Optical sensor device
09773926 · 2017-09-26
Assignee
Inventors
Cpc classification
H01L2224/48465
ELECTRICITY
H01L31/0203
ELECTRICITY
H01L31/02005
ELECTRICITY
H01L31/02164
ELECTRICITY
Y02E10/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01L2924/00012
ELECTRICITY
H01L2924/00014
ELECTRICITY
H01L2924/00
ELECTRICITY
H01L31/02322
ELECTRICITY
C03C3/21
CHEMISTRY; METALLURGY
H01L2924/00014
ELECTRICITY
H01L2924/00012
ELECTRICITY
H01L2924/00
ELECTRICITY
H01L2224/48465
ELECTRICITY
International classification
H01L31/0232
ELECTRICITY
C03C3/21
CHEMISTRY; METALLURGY
Abstract
An optical sensor device includes a resin sealing portion for sealing an optical sensor element fixed to an element-mounting portion. The resin sealing portion is constituted of a resin having mixed and dispersed therein a glass filler obtained by pulverizing a phosphate-based glass which has spectral luminous efficacy properties by composition adjustment and high heat resistance and weatherability. The optical sensor device is highly reliable and capable of accommodating size and thickness reductions in packages and has stable and hardly changeable spectral luminous efficacy properties.
Claims
1. An optical sensor device, comprising: an element-mounting portion; an optical sensor element fixed to the element-mounting portion; a lead frame in which one end is connected to the optical sensor element through a wire, and another end functions as an external terminal; and a resin sealing portion covering the element-mounting portion, the optical sensor element, and the lead frame, the resin sealing portion being entirely constituted by a resin in which glass filler obtained by pulverizing phosphate-based glass having specific spectral luminous efficacy properties is dispersed and mixed, and a composition of the phosphate-based glass having the specific spectral luminous efficacy properties containing, in terms of % by weight, 1) 40% to 60% of P.sub.2O.sub.5, 2) 20% to 40% of BaO, 3) Al.sub.2O.sub.3, La.sub.2O.sub.3, and Y.sub.2O.sub.3 in a total amount of 1% to 8%, 4) ZnO, MgO, CaO, and SrO in a total amount of 1% to 15%, 5) Li.sub.2O, Na.sub.2O, K.sub.2O in a total amount of 1% to 15%, 6) 3% to 10% of CuO, 7) 1% to 5% of V.sub.2O.sub.5, and 8) 1% to 5% of NiO.
2. The optical sensor device according to claim 1, wherein the resin sealing portion has characteristics in which a central peak of a transmittance is in a wavelength range of 540 nm to 560 nm, a transmittance in a wavelength range of 700 nm to 1200 nm is 2% or less, and a transmittance in a wavelength range of 300 nm to 430 nm is 3% or less.
3. The optical sensor device according to any claim 1, wherein a particle size of the glass filler is 1 μm to 20 μm.
4. The optical sensor device according to claim 1, wherein a part of the element-mounting portion is exposed from the resin sealing portion.
5. The optical sensor device according to claim 1, wherein the optical sensor device has a structure in which a periphery of the optical sensor element is sealed by a transfer mold method by using a tablet obtained by molding the resin in which filler obtained by pulverizing the phosphate-based glass having the specific spectral luminous efficacy properties is mixed.
6. An optical sensor device, comprising: an element-mounting portion; an optical sensor element fixed to the element-mounting portion; a lead frame in which one end is connected to the optical sensor element through a wire, and another end functions as an external terminal; and a resin sealing portion covering the element-mounting portion, the optical sensor element, and the lead frame, the resin sealing portion consisting of a first resin sealing portion that is constituted by a resin in which glass filler obtained by pulverizing phosphate-based glass having specific spectral luminous efficacy properties is dispersed and mixed, and a second resin sealing portion that is constituted by a resin in which glass filler obtained by pulverizing phosphate-based glass having specific light-shielding properties is dispersed and mixed.
