METHOD FOR PRODUCING IMPREGNATED FIBER STRUCTURES

Abstract

The invention relates to a process for the production of saturated fiber structures. The process includes (a) introduction of a fiber structure onto a conveyor belt; (b) application of a solution including monomer and optionally including activator, and optionally including catalyst in at least one line to the fiber structure; (c) passage of the fiber structure with the solution through at least one roll pair in which pressure is exerted on the fiber structure; and (d) cooling of the saturated fiber structure, so that the monomer solidifies.

Claims

2. The process according to claim 1, wherein the at least one line applied is one of a straight, undulating, and zigzag shape.

3. The process according to claim 1, wherein one line is applied central in the fiber structure.

4. The process according to claim 2, wherein an even number of lines having an undulating or zigzag shape is applied, wherein the lines applied having an undulating or zigzag shape are applied with axial symmetry to the fiber structure.

5. The process according to claim 2, wherein the lines applied having an undulating or zigzag shape intersect.

6. The process according to claim 1, wherein the solution comprising monomer is applied by using a nozzle which has an aperture diameter of at most 5 mm.

7. The process according to claim 1, wherein the distance between the application of the solution in step (b) and the roll pair through which the fiber structure is passed in step (c) is at most 3 m.

8. The process according to claim 1, wherein the viscosity of the solution comprising monomer is in the range from 5 to 500 mPas.

9. The process according to claim 1, wherein the distance between the rolls of the roll pair is from 1 to 1.5 times the thickness of the fiber structure.

10. The process according to claim 1, wherein the flow rate of the solution comprising monomer and the transport velocity of the fiber structure are selected in such a way that after passage of the saturated fiber structure through the roll pair the content of fibers in the saturated fiber structure is from 20 to 70% by volume.

11. The process according to claim 1, wherein the monomer is selected from the group of the lactams.

12. The process according to claim 11, wherein the lactam is selected from the group consisting of caprolactam, piperidone, pyrrolidone, lauryllactam, and a mixture of these.

13. The process according to claim 19, wherein the lactone is caprolactone.

14. The process according to claim 11, wherein the temperature used for applying the solution is in the range from 80 to 120° C., and the temperature of the roll pair is at most 100° C.

15. The process according to claim 1, wherein the fiber structure is selected from the group consisting of a woven fabric, laid scrim, nonwoven, knitted fabric, braided fabric, and rovings.

16. The process according to claim 1, wherein the fiber structure comprises fibers selected from the group consisting of glass fibers, carbon fibers, aramid fibers, steel fibers, potassium titanate fibers, basalt fibers, ceramic fibers, and mixtures thereof.

17. The process of claim 1 wherein the solution comprising a monomer further comprises at least one of activator and catalyst.

18. The process of claim 1 wherein a plurality of lines are applied wherein the distance between the individual lines is equal, and the distance between the outermost lines and the periphery of the fiber structure is half as great as the distance between two lines.

19. The process of claim 11, wherein the lactam is mixed with up to 50% by volume lactones.

Description

[0058] An embodiment of the invention is depicted in the figures and is explained in more detail in the description below.

[0059] FIG. 1 is a diagram of the process of the invention for the production of a saturated fiber structure,

[0060] FIG. 2 is a plan view of the fiber structure between application of the solution comprising monomer and optionally comprising activator, and optionally comprising catalyst and the roll pair,

[0061] FIG. 3 is a plan view of the fiber structure between application of the solution comprising monomer and the roll pair when the solution is applied in zigzag lines,

[0062] FIG. 4 is a plan view of a fiber structure with application of the solution comprising monomer in two line systems,

[0063] FIG. 5 is a plan view of a fiber structure with application of the solution comprising monomer in a plurality of overlapping lines.

[0064] FIG. 1 is a diagram of the process of the invention for the production of a saturated fiber structure.

[0065] A first foil 5 is introduced into an apparatus 1 for the production of a saturated fiber structure. In the embodiment depicted here, the first foil 5 is placed onto a conveyor belt 7. A suitable conveyor belt 7 is any desired conveyor belt that is known to the person skilled in the art and that can transport the foil 5. The design of the surface of the conveyor belt 7 here is such that the foil 5 is not damaged by the motion of the conveyor belt 7 or during application to the conveyor belt 7. In order that the process can be operated continuously, the foil 5 is held on a roll 9, from which it is unwound and introduced into the apparatus 1.

