FIBRE-REINFORCED COMPONENTS
20170320278 · 2017-11-09
Inventors
Cpc classification
B29C43/18
PERFORMING OPERATIONS; TRANSPORTING
B29C70/081
PERFORMING OPERATIONS; TRANSPORTING
B29C70/86
PERFORMING OPERATIONS; TRANSPORTING
B29C45/14786
PERFORMING OPERATIONS; TRANSPORTING
B29C45/14418
PERFORMING OPERATIONS; TRANSPORTING
B29C70/12
PERFORMING OPERATIONS; TRANSPORTING
B29C70/76
PERFORMING OPERATIONS; TRANSPORTING
International classification
B29C70/86
PERFORMING OPERATIONS; TRANSPORTING
B29C43/18
PERFORMING OPERATIONS; TRANSPORTING
B29C70/12
PERFORMING OPERATIONS; TRANSPORTING
B29C70/08
PERFORMING OPERATIONS; TRANSPORTING
B29C70/76
PERFORMING OPERATIONS; TRANSPORTING
B29C45/14
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method for forming a composite component, comprising: locating a rigid composite element comprising a matrix interspersed with long fibre reinforcement in a mould that is shaped to define a cavity about the rigid element; loading a material comprising a matrix precursor interspersed with short fibre reinforcement into the cavity; and curing the matrix precursor.
Claims
1. A method for forming a composite component, comprising: locating a rigid composite element comprising a matrix interspersed with long fibre reinforcement in a mould that is shaped to define a cavity about the rigid element; loading a material comprising a matrix precursor interspersed with short fibre reinforcement into the cavity; and curing the matrix precursor.
2. A method as claimed in claim 1, wherein a first part of the mould is shaped to fit to the contours of the rigid element and a second part of the mould is shaped to define the cavity around the rigid element, and the step of locating comprises closing the mould against the rigid element without substantially altering the shape of the rigid element.
3. A method as claimed in claim 1, wherein the rigid element is hollow in the region adjacent the cavity.
4. A method as claimed in claim 1, wherein the method comprises, prior to the loading step, heating the mould to a temperature at which the matrix of the rigid element will soften.
5. A method as claimed in claim 4, wherein the temperature to which the mould is heated is between the glass transition temperature of the matrix of the rigid element and 20° C. above that temperature.
6. A method as claimed in claim 4, wherein the rigid element is hollow in the region adjacent the cavity, and wherein the step of closing the mould comprises indenting the mould into the surface of the rigid element so as to seal the cavity.
7. A method as claimed in claim 1, wherein the mould comprises a first part of the mould and a second part of the mould, the first part of the mould comprising a mould body and at least one mould slider moveable between an extended position and a retracted position relative to the mould body, and the step of locating comprises closing the mould against the rigid element by: bringing the at least one mould slider, in the extended position, into contact with a second part of the mould, closing the first part of the mould and the second part of the mould around the rigid composite element so that the mould slider moves between the extended position and the retracted position.
8. A method as claimed in claim 7, wherein the step of bringing the at least one mould slider into contact with a second part of the mould comprises securing the rigid composite element in the second part of the mould by the at least one mould slider.
9. A method as claimed in claim 1, wherein the rigid composite element comprises at least one projection, the mould is shaped to fit against the contours of the surfaces of the projection facing away from the cavity, and the step of locating comprises locating at least one projection at an edge the cavity.
10. A method as claimed in claim 1, wherein the rigid composite element comprises at least one projection, the mould is shaped to fit against the contours of the surfaces of the projection not facing the cavity, and the step of locating comprises locating at least one projection at an edge the cavity.
11. A method as claimed in claim 9, wherein the mould seals against at least one the projection to substantially inhibit flow of the matrix precursor out of the cavity.
12. A method as claimed in any of claim 9, wherein a first part of the mould is shaped to fit to the contours of the rigid element and a second part of the mould is shaped to define the cavity around the rigid element, and the step of locating comprises locating at least one projection at an edge of the cavity of the second part of mould.
13. A method as claimed in claim 9, wherein the projection extends away from the exterior surface of the rigid composite element.
14. A method as claimed in claim 1, wherein the method comprises, heating the said material to a temperature at which the matrix of the rigid element will soften.
15. A method as claimed in claim 14, wherein the temperature to which the said material is heated is between the glass transition temperature of the matrix of the rigid element and 20° C. above that temperature.
16. A method as claimed in claim 14, wherein the method comprises heating the said material to the said temperature after loading it into the cavity.
17. A method as claimed in claim 14, wherein the method comprises heating the said material to the said temperature before loading it into the cavity.