7. The optical sensor device according to claim 6, wherein a composition of the phosphate-based glass having the specific spectral luminous efficacy properties contains, in terms of % by weight, 1) 40% to 60% of P.sub.2O.sub.5, 2) 20% to 40% of BaO, 3) Al.sub.2O.sub.3, La.sub.2O.sub.3, and Y.sub.2O.sub.3 in a total amount of 1% to 8%, 4) ZnO, MgO, CaO, and SrO in a total amount of 1% to 15%, 5) Li.sub.2O, Na.sub.2O, K.sub.2O in a total amount of 1% to 15%, 6) 3% to 10% of CuO, 7) 1% to 5% of V.sub.2O.sub.5, and 8) 1% to 5% of NiO; and wherein a composition of the phosphate-based glass having the specific light-shielding properties contains, in terms of % by weight, 1) 40% to 60% of P.sub.2O.sub.5, 2) 20% to 40% of BaO, 3) Al.sub.2O.sub.3, La.sub.2O.sub.3, and Y.sub.2O.sub.3 in a total amount of 1% to 8%, 4) ZnO, MgO, CaO, and SrO in a total amount of 1% to 15%, 5) Li.sub.2O, Na.sub.2O, K.sub.2O in a total amount of 1% to 15%, 6) 1% to 5% of CoO, 7) 3% to 10% of CuO, 8) 5% to 15% of V.sub.2O.sub.5, and 9) 1% to 5% of NiO.
8. The optical sensor device according to claim 6, wherein the first resin sealing portion has characteristics in which a central peak of a transmittance is in a wavelength range of 540 nm to 560 nm is in, a transmittance in a wavelength range of 700 nm to 1200 nm is 2% or less, and a transmittance in a wavelength range of 300 nm to 430 nm is 3% or less, and wherein the second resin sealing portion has characteristics in which a transmittance in a wavelength range of 300 nm to 1200 nm is 2% or less.
9. An optical sensor device, comprising: an optical sensor element; a mounting substrate on which the optical sensor element is provided; a through-electrode provided to pass through the mounting substrate, and in which a first end is connected to the optical sensor element and multi-ends become an external connection terminal; and a resin sealing portion covering upper surfaces of the mounting substrate and the optical sensor element, the resin sealing portion being entirely constituted by a resin in which glass filler obtained by pulverizing phosphate-based glass having specific spectral luminous efficacy properties is dispersed and mixed.
10. The optical sensor device according to claim 9, wherein a composition of the phosphate-based glass having the specific spectral luminous efficacy properties contains, in terms of % by weight, 1) 40% to 60% of P.sub.2O.sub.5, 2) 20% to 40% of BaO, 3) Al.sub.2O.sub.3, La.sub.2O.sub.3, and Y.sub.2O.sub.3 in a total amount of 1% to 8%, 4) ZnO, MgO, CaO, and SrO in a total amount of 1% to 15%, 5) Li.sub.2O, Na.sub.2O, K.sub.2O in a total amount of 1% to 15%, 6) 3% to 10% of CuO, 7) 1% to 5% of V.sub.2O.sub.5, and 8) 1% to 5% of NiO.
11. The optical sensor device according to claim 9, wherein the resin sealing portion has characteristics in which a central peak of a transmittance is in a wavelength range of 540 nm to 560 nm, a transmittance in a wavelength range of 700 nm to 1200 nm is 2% or less, and a transmittance in a wavelength range of 300 nm to 430 nm is 3% or less.
12. The optical sensor device according to claim 9, wherein the mounting substrate is provided with an element-mounting portion of which a part is exposed to an outer side in a through manner from a surface on which the optical sensor element is mounted to an opposite surface.
13. The optical sensor device according to claim 9, wherein the through-electrode is a lead frame that is bent at the inside of the mounting substrate, and is accommodated within the width of the mounting substrate, and a front end portion and a rear surface portion of the lead frame are exposed from a surface of the mounting substrate.
14. An optical sensor device, comprising: a mounting portion having a cavity; an optical sensor element fixed to a bottomed surface of the mounting portion; a lead frame in which one end is exposed to the bottomed surface and is connected to the optical sensor element through a wire, and another end is exposed from the mounting portion and functions as an external terminal; and a resin sealing portion with which the cavity is filled, the resin sealing portion being entirely constituted by a resin in which glass filler obtained by pulverizing phosphate-based glass having specific spectral luminous efficacy properties is dispersed and mixed, and a composition of the phosphate-based glass having the specific spectral luminous efficacy properties containing, in terms of % by weight, 1) 40% to 60% of P.sub.2O.sub.5, 2) 20% to 40% of BaO, 3) Al.sub.2O.sub.3, La.sub.2O.sub.3, and Y.sub.2O.sub.3 in a total amount of 1% to 8%, 4) ZnO, MgO, CaO, and SrO in a total amount of 1% to 15%, 5) Li.sub.2O, Na.sub.2O, K.sub.2O in a total amount of 1% to 15%, 6) 3% to 10% of CuO, 7) 1% to 5% of V.sub.2O.sub.5, and 8) 1% to 5% of NiO.
