Method of transforming biomass into hydrocarbon

Abstract

A method is provided to transform biomass. Non-food biomass is preprocessed. Then, fermentation is processed to generate ethanol. Ethanol is dehydrated through a catalyst to generate ethylene. After the dehydration, oligomerization is processed with a catalyst to transform ethylene into olefins having 6˜20 carbon atoms (C.sub.6˜C.sub.20). The olefins are hydrotreated into alkanes. Thus, C.sub.6˜C.sub.20 hydrocarbons having long carbon chains are formed. The hydrocarbons having 6˜10 carbon atoms can be used as gasoline; those having 8˜16 carbon atoms, jet fuel; and those having 16˜20 carbon atoms, diesel. On generating ethanol, byproducts of lignin may be generated. The byproducts can be processed through depolymerization/deoxygenation to generate aromatic hydrocarbons or can be gasified to generate methanol or dimethyl ether. By further processing dehydration, aromatic hydrocarbons are generated to be mixed into gasoline, jet fuel or diesel. Or, the lignin byproducts are gasified to generate syngas.

Claims

1. A method of transforming biomass into hydrocarbons, comprising steps of: preprocessing a non-grain biomass and fermenting said biomass into ethanol and lignin; processing said ethanol through dehydration with a catalyst to obtain ethylene; transforming said ethylene into olefin having 6˜20 carbon atoms through oligomerization with a catalyst; and hydrotreating said olefin into alkanes having long carbon chains of C.sub.6˜C.sub.20, wherein said alkanes having 6˜10 carbon atoms form gasoline; said alkanes having 8˜16 carbon atoms form jet fuel; and said alkanes having 16˜20 carbon atoms form diesel fuel; processing said lignin through depolymerization/deoxygenation to obtain aromatic hydrocarbon; processing said lignin through gasification to obtain syngas; and processing said syngas through a synthesis reaction to obtain one or both of methanol and dimethyl ether which is then dehydrated with a catalyst to obtain aromatic hydrocarbon and blended into gasoline/jet fuel/diesel and/or processing the syngas through a water-gas shift reaction to obtain hydrogen which is then used in hydrogenation reactions of olefins.

2. The method according to claim 1, wherein said non-grain biomass is selected from a group consist of a fiber material and a mixture of fiber materials and said fiber material is selected from a group consist of straw, bagasse, miscanthus, bamboo, hardwood, softwood, sunflower stalk and Pennisetum.

3. The method according to claim 1, wherein a selectivity of said ethylene is higher than 90%.

4. The method according to claim 1, comprising using an acidic catalyst to process said oligomerization of ethylene to lengthen carbon chains.

5. The method according to claim 1, wherein a selectivity of said hydrocarbon having 6˜10 carbon atoms is greater than 60%.

Description

BRIEF DESCRIPTION OF THE DRAWING

(1) The present invention will be better understood from the following detailed description of the preferred embodiment according to the present invention, taken in conjunction with the accompanying drawing, in which

(2) FIG. 1 is the flow view showing the preferred embodiment according to the present invention.

DESCRIPTION OF THE PREFERRED EMBODIMENT

(3) The following description of the preferred embodiment is provided to understand the features and the structures of the present invention.

(4) Please refer to FIG. 1, which is a flow view showing a preferred embodiment according to the present invention. As shown in the FIGURE, the present invention is a method of transforming biomass into hydrocarbons, which integrates biomass refining processes to transform primary products of ethanol into gasoline/jet fuel/diesel and to transform byproducts of lignin into aromatic hydrocarbons/hydrogen, comprising the following steps:

(5) (a) A non-grain biomass 10 is preprocessed 101 and, then, fermented 102 into main products of ethanol 11 and byproducts of lignin 12. The products of ethanol 11 are processed through dehydration 111 with a catalyst to generate products of ethylene 13. Then, the products of ethylene 13 are transformed into products of olefin 14 having 6˜20 carbon atoms (C.sub.6˜C.sub.20) through oligomerization 131 with a catalyst. The products of olefin 14 are hydrotreated 141 into products of hydrocarbon of alkane 15 having long carbon chains of C.sub.6˜C.sub.20.