18. A method as claimed in claim 1, wherein the long fibre reinforcement comprises fibres longer than 50 cm.
19. A method as claimed in claim 1, wherein the said material comprises fibres shorter than 10 cm.
20. A method as claimed in claim 1, wherein the said material comprises no fibres longer than 10 cm.
21. A method as claimed in claim 1, comprising the step of forming the rigid composite element by resin transfer moulding.
22. A method as claimed in claim 1, wherein the rigid composite element is a tub for a vehicle.
23. A method as claimed in claim 22, wherein the cavity is adjacent to a portion of the tub forming part of a crash structure.
24. A method as claimed in claim 23, wherein the material injected into the cavity defines a structural feature of the crash structure.
25. A method as claimed in claim 22, wherein the cavity is adjacent to an A-pillar of the tub.
26. A method as claimed in claim 25, wherein the material injected into the cavity defines a feature running lengthwise along the A-pillar.
27. A method as claimed in claim 26, wherein the feature is one of a flange for carrying a door seal and a flange for bonding glass to.
28. A method as claimed in claim 1, comprising, prior to the step of loading, coating at least a part of the surface of the rigid element with an adhesive, wherein that part of the surface is overlain by the cavity.
29. A method as claimed in claim 28, wherein the adhesive is applied as a peelable film.
30-44. (canceled)
Description
[0039] The present invention will be described by way of example with reference to the accompanying drawings. In the drawings:
[0040]
[0041]
[0042]
[0043]
[0044]
[0045]
[0046]
[0047]
[0048]
[0049] In the examples described below a rigid vehicle tub is formed as a long-fibre composite element, for example by resin transfer moulding. Then the tub is transferred to another mould which accommodates all or part of the tub and defines one or more mould cavities adjacent to the outer surface of the tub. That second mould is shaped so as to conform to the exterior contours of part or all of the tub. That mould is sealed against the outer surface of the tub 11, and then a material comprising a fluid matrix precursor in which short reinforcing fibres have been dispersed loaded into the mould cavities. The matrix precursor is cured, leaving the material in the cavities adhered to the tub as overmoulded elements. The overmoulded elements could contribute substantially to the structural strength of the tub. Similar principles could be adopted for parts other than vehicle tubs.
[0050]
[0051] The walls forming the tub frame are formed of rigid, cured epoxy in which are embedded long runs of carbon fibre. The fibre could be in the form of tow, mats or individual fibres. The mean length of the fibres in the walls could be greater than 10 cm or 50 cm. The fibres are laid up in a way that strengthens the tub frame against the stresses expected to be imposed on it in use. Typically most parts of the walls will contain multiple layers of reinforcing fibre. In each tube element of the tub frame the fibres may run generally longitudinally and/or generally circumferentially. Fibres running generally circumferentially are known as hoop fibres.
[0052]
[0053] The tub frame as shown in
[0054] The tub frame is preferably formed by RTM: that is by the positioning of reinforcing fibres in a mould, followed by the injection of liquid resin into the mould, followed by the curing of the resin to rigidify the moulded component. A vacuum may be drawn in the mould before the resin is injected, and the vacuum may then pull the resin into the mould. The mould may be heated to promote curing of the resin. Alternative methods may be used to form the tub frame. For example it could be formed by laying up mats of reinforcing fibre that have been pre-impregnated with resin (prepreg) and then curing the resin.
[0055]
[0056]
[0057] The tub frame is then inserted into a mould whose mould cavity accommodates the tub frame but defines volumes around at least some parts of the tub frame.
[0058] Prior to being contacted with the SMC material the tub is fully cured and rigid.
[0059] Next SMC material is loaded into the mould cavity. In one approach, the SMC material may be in the form of a semi-rigid body comprising resin and short fibres. That body can be loaded together with the tub frame into the mould cavity. Then the mould can be closed. In this approach the closing of the mould shapes the SMC body to the mould cavity and forces the SMC body into intimate contact with the adjacent surfaces of the tub frame. The pressure exerted as the mould closes causes the SMC body to flow plastically so as to fill the volumes 24, 25, 26 between the exterior surface of the tub frame and the surface of the mould cavity. In this approach the ports 27 can be omitted, or can be used to draw a vacuum in the mould cavity after the mould is closed. In another approach the SMC material may initially be in a liquid form comprising a mixture of liquid resin and short fibres. Once the mould is closed with the tub in place within it the liquid SMC material can be loaded into the mould be injecting it through multiple ports 27 extending from the exterior of the mould bodies to the volumes 24, 25, 26. Before the SMC material is injected the mould cavity may be evacuated so as to reduce the chance of air being trapped in the mould when the SMC materials is injected.