15. The optical sensor device according to claim 14, wherein the mounting portion is provided with an element-mounting portion of which a part is exposed to an outer side in a through manner from the bottomed surface to which the optical sensor element is fixed to an opposite surface.
Description
BRIEF DESCRIPTION OF DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
EMBODIMENTS OF THE INVENTION
(15) An optical sensor device of the invention has a structure in which the periphery of an element-mounting portion is sealed with a resin obtained by mixing phosphate-based glass, which has spectral luminous efficacy properties due to a specific composition and is pulverized into filler, in the resin.
(16) A resin, sealing portion is constituted by a resin in which glass filler obtained by pulverizing phosphate-based glass provided with spectral luminous efficacy properties through composition adjustment is dispersed and mixed. The periphery of optical sensor element and the element-mounting portion is constituted by a resin in which glass filler having spectral luminous efficacy properties is mixed, and the optical sensor element and the element-mounting portion come into close contact with the resin. The close contact resin is cured and constitutes a package.
(17) A composition of the phosphate-based glass having the spectral luminous efficacy properties contains,
(18) 1) 40% to 60% of P.sub.2O.sub.5,
(19) 2) 20% to 40% of BaO,
(20) 3) Al.sub.2O.sub.3, La.sub.2O.sub.3, and Y.sub.2O.sub.3 in a total amount of 1% to 8%,
(21) 4) ZnO, MgO, CaO, and SrO in a total amount of 1% to 15%,
(22) 5) Li.sub.2O, Na.sub.2O, K.sub.2O in a total amount of 1% to 15%,
(23) 6) 3% to 10% of CuO,
(24) 7) 1% to 5% of V.sub.2O.sub.5, and
(25) 8) 1% to 5% of NiO.
(26) According to the composition, the spectral luminous efficacy properties and higher weather resistance are provided in comparison to phosphate-based glass of the related art.
(27) The phosphate-based glass having the spectral luminous efficacy properties is pulverized glass filler in which a particle size has a dimension of approximately 1 μm to 20 μm, and preferably 1 μm to 3 μm. Glass filler that is pulverized is mixed with a resin, and the resultant mixture is kneaded. The kneaded mixture is made into a paste state or a slurry state after being subjected to de-foaming and compatibilization. According to this, a liquid resin shape in which glass filler is mixed is obtained. A lead frame or a substrate on which the optical sensor element is mounted is set in a resin sealing mold, and then the mold is filled with the glass filler-containing resin that is liquid state and the glass filler-containing resin is cured to obtain a package shape.
(28) It is possible to realize a structure in which the periphery of the optical sensor element mounted on the lead frame and the substrate, which do not have a cavity on an upper side of the element-mounting portion, is sealed with a resin. A metal or a member obtained by subjecting a resin to metallization is used as the lead frame, and a member formed from a resin, ceramic, a metal, glass, or silicon is used as the substrate. In addition, it is also possible to realize a structure in which the periphery of the optical sensor element, which is mounted on the lead frame and the substrate which have a cavity, is filled with a resin.
(29) Hereinafter, a configuration of the optical sensor device will be described reference to Examples on the basis of the accompanying drawings.
Example 1
(30)
(31) As an example of a manufacturing method, glass filler, which is obtained by pulverizing glass having spectral luminous efficacy properties into fine particles, is dispersed and mixed in a resin, and the resultant mixture is molded to a tablet. The periphery of the optical sensor element is sealed with the tablet by using a transfer mold method. According to this, the resin sealing portion 1 can be made as a package.
