A method for measuring an amount of dissolved oxygen contained in a liquid sample, including the steps of: (1) adding a deoxygenating amino compound to a liquid sample to prepare the liquid sample having a predetermined concentration of the deoxygenating amino compound; (2) after Step (1), heating the liquid sample containing the deoxygenating amino compound at a temperature of 80° C. or more; (3) after Step (2), measuring the concentration of the deoxygenating amino compound contained in the liquid sample; and (4) calculating the amount of the dissolved oxygen contained in the liquid sample in Step (1) from the amount of the reacted deoxygenating amino compound by comparing the concentration of the deoxygenating amino compound measured in Step (3) and the concentration of the deoxygenating amino compound measured in Step (1).

This invention relates to the preparation of N-(phosphonomethyl)glycine (“glyphosate”) from N-(phosphonomethyl)iminodiacetic acid (“PMIDA”), and more particularly to methods for control of the conversion of PMIDA, for the identification of reaction end points relating to PMIDA conversion and the preparation of glyphosate products having controlled PMIDA content.

This invention relates to the preparation of N-(phosphonomethyl)glycine (“glyphosate”) from N-(phosphonomethyl)iminodiacetic acid (“PMIDA”), and more particularly to methods for control of the conversion of PMIDA, for the identification of reaction end points relating to PMIDA conversion and the preparation of glyphosate products having controlled PMIDA content.

Provided are a method and system for measuring hydrogen peroxide concentration in sample water collected from a prescribed position in a water treatment process and includes: collecting the sample water; measuring a concentration of a dissolved oxygen in the sample water or a treated water obtained by treating the sample water with the hydrogen peroxide decomposing device by first and second dissolved oxygen concentration measuring analyzers to obtain a corrected value that is a difference between the two dissolved oxygen concentration values; measuring the concentration of the dissolved oxygen in the sample and treated water by the first and second dissolved oxygen concentration measuring analyzers, respectively, and obtaining a measured value that is a difference between the dissolved oxygen concentration values; and calculating a corrected concentration of hydrogen peroxide from the measured value obtained during the measured value obtaining and the corrected value obtained during the corrected value obtaining.

This invention relates to the preparation of N-(phosphonomethyl)glycine (“glyphosate”) from N-(phosphonomethyl)iminodiacetic acid (“PMIDA”), and more particularly to methods for control of the conversion of PMIDA, for the identification of reaction end points relating to PMIDA conversion and the preparation of glyphosate products having controlled PMIDA content. One such method involves obtaining a series of Fourier transform infrared (“FTIR”) analyses of the PMIDA content of the aqueous reaction medium or a sample thereof during the course of the reaction. From a plurality of FTIR analyses, a projection is made of the batch reaction time or continuous oxidation residence time within the oxidation reaction zone at which a target conversion or end point may be anticipated to be attained or is attained.

Provided are a method and system for measuring hydrogen peroxide concentration in sample water collected from a prescribed position in a water treatment process and includes: collecting the sample water; measuring a concentration of a dissolved oxygen in the sample water or a treated water obtained by treating the sample water with the hydrogen peroxide decomposing device by first and second dissolved oxygen concentration measuring analyzers to obtain a corrected value that is a difference between the two dissolved oxygen concentration values; measuring the concentration of the dissolved oxygen in the sample and treated water by the first and second dissolved oxygen concentration measuring analyzers, respectively, and obtaining a measured value that is a difference between the dissolved oxygen concentration values; and calculating a corrected concentration of hydrogen peroxide from the measured value obtained during the measured value obtaining and the corrected value obtained during the corrected value obtaining.

A composite comprises a polymer matrix and a luminophore dispersed therein. The composite is useful as a sensing film that is used as an optical sensor for oxygen measurement comprising the composite sensing film; a source of photons for photo-exciting the luminophores and a waveguide, transparent in the frequency range of the excitation photons, for guiding the excitation photons from the source to the composite sensing film; a detector for measuring properties of photons emitted from the luminophores. A system including a computer may be useful for coordinating the activities of the sensor.

This invention relates to the preparation of N-(phosphonomethyl)glycine (glyphosate) from N-(phosphonomethyl)iminodiacetic acid (PMIDA), and more particularly to methods for control of the conversion of PMIDA, for the identification of reaction end points relating to PMIDA conversion and the preparation of glyphosate products having controlled PMIDA content.

A method and device to adjust the concentration of at least two gasses in a fluid, wherein the method involves adjusting the concentration of a first gas in the fluid by adjusting the concentration of a second gas in the fluid wherein the first and second gases are kept separate until dissolved in the fluid.

A method for measuring an amount of dissolved oxygen contained in a liquid sample, including the steps of: (1) adding a deoxygenating amino compound to a liquid sample to prepare the liquid sample having a predetermined concentration of the deoxygenating amino compound; (2) after Step (1), heating the liquid sample containing the deoxygenating amino compound at a temperature of 80 C. or more; (3) after Step (2), measuring the concentration of the deoxygenating amino compound contained in the liquid sample; and (4) calculating the amount of the dissolved oxygen contained in the liquid sample in Step (1) from the amount of the reacted deoxygenating amino compound by comparing the concentration of the deoxygenating amino compound measured in Step (3) and the concentration of the deoxygenating amino compound measured in Step (1).