[0066] In the embodiment depicted here, two layers of fibers 11 are laid on the foil 5. The fibers 11 here can take the form of woven fabric, knitted fabric, laid scrim, nonwoven, or of parallel-oriented fibers, yarns, threads, or cords. If parallel-oriented fibers are used, it is preferable to orientate the fibers of the individual layers at an angle to one another, preferably at an angle of 90° to one another. The addition of the fibers 11 likewise takes place continuously, and the fibers 11 here are held on a roll 13. The fibers 11 laid on the foil 5 form the fiber structure 15 to be saturated.

[0067] In order to obtain uniform wetting of the fibers of the fiber structure 15 with lactam, the fiber structure 15 is preferably heated. FIG. 1 uses arrows 17 to depict the heat supply. After the heating, molten lactam is applied to the fiber structure 15. The molten lactam preferably comprises at least one catalyst which catalyzes the anionic polymerization to give polyamide, and also optionally comprises at least one activator. The material can also comprise other additives which can influence the properties of a polyamide produced from the lactam. The temperature to which the fiber structure 15 is heated preferably corresponds to the melting point of the lactam used. The temperature is preferably in the range from 70 to 90° C. During the heating, care has to be taken that the temperature of the molten lactam and the temperature to which the fiber structure 15 is heated are kept below the onset temperature for the anionic polymerization of the lactam. A nozzle 16 is used in the invention for the application of the molten lactam, and applies the lactam in the form of a narrow line to the fiber structure 15. The nozzle 16 here preferably has a circular nozzle aperture of diameter at most 2 mm. The line here is preferably parallel to the lateral peripheries of the fiber structure 15. If the width of the fiber structure 15 is great, or if the quantity of lactam introduced via a nozzle 16 is inadequate to apply, to the fiber structure 15, the quantity of lactam desired for the production of the saturated fiber structure 3, it is also possible to use a plurality of nozzles 16 arranged parallel alongside one another, preferably at equal distances.

[0068] In the embodiment depicted here, the following are added to a mixing unit 23: molten lactam with activator by way of a first inlet 19 and molten lactam with catalyst by way of a second inlet 21. The mixing unit can by way of example take the form of extruder or else of static mixer. A homogeneous mixture of the lactam with activator and catalyst is produced in the mixing unit. The molten lactam comprising activator and comprising catalyst is applied via the nozzle 16 to the textile structure 15.

[0069] In the embodiment depicted here there is a temperature-controllable roll 24 below the nozzle 16. The temperature of the roll 24 can preferably be controlled in the range from −30° C. to 100° C. The temperature of the roll 24 here is adjusted in such a way as to adjust the viscosity of the solution applied via the nozzle 16 to a value that firstly permits uniform distribution of said solution in the fiber structure 15 but secondly also prevents premature reaction of the monomer at this location to give the polymer. The temperature selected is moreover also not permitted to be so low that the solution solidifies in the fiber structure 15, since that can result in production of cavities and defects in the component to be produced from the saturated fiber structure.

[0070] In the embodiment depicted here, a second foil 27 is applied to the saturated fiber structure 25 after the saturation process. The second foil 27 here is preferably, like the first foil 5, unwound from a roll 29 on which it is held.

[0071] In a following step, the saturated fiber structure 25 is passed through a roll pair 31, where pressure is exerted on the saturated fiber structure 25. The distance between the rolls of the roll pair 31 here is preferably from 1 to 1.5 times the thickness of the unsaturated fiber structure 15 plus the thickness of the conveyor belt 7 and of the foil 5.

[0072] In an embodiment not depicted here, at least one further fiber layer is applied on the upper side and/or the underside of the saturated textile structure after the saturation process. It is preferable here that the fibers additionally applied are of the same type as the fibers 11 which form the textile structure 15. However, it is also alternatively possible that the fibers that form the fiber structure 15 are by way of example individual layers of parallel-oriented fibers, yarns, threads, or cords, or that a nonwoven forms the fiber structure 15, and that the additional layers are woven fabrics or knitted fabrics.

[0073] The compression of the saturated fiber structure 25 also forces lactam into the fiber layers additionally applied, and the fiber layers additionally applied are thus likewise saturated with lactam.

[0074] After compression, the saturated fiber structure 25 is cooled. An arrow 33 depicts this. The cooling solidifies the lactam, and a fiber structure comprising solid lactam is produced. This can then be further processed by using a cutter 35, for example a blade, a punch, or a saw, to give a flat fiber-reinforced semifinished product 3.

[0075] FIG. 2 is a plan view of the fiber structure between application of the solution comprising monomer and optionally comprising activator, and optionally comprising catalyst and the roll pair.

