Method of processing single-crystal substrate
09735040 · 2017-08-15
Assignee
Inventors
Cpc classification
B23K26/53
PERFORMING OPERATIONS; TRANSPORTING
H01L21/78
ELECTRICITY
B23K2103/172
PERFORMING OPERATIONS; TRANSPORTING
H01L2221/6834
ELECTRICITY
B23K26/0823
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0006
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0624
PERFORMING OPERATIONS; TRANSPORTING
B23K26/04
PERFORMING OPERATIONS; TRANSPORTING
H01L33/0095
ELECTRICITY
International classification
B23K26/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method of dividing a single-crystal substrate along a plurality of preset division lines, includes a shield tunnel forming step of applying a pulsed laser beam having such a wavelength that permeates through the substrate along the division lines to form shield tunnels, each including a fine hole and an amorphous region shielding the fine hole, a protective member adhering step of adhering a protective member to the substrate before or after the shield tunnel forming step, and a grinding step of holding the protective member on the substrate, to which the shield tunnel forming step and the protective member adhering step are performed, on a chuck table of a grinding apparatus, grinding a reverse surface of the substrate to bring the substrate to a predetermined thickness, and dividing the substrate along the division lines along which the shield tunnels have been formed.
Claims
1. A method of processing a single-crystal substrate to divide the single-crystal substrate along a plurality of preset division lines, comprising: a shield tunnel forming step of applying a pulsed laser beam to the single-crystal substrate along the division lines to form shield tunnels, which each include a fine hole and an amorphous region shielding the fine hole, in the single-crystal substrate along the division lines, wherein the pulsed laser beam has a wavelength that is configured to permeate through the single-crystal substrate; a protective member adhering step of adhering a protective member to the single-crystal substrate; and a grinding step of holding the protective member on the single-crystal substrate, to which the shield tunnel forming step and the protective member adhering step have been performed, on a chuck table of a grinding apparatus, grinding a reverse surface of the single-crystal substrate to bring the single-crystal substrate to a predetermined thickness, and dividing the single-crystal substrate along the division lines along which the shield tunnels have been formed, wherein the amorphous regions and the fine holes of the shield tunnels are formed by the pulsed laser beam during the shield tunnel forming step.
2. The method of processing the single-crystal substrate according to claim 1, wherein the pulsed laser beam used in the shield tunnel forming step has a peak energy density set to a value in a range from 1 TW/cm.sup.2 to 100 TW/cm.sup.2.
3. The method of processing the single-crystal substrate according to claim 1, wherein the protective member adhering step is performed before the shield tunnel forming step.
4. The method of processing the single-crystal substrate according to claim 1, wherein the protective member adhering step is performed after the shield tunnel forming step.
5. The method of processing the single-crystal substrate according to claim 1, wherein the amorphous region extends from a front surface of the single-crystal substrate to the reverse surface of the single-crystal substrate.
6. The method of processing the single-crystal substrate according to claim 1, wherein the amorphous region extends from a front surface of the single-crystal substrate towards the reverse surface of the single-crystal substrate.
7. The method of processing the single-crystal substrate according to claim 1, wherein the pulsed laser beam used in the shield tunnel forming step has a pulse width within the range of 0.7 ps to 63 ps.
8. The method of processing the single-crystal substrate according to claim 1, wherein the pulsed laser beam used in the shield tunnel forming step has a spot diameter of 10 μm.
9. The method of processing the single-crystal substrate according to claim 1, wherein the pulsed laser beam used in the shield tunnel forming step has an average output power of 5 W.
10. The method of processing the single-crystal substrate according to claim 1, wherein the pulsed laser beam used in the shield tunnel forming step has: a pulse width within the range of 0.7 ps to 63 ps; a spot diameter of 10 μm; and an average output power of 5 W.
11. The method of processing the single-crystal substrate according to claim 1, wherein the fine holes formed during the shield tunnel forming step are formed at predetermined intervals.
12. The method of processing the single-crystal substrate according to claim 11, wherein each of the predetermined intervals is 10 μm.
13. The method of processing the single-crystal substrate according to claim 1, wherein the fine hole in each of said shield tunnels has a diameter of about 1 μm.
