A device for diverting and defoaming with a bent pipe applied to a high head water supply structure includes an inner well, an outer well, a baffle, and a plurality of overflow pipes. The baffle is respectively connected with an outer wall of the inner well and an inner wall of the outer well to form an overflow groove, the top end of the inner well is higher than the baffle to form an overflow weir, one end of the overflow pipe is provided with a first pipe orifice in the overflow groove, the other end of the overflow pipe is communicated with the inner well to form a second pipe orifice, the first pipe orifice is higher than the second pipe orifice, the overflow pipe is bent in the overflow groove to form a first bending part, and the first bending part is higher than the first pipe orifice.