A multilayer structure for storing hydrogen, including, from the inside, at least one sealing layer and at least one composite reinforcement layer, an innermost composite reinforcement layer being welded to an outermost adjacent sealing layer, the sealing layers being a composition predominantly of: at least one semi-crystalline polyamide thermoplastic polymer P1i, i=1 to n, n being the number of sealing layers, excluding an amide polyether block (PEBA), up to 50% by weight of impact modifier relative to the total weight of the composition, up to 1.5% by weight of plasticizer relative to the total weight of the composition, and at least one of the composite reinforcement layers of a fibrous material in the form of continuous fibers, which is impregnated with a composition predominantly of at least one semi-crystalline polyamide polymer P2j, j=1 to m, m being the number of reinforcement layers.

A hydrogen storage device 200 comprises: a first vessel 230, having a first fluid inlet 210 and/or a first fluid outlet 220, having therein a thermally conducting network 240 thermally coupled to a first heater (not shown); wherein the first vessel 230 is arranged to receive therein a hydrogen storage material in thermal contact, at least in part, with the thermally conducting network 240; wherein the thermally conducting network 240 has a lattice geometry, a gyroidal geometry and/or a fractal geometry in two and/or three dimensions, comprising a plurality of nodes, having thermally conducting arms therebetween, with voids between the arms; and wherein the hydrogen storage material comprises and/or is a liquid organic hydrogen carrier, LOHC.

A gaseous hydrogen storage and distribution system with a cryogenic supply and a method for the cryogenic conversion of liquid hydrogen into high-pressure gaseous hydrogen are provided. The gaseous hydrogen storage and distribution system includes pressuring liquid hydrogen from a cryogenic tank using a low pressure liquid pump before vaporization within a relatively small vaporizer. The resulting high pressure gaseous hydrogen is transferred to a plurality of storage tanks at ambient temperature according to a desired fill sequence. The high pressure hydrogen gas is subsequently distributed from the storage tanks through a hydrogen fueling dispenser according to a desired dispensing sequence. The present system and method provide improvements in operational safety, eliminates the use of high pressure gas compressor, and minimizes boiling off and ventilation losses at a reduced cost when compared to existing thermal compression storage systems.

A hydrogen cooling apparatus according to an embodiment includes: a binary refrigeration unit including a high-temperature-side refrigerator and a low-temperature-side refrigerator; and a hydrogen-cooling-fluid circulation unit. The binary refrigeration unit cools a hydrogen cooling fluid circulated by the hydrogen-cooling-fluid circulation unit by means of a low-temperature-side evaporator of the low-temperature-side refrigerator. The high-temperature-side refrigerator includes: a high-temperature-side refrigeration circuit; and a high-temperature-side bypass circuit including: a high-temperature-side bypass flow path that extends from a part, which is downstream of a high-temperature-side compressor and upstream of a high-temperature-side condenser in the high-temperature-side refrigeration circuit, to a part, which is downstream of a high-temperature-side expansion valve and upstream of a high-temperature-side evaporator in the high-temperature-side refrigeration circuit; and a high-temperature-side opening and closing valve provided on the high-temperature-side bypass flow path. The high-temperature-side refrigerator opens the high-temperature-side opening and closing valve when a high-temperature-side refrigerant has an abnormal pressure.

A method of detecting a leakage in a hydrogen refueling including establishing at a first and a second time a first and a second representation of at least one fluid parameter associated with hydrogen stored in at least one hydrogen storage tank of the hydrogen refuelling station, determining a relative difference between the first and second representation of the at least one fluid parameter, and comparing the relative difference with a threshold difference to detect a leakage, where a hydrogen refuelling station is provided including a hydrogen storage module comprising with a plurality of hydrogen storage tanks, a hydrogen station module having a compressor, and a dispensing module with at least one dispensing nozzle, the hydrogen refuelling station including at least one controller arranged to control the hydrogen refuelling station and arranged to detect a leakage using the beforementioned method.

A multilayer structure for transporting, distributing and storing hydrogen including, from the inside to the outside, a sealing layer and at least one composite reinforcement layer, the sealing layer including from the inside to the outside: a layer of a composition including: a short-chain polyamide thermoplastic polymer, more than 15% and up to 50% by weight of impact modifier, or including: a semi-crystalline long-chain polyamide thermoplastic polymer, up to 50% by weight of impact modifier, up to 3% by weight of plasticizer; a hydrogen barrier layer; a layer of a composition including: a short-chain polyamide thermoplastic polymer, more than 15% and up to 50% by weight of impact modifier, or including: a semi-crystalline long-chain polyamide thermoplastic polymer, up to 50% by weight of impact modifier, up to 3% of weight of plasticizer, the innermost composite reinforcement layer being wound around the sealing layer.

The invention relates to a method for storing and distributing liquefied hydrogen using a facility that comprises a store of liquid hydrogen at a predetermined storage pressure, a source of hydrogen gas, a liquefier comprising an inlet connected to the source and an outlet connected to the liquid hydrogen store, the store comprising a pipe for drawing liquid, comprising one end connected to the liquid hydrogen store and one end intended for being connected to at least one mobile tank, the method comprising a step of liquefying hydrogen gas supplied by the source and a step of transferring the liquefied hydrogen into the store characterized in that the hydrogen liquefied by the liquefier and transferred into the store has a temperature lower than the bubble temperature of hydrogen at the storage pressure.

A system for supplying hydrogen gas to an engine is disclosed. The system includes a main line configured to send hydrogen gas produced in a hydrogen gas producer by electrolysis to a supply line; a sub-line configured to send hydrogen gas from a hydrogen absorbing alloy cylinder to the main line, a governor configured to maintain an engine rotation speed within certain range; and a control device. The governor sends a signal corresponding to the engine rotation speed to the control device. A pressure regulating valve is disposed in the sub-line to be downstream with respect to the hydrogen absorbing alloy cylinder to regulate a supply amount of added hydrogen. An opening degree of the valve is adjusted based on a signal from the control device corresponding to the opening degree of the valve for supplying the added hydrogen with an amount according to a load state of the engine.

Disclosed is a liquefied hydrogen filling apparatus configured such that connection between liquefied hydrogen injection lines is performed stepwise, whereby there is no concern of leakage of liquefied hydrogen the moment the liquefied hydrogen injection lines are connected to each other, and therefore it is possible to guarantee safety and to prevent loss of fuel. In addition, the state of connection between the liquefied hydrogen injection lines is securely maintained, whereby there is no concern of separation due to internal pressure at the time of filling or other external force, and therefore it is possible to perform safe filling.

A heat generating system includes a heat-generating element cell and a circulation device. The heat-generating element cell includes a container having a recovery port and a discharge port, and a reactant that is provided in the container, is made from a hydrogen storage metal or a hydrogen storage alloy, has metal nanoparticles on a surface of the reactant. The heat-generating element cell generates excess heat when hydrogen-based gas contributing to heat generation is supplied into the container and hydrogen atoms are occluded in the metal nanoparticles. The circulation device circulates the hydrogen-based gas in the heat-generating element cell. The circulation device includes a circulating passage that is provided outside the container and connects the recovery port to the discharge port, a pump circulates the hydrogen-based gas in the container via the circulating passage, and a filter on the circulating passage adsorbs and removes the impurities in the hydrogen-based gas.