14. The method of processing the single-crystal substrate according to claim 13, wherein the amorphous region surrounding the fine hole in each of said shield tunnels has a diameter of about 10 μm.
15. The method of processing the single-crystal substrate according to claim 1, wherein the amorphous region of each of said shield tunnels is generally cylindrical-shaped.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
(11) A method of processing a single-crystal substrate according to a preferred embodiment of the present invention will be described in detail below with reference to the accompanying drawings.
(12) An optical device wafer 2 shown in
(13) First, in order to protect the optical devices 22 formed on the surface 2a of the optical device wafer 2, a protective member adhering step is carried out to adhere a protective member to the surface 2a of the optical device wafer 2. Specifically, as shown in
(14) After the protective member adhering step has been performed, a shield tunnel forming step is carried out to apply a pulsed laser beam having such a wavelength that permeates through the optical device wafer 2 which includes the sapphire (Al.sub.2O.sub.3) substrate as the single-crystal substrate along the division lines 21, forming shield tunnels, each including a fine hole and an amorphous region shielding the fine hole, along the division lines 21. According to the present embodiment, the shield tunnel forming step is performed using a laser processing apparatus 4 shown in
(15) The laser beam applying means 42 includes a casing 421 of a hollow cylindrical shape extending essentially horizontally. As shown in
(16) The converging unit or condenser 424 includes a direction changing mirror 424a for changing the direction of the pulsed laser beam LB downwardly which has been emitted from the pulsed laser beam oscillating means 422 and whose output power has been adjusted by the output power adjusting means 423, and a condensing lens 424b for converging the pulsed laser beam LB which has been changed in direction by the direction changing mirror 424a and applying the converged pulsed laser beam to a workpiece W held on the holding surface as the upper surface of the chuck table 41. The present inventor has confirmed that a shield tunnel is formed insofar as a value generated by dividing the numerical aperture (NA) of the condensing lens 424b of the converging unit 424 by the refractive index (N) of the single-crystal substrate is in the range from 0.05 to 0.4. The relationship between the numerical aperture (NA), the refractive index (N), and the value (S=NA/N) generated by dividing the numerical aperture (NA) by the refractive index (N) will be described below with reference to
(17) In
(18) The image capturing means 43, which is mounted on a distal end portion of the casing 421 of the laser beam applying means 42, includes, other than an ordinary image capturing device (CCD) which captures an image with a visible light beam, infrared radiation applying means for applying an infrared radiation to the workpiece, an optical system for capturing the infrared radiation applied by the infrared radiation applying means, and an image capturing device (infrared CCD) for outputting an electric signal depending on the infrared radiation captured by the optical system. The image capturing means 43 sends a captured image signal to the control means, not shown.
(19) For laser-processing the optical device wafer 2, on which the wafer supporting step has been performed, along the division lines 21 using the laser processing apparatus 4, the protective tape 3 to which the optical device wafer 2 has been adhered is placed on the chuck table 41 of the laser processing apparatus 4 shown in
(20) When the chuck table 41 is positioned immediately below the image capturing means 43, the image capturing means 43 and the non-illustrated control means carry out an alignment process to detect an area to be laser-processed of the optical device wafer 2. Specifically, the image capturing means 43 and the non-illustrated control means perform an image processing process such as pattern matching or the like to position a division line 21 along a first direction on the optical device wafer 2 and the converging unit 424 of the laser beam applying means 42 which applies the laser beam along the division line 21, with respect to each other, thereby aligning a laser beam applying position (alignment step). A laser beam applying position is similarly aligned with respect to a division line 21 that extends on the optical device wafer 2 perpendicularly to the above first direction. In the alignment step, the division lines 21 on the optical device wafer 2 and the optical devices 22 are positioned downwardly. Since the image capturing means 43 includes the infrared radiation applying means, the optical system for capturing the infrared radiation, and the image capturing device (infrared CCD) for outputting an electric signal depending on the infrared radiation, as described above, the image capturing means 43 can capture an image of the division line 21 through the optical device wafer 2 which includes the sapphire (Al.sub.2O.sub.3) substrate as a single-crystal substrate, from the reverse side 2b of the optical device wafer 2.