[0076] The plan view in FIG. 2 shows how the solution comprising monomer and optionally comprising activator, and optionally comprising catalyst is first applied via the nozzle 16 in the form of a line 37 to the fiber structure 15. By virtue of the porosity of the fiber structure 15 and of the low viscosity of the solution, the solution flows through the fiber structure 15 and becomes distributed across the width of the fiber structure 15. On passage through the roll pair 31, the solution is then also forced into the regions of the fiber structure 15 that have not previously been wetted. The arrow 39 depicts the direction of transport of the fiber structure 15.

[0077] FIG. 3 depicts an alternative embodiment for the application of the lines of the solution comprising monomer and optionally comprising activator, and optionally comprising catalyst.

[0078] In the embodiment depicted in FIG. 3, unlike in the embodiment depicted in FIG. 2, the lines 37 are applied in a zigzag shape. The lines here intersect in an axis of symmetry running centrally on the fiber structure 15, and the points at which the direction of application changes are, for each of the two lines 37, on a line running in the direction 39 of transport. In an example of a method permitting achievement of zigzag application, each of the nozzles 16 can be held in a linear unit 41, and in order to achieve symmetrical application here the linear units 41 are moved in opposite directions perpendicularly to the direction 39 of transport of the fiber structure 15.

[0079] FIGS. 4 and 5 depict other possible alternatives of possible modes of application of the solution comprising monomer and optionally comprising activator, and optionally comprising catalyst.

[0080] In the case of the embodiment depicted in FIG. 4, the solution comprising monomer and optionally comprising activator, and optionally comprising catalyst is applied in two line systems 43 to the fiber structure 15. In the embodiment depicted here, each line system 43 comprises two mutually overlapping zigzag lines 37 with axial symmetry. The individual line systems 43 here are likewise symmetrical with respect to an axis of symmetry running in the direction of transport of the fiber structure, but there is no contact between, or intersection of, the line systems 43.

[0081] In the embodiment depicted in FIG. 5, the solution comprising monomer and optionally comprising activator, and optionally comprising catalyst is applied in a plurality of parallel zigzag lines 37, and the individual lines 37 here respectively intersect, and the points at which the direction of the lines changes are respectively, for all of the lines, on a line located in the direction 39 of transport of the fiber structure.

[0082] Alongside the variants depicted here for the application of the solution comprising monomer and optionally comprising activator, and optionally comprising catalyst, any other variant or combination of the variants depicted here is also possible. The lines can moreover also have an undulating shape instead of the zigzag shape.

[0083] For the production of components, the flat fiber-reinforced semifinished product is inserted into a mold heated to a temperature at which the lactam polymerizes anionically to give the polyamide. The heating to a temperature above the onset temperature of the anionic polymerization polymerizes the lactam with which the textile structures have been saturated, to give the corresponding polyamide. The simultaneous compression converts the flat fiber-reinforced semifinished product to the desired shape of the component to be produced.

[0084] Examples of components that can be produced in this way are components of vehicle bodywork, structural components for vehicles, for example floors or roofs, constituent components for vehicles, for example assembly supports, seat structures, door cladding or interior cladding, and also components for wind turbines or rail vehicles.

KEY

[0085] 1 Apparatus for the production of flat fiber-reinforced semifinished products

[0086] 3 Flat fiber-reinforced semifinished product

[0087] 5 Polyamide foil

[0088] 7 Conveyor belt

[0089] 9 Roll with polyamide foil

[0090] 11 Fiber

[0091] 13 Roll holding fiber

[0092] 15 Fiber structure

[0093] 16 Nozzle

[0094] 17 Heat supply

[0095] 19 First inlet

[0096] 21 Second inlet

[0097] 23 Mixing unit

[0098] 24 Roll

[0099] 25 Saturated fiber structure

[0100] 27 Second polyamide foil

[0101] 29 Roll holding second polyamide foil

[0102] 31 Roll pair

[0103] 33 Cooling

[0104] 35 Cutter

[0105] 37 Line

[0106] 39 Direction of transport of fiber structure 15

[0107] 41 Linear unit

[0108] 43 Line system cm 1. A process for the production of saturated fiber structures, the process comprising: [0109] (a) introduction of a fiber structure onto a conveyor belt, [0110] (b) application of a solution comprising monomer in at least one line to the fiber structure, [0111] (c) passage of the fiber structure with the solution through at least one roll pair in which pressure is exerted on the fiber structure, and [0112] (d) cooling of the saturated fiber structure, so that the monomer solidifies.