[0060]
[0061] The position within the mould body 22 of the or each moveable member 70, 71 may be selected so that the moveable member(s) engage with the A-pillar 20 prior to the closing of the main mould body 69 against the other mould bodies that surround the A-pillar 20. In this configuration, the moveable member(s) 70, 71 secure the A-pillar within the first mould body 21 prior to the closure of the main mould body 69 of second mould body 22 against the first mould body 21. The securing of the A-pillar may prevent any SMC material from flowing around the A-pillar 20 prior to the closure of the main mould body 69. As shown in
[0062]
[0063] As shown in the close-up view of
[0064] The mould body may be shaped so as to comprise complimentary regions in the surface of the mould cavity that lie adjacent the exterior surface of the projections. In this way, the complimentary regions in the surface of the mould cavity can seal against the exterior surface of the projections to limit or prevent flow of SMC material out of the free volume. The mould body surface, in the complimentary regions, and the surface of the projections may be controlled to tight tolerances so as to ensure the necessary engagement between the mould body and the exterior surface of the tub frame is achieved to prevent overspill of SMC material.
[0065] Once the SMC material is in place in the mould volume it is cured (e.g. through the application of heat) and the resulting component is removed from the mould.
[0066] The SMC material is a liquid matrix precursor (e.g. curable resin) which contains a multiplicity of short reinforcing fibres.
[0067] It is preferred that substantially all the short reinforcing fibres are free from each other so that the SMC material can flow readily into the mould cavity. The fibres are preferably distributed substantially uniformly in the liquid precursor. The fibres may be orientated randomly, or there may be preferential orientation of the fibres due, for example, to the flow behaviour of the liquid precursor when it is compressed by the closing of the mould or is injected into the mould. The proportion of fibres contained in the SMC material will depend on the properties of the materials and the desired application, but it could be between 40% and 60% in volume fraction. The mean length of the short fibres is preferably in the range from 10 mm to 60 mm. The liquid matrix precursor could be a resin, for example an epoxy, nylon, polyester resin or vinyl ester resin. The fibres could be fibres of a material having higher tensile strength than the cured matrix material. The fibres could, for example, be carbon fibre, glass fibre or fibres of a polymer such as an aramid.
[0068] Once the SMC material has been loaded or injected into the mould cavity the mould is heated to cause the matrix precursor to cure and solidify, e.g. by cross-linking. Then the mould is opened and the solid moulded final tub is removed.
[0069]
[0070] Elements such as flanges 31, 32 and rib 33 could alternatively be manufactured separately from the tub frame and then attached to the tub frame with adhesive or with screws or bolts. However, by overmoulding the additional elements, as described above, a much greater degree of adhesion can be achieved between the additional elements and the tub frame. In that way the overmoulded elements can contribute significantly to the strength of the final tub. In designing the tub, calculations for operational or crash loads on structural elements of the tub, including crash structures, can take into account the contribution to strength provided by the overmoulded elements. Thus the overmoulded elements can be structural parts of the vehicle, contributing substantially to the strength of the final tub. Examples of crash protection structures include forward and rear beams extending from a passenger cell to forward and rear bumpers respectively, side beams for resisting sideways ingress into a passenger cell and roll-over protection systems such as A-pillars and roll-over hoops or struts.
[0071] The overmoulded elements illustrated in
[0072] The adhesion of the overmoulded elements to the tub frame can be enhanced if the matrix of the overmoulded elements is of the same or substantially the same material as the matrix of the matrix of the tub frame. For example, they could both be of the same structural polymer or of polymers having substantially the same coefficient of thermal expansion once cured.
[0073]
[0074] In the arrangements of
[0075] In the illustrated examples the SMC material is moulded against the exterior surface of a region of the tub frame that is hollow. That means that the material of the tub against which the SMC material exerts pressure (e.g. when it is shaped during closing of the mould) has a void on its opposite face to the SMC material. The mould does not directly press against that opposite face because it is enclosed by the tub body. When the mould is not present directly behind the part of the tub body on which the SMC material is pressing there is a risk that the tub body will flex during the moulding process. This raises a number of difficulties. First, it is more difficult to achieve a seal between the mould and the tub structure to prevent the SMC material from spreading outside the mould. Second, it is possible that the tub structure might be permanently deformed, either through overloading or because the SMC material sets with the hollow tub part in a deformed condition.