(21) After the above alignment step has been carried out, as shown in
(22) After the positioning step has been carried out as described above, a shield tunnel forming step is carried out to operate the laser beam applying means 42 to emit the laser beam LB from the converging unit 424 and form, in the optical device wafer 2 which includes the sapphire (Al.sub.2O.sub.3) substrate as a single-crystal substrate, a fine hole and an amorphous region shielding the fine hole which extend from a region in the vicinity of the converged point P (reverse side 2b) toward the surface 2a, thereby forming a shield tunnel in the optical device wafer 2. Specifically, while the converging unit 424 is emitting the pulsed laser beam LB which has such a wavelength that permeates through the sapphire (Al.sub.2O.sub.3) substrate of the optical device wafer 2, the chuck table 41 is moved at a predetermined feed speed along the direction indicated by the arrow X1 in
(23) When the above shield tunnel forming step is carried out, as shown in
(24) After the shield tunnel forming step has been carried out along the predetermined division line 21, the chuck table 41 is indexed by the interval between division lines 21 on the optical device wafer 2 along the direction indicated by the arrow Y (indexing step), and then the above shield tunnel forming step is performed. When the shield tunnel forming step has been carried out along all the division lines 21 that extend along the first direction, the chuck table 41 is turned 90 degrees, and then the shield tunnel forming step is carried out along the division lines 21 which extend along a direction perpendicular to the division lines 21 along the first direction.
(25) In order to form good shield tunnels 23 in the above shield tunnel forming step, it is important to set the peak energy density of the pulsed laser beam LB to a value in a range from 1 TW/cm.sup.2 to 100 TW/cm.sup.2. The peak energy density can be determined as average output power (W)/{repetitive frequency (Hz)×spot area (cm.sup.2)×pulse width (s)}.
(26) The reasons why the peak energy density of the pulsed laser beam LB is set to a value in the range from 1 TW/cm.sup.2 to 100 TW/cm.sup.2 will be described below.
(27) [Experiment 1]
(28) Condition 1 . . . single-crystal substrate: sapphire substrate (having a thickness of 400 μm)
(29) Condition 2 . . . the wavelength of the pulsed laser beam is set to 1030 nm
(30) Condition 3 . . . the repetitive frequency of the pulsed laser beam is set to 100 kHz
(31) Condition 4 . . . the spot diameter of the pulsed laser beam is set to 10 μm
(32) Condition 5 . . . the average output power of the pulsed laser beam is set to 5 W
(33) Condition 6 . . . variable: the pulse width of the pulsed laser beam
(34) The pulsed laser beam was applied to the sapphire substrate while the pulse width was varied from 0.1 ps to 100 ps under the above conditions, and the processed state was observed.
(35) When the pulse width ranged from 0.1 ps to 0.6 ps, voids were formed within the sapphire substrate.
(36) When the pulse width ranged from 0.7 ps to 63 ps, shield tunnels including fine holes and amorphous regions shielding the fine holes were formed within the sapphire substrate.
(37) When the pulse width ranged from 64 ps to 100 ps, the inside of the sapphire substrate was melted.
(38) It can be seen from the above experimental results that shield tunnels including fine holes and amorphous regions shielding the fine holes are formed within the sapphire substrate when the pulse width is in the range from 0.7 ps to 63 ps.
(39) Consequently, the peak energy density is determined with the pulse width in the range from 0.7 ps to 63 ps under the above conditions, and shield tunnels are formed by setting the peak energy density to a value in the range from 1 TW/cm.sup.2 to 100 TW/cm.sup.2.
(40) [Experiment 2]
(41) Condition 1 . . . single-crystal substrate: sapphire substrate (having a thickness of 400 μm)
(42) Condition 2 . . . the wavelength of the pulsed laser beam is set to 1030 nm
(43) Condition 3 . . . the pulse width is set to 10 ps
(44) Condition 4 . . . the spot diameter of the pulsed laser beam is set to 10 μm
(45) Condition 5 . . . the average output power of the pulsed laser beam is set to 5 W
(46) Condition 6 . . . variable: the repetitive frequency of the pulsed laser beam
(47) The pulsed laser beam was applied to the sapphire substrate while the repetitive frequency was varied from 1 kHz to 1000 kHz under the above conditions, and the processed state was observed.