(6) (b) The products of lignin 12 are processed through depolymerization/deoxygenation 121 to generate products of aromatic hydrocarbon 16 and processed through gasification 122 to generate products of syngas 17. The products of syngas 17 are processed through a synthesis reaction 171 to generate methanol or dimethyl ether 18 to be dehydrated/aromatized 181 with a catalyst to generate products of aromatic hydrocarbon 16 to be blended into gasoline/jet fuel/diesel. Or, the products of syngas 17 are processed through a water-gas shift reaction 172 to generate hydrogen 19 to be used in hydrogenation reactions of olefins.

(7) Thus, a novel method of transforming biomass into hydrocarbons is obtained.

(8) The non-food biomass is a fiber material or a mixture of fiber materials and the fiber material is straw, bagasse, miscanthus, bamboo, hardwood, softwood, sunflower stalk or Pennisetum.

(9) On using, the present invention uses a non-food biomass of cellulose and semi-cellulose as a raw material to be transformed for generating alcohol (i.e. ethanol) through fermentation while lignin in the biomass becomes byproduct to be left during processing. Thus, the whole processes are effectively integrated to improve product economy. In FIG. 1, the bio-alcohol (i.e. ethanol) is processed through dehydration with a catalyst to generate ethylene (a conventional reaction, no need to describe in detail). Then, ethylene is transformed into olefins having C.sub.6˜C.sub.20 through oligomerization with a catalyst (a conventional reaction, no need to describe in detail). A part of olefins is hydrotreated (a conventional reaction, no need to describe in detail). Thus, hydrocarbons of alkane having C.sub.6˜C.sub.20 are generated, each of which has a total olefin content meeting regulations. Therein, hydrocarbons having 6˜10 carbon atoms are used as gasoline; hydrocarbons having 8˜16 carbon atoms are used as jet fuel; and hydrocarbons having 16˜20 carbon atoms are used as diesel.

(10) The lignin left is a by-product of the ethanol production and can be further depolymerized/deoxygenated to generate aromatic hydrocarbons (a conventional reaction, no need to describe in detail); or gasified to produce syngas. Syngas is synthesized into methanol or dimethyl ether to be dehydrated with a zeolite catalyst to generate aromatic hydrocarbons (a conventional reaction, no need to describe in detail). The aromatic hydrocarbons are used to be blended into gasoline/jet fuel/diesel. Or, lignin can be gasified into syngas to be processed through a water-gas shift reaction to generate hydrogen to be used in hydrogenation reactions of olefins. Thus, the integrated biomass refining process enhances product breadth of the whole plant and economy of the production.

(11) In the present invention, selectivity of ethylene is higher than 90%. Ethylene has high reactivity and, by using an acidic catalyst, the length of carbon chain can be lengthened through oligomerization under a mild reaction condition. Meanwhile, lignin can be used to produce hydrogen or aromatic hydrocarbons. As corresponding to the general biomass refinery which uses lignin as a fuel, the present invention further enhances the use of lignin, whose advantages to the products of HEFA (Hydroprocessed Ethers and Fatty Acids) & FT SPK (Fisher-Tropsch Synthetic Paraffinic Kerosense) are shown in Table 1.

(12) TABLE-US-00001 TABLE I The present FT SPK HEFA SPK invention Raw Coal, natural Oily biomass biomass material gas, biomass C.sub.8~C.sub.16 ~15% 25-50% >60% selectivity estimation minimum ~400 kiloliters ~150 kiloliters ~150 kiloliters economic scale estimation Technical Having a variety Using biological Producing alcohol features of source material oily source through Mature material only, fermentation technology having great After dehydration, Need for mass impact on cost oligomerizing production Unrefined olefin to be Low selectivity, products saturated through subject to further with very hydrogenation refinement for narrow carbon Products enhancing yield number containing of target product distribution alkanes/aromatic Refined products hydrocarbons if mostly having transforming lignin straight chains into aromatic hydrocarbons

(13) To sum up, the present invention is a method of transforming biomass into hydrocarbons, where a second-generation bio-ethanol technology is provided for transforming primary products of ethanol into gasoline/jet fuel/diesel and transforming byproducts of lignin into aromatic hydrocarbons/hydrogen with biomass refining processes integrated to effectively increase product breadth and reduce production cost.

(14) The preferred embodiment herein disclosed is not intended to unnecessarily limit the scope of the invention. Therefore, simple modifications or variations belonging to the equivalent of the scope of the claims and the instructions disclosed herein for a patent are all within the scope of the present invention.