[0076] It has been found that the performance of the final tub structure is improved if the mould 21, 22, 41 used to form the SMC structure is heated to a temperature at which the matrix material of the tub frame will soften. That temperature will depend on the nature of the matrix material, but it may be above the glass transition temperature (T.sub.g) of the matrix material. The temperature to which the mould body/bodies is/are heated is preferably not more than 10° C. or 20° C. above T.sub.g of the matrix material. Instead of this, or in addition, the SMC material may be heated to such a temperature during the process of curing it. It is believed that elevating the temperature of the mould and/or the SMC material in this way can help to relieve stress in the tub frame that could otherwise arise from the overmoulding of the SMC material. Furthermore, when the rim of the mould cavity abuts the tub frame as shown in
[0077] Sealing of the mould 41 against the tub frame 40 can also be enhanced by providing significant hoop fibres in the tub frame at the region where the mould 41 is to seal against it. For example, those sections of reinforcing fibre that are orientated at 45° or more to the principal longitudinal axis of the hollow part of the tub that is being overmoulded may constitute more than 10% or more than 15% or more than 20% of the total length of reinforcing fibres in that hollow part of the tub. Those sections of reinforcing fibre that are orientated at 45° or less to a plane transverse to the extent of the cavity running along the hollow part of the tub that is being overmoulded may constitute more than 10% or more than 15% or more than 20% of the total length of reinforcing fibres in that hollow part of the tub. It has been found that when the mould cavity is closed so as to deform the already-loaded SMC material, or SMC material is injected into the mould cavity, there can be a tendency for the tub frame member, being hollow, to deform inwards. That deformation can break the seal of the mould against the tub frame member, allowing SMC material to leak from the mould cavity. The tub frame can be strengthened against that deformation by means of hoop fibres in the region where the mould 41 is to be applied.
[0078] Some commercially available SMC compounds contain a release agent to help the cured SMC component to be released from a mould. If such SMC compounds are used to overmould the tub frame then it can be advantageous to take additional steps to improve adhesion between the SMC overmould and the tub frame. One way to achieve that is to coat the tub frame with adhesive in the region where the SMC component is to be overmoulded before the tub frame is located in or against the mould for the SMC component. The adhesive could be applied as a liquid to the appropriate region. More conveniently it could be applied as a sheet. For example, the adhesive could initially be provided on a backing sheet which is coated with a release layer and an adhesive layer over the release layer. Then the adhesive side of the sheet can be located against the appropriate region and the backing sheet removed, leaving the adhesive stuck to the tub frame.
[0079] Any suitable material could be used for the matrix material of each of the initially formed element and the matrix material of the overmoulded element. Each matrix material could be a polymer, for example, an epoxy, a nylon, a polyester or a vinyl ester. The matrix materials could be different or the same. Preferably the matrix material of the initially formed element is capable of softening to a limited extent at a temperature suitable for curing the matrix material of the overmoulded element. For example, a suitable temperature for curing the matrix material of the overmoulded element may be in the range from the T.sub.g of the matrix material to 10° C. or 20° C. above that T.sub.g. Any suitable material could be used for the reinforcing fibres of each of the initially formed element and the reinforcing fibres of the overmoulded element. Each fibre material could, for example, be carbon fibre, glass fibre or a polymer fibre such as an aramid fibre. The fibre materials could be different or the same.
[0080] The initially formed element can be a continuous fibre element. That is, it can be formed of fibres having a length greater than 10 cm, or greater than 20 cm, or greater than 30 cm, or greater than 50 cm, or greater than 1 m.
[0081] In the examples discussed above, the initially formed element is a vehicle tub. The initially formed element could be for any appropriate purpose: for example it could be a vehicle seat, a bicycle frame, a vehicle suspension element or a casing for a mobile phone. More than one initially formed element could be inserted into the mould for the overmoulding process, and they could be joined together by the overmould. The initially formed element could be formed by RTM or by any other suitable process.
[0082] In a normal automobile the surfaces of the A-pillar that are exposed inside the cabin are covered in interior trim and energy absorbing materials in order to reduce the damage that might result from an occupant's head impacting the A-pillar.
[0083]
[0084] The cover layer may cover extend only over the rearward-facing part of the A-pillar, or it may extend a little on to the lateral surface, as shown in
[0085] The applicant hereby discloses in isolation each individual feature described herein and any combination of two or more such features, to the extent that such features or combinations are capable of being carried out based on the present specification as a whole in the light of the common general knowledge of a person skilled in the art, irrespective of whether such features or combinations of features solve any problems disclosed herein, and without limitation to the scope of the claims. The applicant indicates that aspects of the present invention may consist of any such individual feature or combination of features. In view of the foregoing description it will be evident to a person skilled in the art that various modifications may be made within the scope of the invention.