chemistry regions (210) between the at least one first fluid mid-port (230, 235) and each respective opposed cell end.

Various embodiments include fuel cell interconnects having a fuel distribution portion having an inlet opening, a fuel collection portion having an outlet opening, and a primary fuel flow field containing channels, wherein the fuel distribution portion comprises at least one raised feature defining a fuel distribution flow path, and the fuel distribution flow path is not continuous with the channels in the primary fuel flow field. The at least one raised feature may include, for example, a network of ribs and/or dots. Further embodiments include interconnects having a fuel distribution portion with a variable surface depth to provide variable flow restriction and/or a plenum with variable surface depth and raised a raised relief feature on the cathode side, and/or varying flow channel depths and/or rib heights adjacent a fuel hole.

Various embodiments include fuel cell interconnects having a fuel distribution portion having an inlet opening, a fuel collection portion having an outlet opening, and a primary fuel flow field containing channels, wherein the fuel distribution portion comprises at least one raised feature defining a fuel distribution flow path, and the fuel distribution flow path is not continuous with the channels in the primary fuel flow field. The at least one raised feature may include, for example, a network of ribs and/or dots. Further embodiments include interconnects having a fuel distribution portion with a variable surface depth to provide variable flow restriction and/or a plenum with variable surface depth and raised a raised relief feature on the cathode side, and/or varying flow channel depths and/or rib heights adjacent a fuel hole.

An electrolyzer system includes a steam generator configured to generate steam, a stack of solid oxide electrolyzer cells configured to generate a hydrogen stream using the steam received from the steam generator, and a water preheater configured to preheat water provided to the steam generator using heat extracted from oxygen exhaust output from the stack.