(32) The phosphate-based glass, which is made into glass filler, has spectral luminous efficacy properties, and a composition thereof contains, in terms of % by weight,
(33) 1) 40% to 60% of P.sub.2O.sub.5,
(34) 2) 20% to 40% of BaO,
(35) 3) Al.sub.2O.sub.3, La.sub.2O.sub.3, and Y.sub.2O.sub.3 in a total amount of 1% to 8%,
(36) 4) ZnO, MgO, CaO, and SrO in a total amount of 1% to 15%,
(37) 5) Li.sub.2O, Na.sub.2O, K.sub.2O in a total amount of 1% to 15%,
(38) 6) 3% to 10% of CuO,
(39) 7) 1% to 5% of V.sub.2O.sub.5, and
(40) 8) 1% to 5% of NiO.
(41) According to this composition, as shown in
(42) A comparison result of this example and a comparative example, which shows the effectiveness of the composition, is shown in Table 1. Although being relative evaluation, it can be confirmed that spectral luminous efficacy properties shown in
(43) TABLE-US-00001 TABLE 1 Addition amount (%) Present Comparative Comparative Comparative Composition Example A Example B Example C Example D P.sub.2O.sub.5 40 to 60 50 to 70 40 to 60 40 to 60 BaO 20 to 40 B.sub.2O.sub.3 1 to 10 SiO.sub.2 1 to 5 (Al.sub.2O.sub.3 + 1 to 8 10 to 30 10 to 30 La.sub.2O.sub.3 + Y.sub.2O.sub.3) (ZnO + MgO + 1 to 15 1 to 15 1 to 10 CaO + SrO) (Li.sub.2O + 1 to 15 1 to 15 10 to 30 10 to 30 Na.sub.2O + K.sub.2O) CuO 3 to 10 3 to 10 3 to 10 3 to 10 V.sub.2O.sub.5 1 to 5 1 to 5 1 to 5 1 to 5 NiO 1 to 5 1 to 5 1 to 5 1 to 5 Spectral ◯ (good) ◯ (good) X (poor) Δ (mediocre) luminous efficacy properties weather ◯ (good) X (poor) ◯ (good) X (poor) resistance
(44) According to the sealing structure using a resin obtained by dispersing and mixing filler glass, which is obtained from phosphate-based glass, in a resin, it is possible to obtain spectral luminous efficacy properties in which the transmittance in a short-wavelength region of 300 nm to 430 nm is 3% or less, and the transmittance in a long-wavelength range of 700 nm to 1200 nm is 2% or less, and the transmittance in a wavelength range of 540 nm to 560 nm is 50% or greater in a resin-sealed structure. In addition to this, it is possible to decease the coefficient of expansion of a resin by 30% or greater, and it is possible to obtain spectral luminous efficacy properties due to glass in which the transmittance in the wavelength range of 540 nm to 560 nm is greater than a transmittance in a configuration of using a resin dye or glass of the related art, and which is tolerant to spectral luminous efficacy heat or ultraviolet rays. As a result, it is possible to obtain a package having a resin-sealed structure with high reliability.
(45) The resin having the spectral luminous efficacy properties may be obtained by mixing filler glass obtained by pulverizing phosphate-based glass having wavelength characteristics in which the transmittance in a wavelength range of 700 nm to 1200 nm is 2% or less, and filler glass obtained by pulverizing phosphate-based glass having wavelength characteristics in which the transmittance in a wavelength range of 300 nm to 430 nm is 3% or less in a resin in a constant ratio.
Example 2
(46)
Example 3
(47)
(48) Here, the resin sealing portion 2 has a package structure in which sealing is performed with a mixture obtained by dispersing and mixing glass filler, which is obtained by pulverizing glass having light-shielding properties into fine particles, in a resin. Phosphate-based glass made into glass filler has light-shielding properties, and is intended to have the light-shielding properties in which the transmittance in a wavelength range of 300 nm to 1200 nm is 2% or less. A composition of the phosphate-based glass contains, in terms of % by weight,
(49) 1) 40% to 60% of P.sub.2O.sub.5,
(50) 2) 20% to 40% of BaO,
(51) 3) Al.sub.2O.sub.3, La.sub.2O.sub.3, and Y.sub.2O.sub.3 in a total amount of 1% to 8%,
(52) 4) ZnO, MgO, CaO, and SrO in a total amount of 1% to 15%,
(53) 5) Li.sub.2O, Na.sub.2O, K.sub.2O in a total amount of 1% to 15%,
(54) 6) 1% to 5% of CoO,
(55) 7) 3% to 10% of CuO,
(56) 8) 5% to 15% of V.sub.2O.sub.5, and
(57) 9) 1% to 5% of NiO.