(48) When the repetitive frequency ranged from 1 kHz to 6 kHz, the inside of the sapphire substrate was broken and cracks were radially developed therein.
(49) When the repetitive frequency ranged from 7 kHz to 640 kHz, shield tunnels including fine holes and amorphous regions shielding the fine holes were formed within the sapphire substrate.
(50) When the repetitive frequency ranged from 650 kHz to 1000 kHz, voids were formed within the sapphire substrate and no shield tunnels were formed therein.
(51) It can be seen from the above experimental results that shield tunnels including fine holes and amorphous regions shielding the fine holes are formed within the sapphire substrate when the repetitive frequency is in the range from 7 kHz to 640 kHz.
(52) Consequently, the peak energy density is determined with the repetitive frequency in the range from 7 kHz to 640 kHz under the above conditions, and shield tunnels are formed by setting the peak energy density to a value in the range from 1 TW/cm.sup.2 to 100 TW/cm.sup.2.
(53) The above described Experiment 1 and Experiment 2 were conducted on the sapphire (Al.sub.2O.sub.3) substrate. Experiments similar to Experiment 1 and Experiment 2 were also conducted on a silicon carbide (SiC) substrate, a gallium nitride (GaN) substrate, a lithium tantalate (LiTaO.sub.3) substrate, a lithium niobate (LiNbO.sub.3) substrate, a diamond substrate, and a quartz (SiO.sub.2) substrate, each as a single-crystal substrate, and the results of those experiments were essentially the same.
(54) After the above shield tunnel step has been carried out, a grinding step is carried out to hold the protective member adhered to the surface 2a of the optical device wafer 2 which includes the sapphire (Al.sub.2O.sub.3) substrate as a single-crystal substrate on a chuck table of a grinding apparatus, grind the reverse side 2b of the optical device wafer 2 to bring the optical device wafer 2 to a predetermined thickness, and divide the optical device wafer 2 along the division lines 21 along which the shield tunnels 23 have been formed. The grinding step is performed using a grinding apparatus 5 shown in
(55) For performing the grinding step using the grinding apparatus 5, the protective tape 3 adhered to the surface 2a of the optical device wafer 2 is placed on the upper surface (holding surface) of the chuck table 51, as shown in
(56) Then, a wafer supporting step is carried out to adhere a dicing tape to the reverse side 2b of the optical device wafer 2 which includes the sapphire (Al.sub.2O.sub.3) substrate as a single-crystal substrate (divided into the individual optical devices 22) on which the grinding step has been performed, and support an outer circumferential portion of the dicing tape on an annular frame. Specifically, as shown in
(57) After the wafer supporting step has been performed, a pickup step is carried out to pick up the individual optical devices 22 divided from the optical device wafer 2 adhered to the dicing tape T. The pickup step is carried out using a pickup apparatus 6 shown in
(58) The tape expanding means 62 has an expanding drum 621 disposed in the annular frame holding member 611. The expanding drum 621 has an outside diameter smaller than the inside diameter of the annular frame F and an inside diameter larger than the outside diameter of the optical device wafer 2 adhered to the dicing tape T which is mounted on the annular frame F. The expanding drum 621 has a support flange 622 on its lower end. The tape expanding means 62 according to the present embodiment has support means 623 for vertically moving the annular frame holding member 611 back and forth. The support means 623 includes a plurality of air cylinders 623a disposed on the support flange 622 and having respective piston rods 623b connected to the lower surface of the annular frame holding member 611. The support means 623 which includes the air cylinders 623a moves the annular frame holding member 611 vertically between a reference position shown in
(59) The pickup step to be carried out using the pickup apparatus 6 thus constructed will be described below with reference to
(60) Then, as shown in
(61) The present invention is not limited to the details of the above described preferred embodiment. The scope of the invention is defined by the appended claims and all changes and modifications as fall within the equivalence of the scope of the claims are therefore to be embraced by the invention.