(58) According to, this composition, it is possible to provide weather resistance higher than that of phosphate-based glass of the related art. In addition, it is possible to realize a package having a resin-sealed structure in which physical properties including the coefficient of expansion of the phosphate-based glass having light-shielding properties become close to those of the phosphate-based glass having the spectral luminous efficacy properties, a difference in the coefficient of expansion the resin sealing portion 1 and the resin sealing portion 2 does not matter, and the resin sealing portion 1 and the resin sealing portion 2 have the same high weather resistance level.
Example 4
(59)
Example 5
(60)
(61) In addition, instead of a configuration in which light beams are reflected from or scattered on the outer peripheral surface of the resin sealing portion, it is also possible to employ a configuration in which light beams are reflected or scattered on an inner side of the resin sealing portion. For example, the periphery of the element is sealed with a resin in which particles such as silica, alumina, and frosted glass which have refractive indexes different from each other are dispersed and mixed in a resin in a constant amount. According to this, light reception sensitivity having spectral luminous efficacy properties is obtained from light beams incident from an upper surface direction of the optical sensor element, and light beams incident from the periphery other than the upper surface direction of the element are scattered and attenuated, and do not reach an element surface.
Example 6
(62)
Example 7
(63)
Example 8
(64)
(65) According to this, in the optical sensor device 14, it is possible to reduce a mounting area, and it is easy to reduce a size. In addition, the mounting substrate 12 is formed from a resin, ceramic, and the like. Accordingly, it is possible to realize a package having high strength and durability with respect to a substrate portion to which a stress such as thermal history and a load, or impact in accordance with mounting is directly transferred. In addition, in the mounting substrate 12, the element-mounting portion 7 may be omitted. In this case, the optical sensor element 4 is mounted on a surface of the mounting substrate formed from a resin, ceramic, and the like.
Example 9
(66)
Example 10
(67)
Example 11
(68)
Example 12
(69)
INDUSTRIAL APPLICABILITY
(70) With regard to an optical sensor device using a package having a structure in which the periphery of the optical sensor element is sealed with a resin, when using a structure in which the sealing is performed with a resin in which glass filler obtained by pulverizing newly developed phosphate-based glass having spectral luminous efficacy properties due to a specific composition is dispersed and mixed, the spectral luminous efficacy properties of light beams, which are received by the light reception optical sensor element, can have directivity of a wide angle including not only an immediate upward direction of the optical sensor element but also an oblique direction or a lateral direction, and it is possible to greatly improve angle dependency.
(71) The phosphate-based glass having the spectral luminous efficacy properties according to the invention has transmittance characteristics in which the transmittance of light beams of a wavelength in an ultraviolet region and the transmittance of light beams of a wavelength in an infrared region is 3% to 2%, and has a composition having high heat-resistant properties and high weather resistance due to glass. Accordingly, in comparison to a configuration in which the spectral luminous efficacy properties are provided with a resin, an absorption rate of the ultraviolet wavelength and the infrared wavelength is higher and more satisfactory spectral luminous efficacy properties is obtained for a long period of time. In addition, the phosphate-based glass has high reliability that is less susceptible to heat, ultraviolet rays, and moisture. According to this, it, is possible to provide an optical sensor device having characteristics which are less susceptible to the ambient environment and in which a variation with the passage of time is small. As a result, the phosphate-based glass can contribute to supply of the optical sensor device to a television, a household electric appliance, and a portable terminal, and further an optical sensor device mounted apparatus with concern of an in-vehicle use or an outdoor use in more severe environments.
REFERENCE SIGNS LIST
(72) 1: Resin sealing portion in which phosphate-based glass filer having spectral minions efficacy properties is included in resin 2: Resin sealing portion in which phosphate-based glass filler having light-shielding properties is included in resin 3: Die attaching agent 4: Optical sensor element 5: Wire 6a, 6b: Lead frame 7: Element-mounting portion 8: Element-mounting portion having heat dissipation property 9: Light-transmitting resin 10: Optical scattering and diffusing wrinkle processed surface 11a, 11b: Through-electrode 12: Optical sensor element mounting substrate 13: Mounting portion having cavity 14: Optical sensor device