APPARATUS AND METHOD FOR FORMING A POLYMERIC WEB
20170266860 · 2017-09-21
Inventors
Cpc classification
B29C48/17
PERFORMING OPERATIONS; TRANSPORTING
B29C48/335
PERFORMING OPERATIONS; TRANSPORTING
B29C48/387
PERFORMING OPERATIONS; TRANSPORTING
B29C48/0255
PERFORMING OPERATIONS; TRANSPORTING
B29C48/21
PERFORMING OPERATIONS; TRANSPORTING
B29C48/70
PERFORMING OPERATIONS; TRANSPORTING
B29L2007/008
PERFORMING OPERATIONS; TRANSPORTING
B29C48/25
PERFORMING OPERATIONS; TRANSPORTING
B29C48/0015
PERFORMING OPERATIONS; TRANSPORTING
B29C48/32
PERFORMING OPERATIONS; TRANSPORTING
B29C48/0018
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
The present invention is directed to an apparatus for forming a multi-layer web formed from at least two polymeric film tubes in intimate contact with each other but not bonded to each other. The apparatus and method includes the use of a blown film extrusion die that extrudes two separate blown film polymeric tubes via two separate annular die lips. A fluid cooling system applies cooling fluid across a plurality of surfaces of the two blown film tubes. One of the die lips may be at a different height from the other die lip. The frost line of one blown film tube may be at a different height from the other blown film tube.
Claims
1. An apparatus for forming a multi-layer polymeric web from multiple collapsed tubes, comprising: a first source of a first molten polymer, a second source of a second molten polymer a blown film extrusion die comprising: an outer die lip comprising an annular opening, wherein the outer die lip extrudes the first molten polymer to form an outer polymeric film tube having an outer frost line, an inner die lip comprising an annular opening, the inner die lip surrounded by the outer die lip, wherein the inner die lip extrudes the second molten polymer to form an inner polymeric film tube within the outer polymeric film tube, the inner polymeric film tube having an inner frost line, and wherein a height of the inner frost line is different from a height of the outer frost line, an outer bubble external cooling source directing cooling fluid onto an exterior of the outer polymeric film tube, and an inner bubble interior cooling source directing cooling fluid onto an interior of the inner polymeric film tube wherein the outer and inner polymeric film tubes are placed in intimate contact with each other but not bonded to each other.
2. The apparatus of claim 1 further comprising: an elevation of the outer die lip different from an elevation of the inner die lip.
3. The apparatus of claim 2 further comprising: the outer die lip at a lower elevation than the inner die lip.
4. The apparatus of claim 1 further comprising: the height of the outer frost line lower than the height of the inner frost line.
5. The apparatus of claim 1 further comprising: an intermediate cooling source directing cooling fluid onto an interior of the outer polymeric film tube and an exterior of the inner polymeric film tube.
6. The apparatus of claim 5 further comprising: an intermediate exhaust that exhausts cooling fluid from an interior of the outer polymeric film tube and an exterior of the inner polymeric film tube.
7. The apparatus of claim 1 further comprising: an inner bubble interior exhaust that exhausts fluid from the interior of the inner polymeric tube.
8. The apparatus of claim 1 further comprising: the height of the inner frost line and the outer frost line below a location where the inner and outer polymeric film tubes initially come into contact with each other.
9. The apparatus of claim 1 further comprising: a characteristic of the first molten polymer different from a characteristic of the second molten polymer.
10. The apparatus of claim 9 further comprising: the characteristic of the first molten polymer differing from the characteristic of the second molten polymer due to a coloring agent added to at least one of the first and second molten polymers.
11. A process for forming a multi-layered polymeric film tube comprising: providing a first source of a first molten polymer, providing a second source of a second molten polymer, wherein a characteristic of the first molten polymer differs from a characteristic of the second molten polymer, extruding the first molten polymer from an outer die lip of an extrusion die, wherein an outer polymeric film tube is formed, the outer polymeric film tube having an outer frost line, extruding the second molten polymer from an inner die lip of the extrusion die, wherein an inner polymeric film tube is formed, the inner polymeric film tube having an inner frost line, wherein the inner die lip is surrounded by the outer die lip and the inner frost line is at a different height than the outer frost line, directing cooling fluid onto an exterior of the outer polymeric film tube by an outer bubble external cooling source, directing cooling fluid onto an interior of the inner polymeric film tube by an inner bubble interior cooling source, collapsing the outer and inner polymeric tubes so that the tubes are placed into intimate contact with each other.
12. The process of claim 11 further comprising: the inner die lip at a higher elevation than the outer die lip.
13. The process of claim 11 further comprising: the height of the outer frost line lower than the height of the inner frost line.
14. The process of claim 11 further comprising: directing from a single cooling fluid supply a cooling fluid onto an interior of the outer polymeric film tube and an exterior of the inner polymeric film tube.
15. The process of claim 11 further comprising: the first molten polymer comprising a different color than the second molten polymer.
16. An apparatus for forming a multi-layered tube of polymeric film, comprising: a first extruder extruding a first molten polymeric stream, a flow splitter splitting the first molten polymeric stream into a second polymeric stream and a third polymeric stream, a static mixer mixing at least one additive to the second polymeric stream, a first die path supplying the second polymeric stream to a first die lip, a second die path supplying the third polymeric stream to a second die lip, a first die lip extruding a first polymeric tube supplied by the first die path, a second die lip extruding a second polymeric tube supplied by the first die path, the second die lip located within the first die lip, a set of nip rollers collapsing the first and second polymeric tubes and placing the tubes in intimate contact with each other.
17. The apparatus of claim 16 further comprising: the first die lip at a lower height than the second die lip.
18. The apparatus of claim 16 further comprising: the first polymeric tube having a first frost line and the second polymeric tube having a second frost line, and the first frost line lower than the second frost line.
19. The apparatus of claim 16 further comprising: an interior of the first polymeric tube and an exterior of the second polymeric tube both cooled by a cooling fluid supplied by a single cooling source.
20. The apparatus of claim 16 further comprising: the second polymeric tube comprising a high stalk.
Description
BRIEF DESCRIPTION OF THE RELATED DRAWINGS
[0021] A full and complete understanding of the present invention may be obtained by reference to the detailed description of the present invention and described embodiments when viewed with reference to the accompanying drawings. The drawings can be briefly described as follows.
[0022]
[0023]
[0024]
[0025]
[0026]
[0027]
[0028]
DETAILED DESCRIPTION OF THE INVENTION
[0029] The present disclosure illustrates one or more embodiments of the present invention. It is not intended to provide an illustration or encompass all embodiments contemplated by the present invention. In view of the disclosure of the present invention contained herein, a person having ordinary skill in the art will recognize that innumerable modifications and insubstantial changes may be incorporated or otherwise included within the present invention without diverging from the spirit of the invention. Therefore, it is understood that the present invention is not limited to those embodiments disclosed herein. The appended claims are intended to more fully and accurately encompass the invention to the fullest extent possible, but it is fully appreciated that certain limitations on the use of particular terms is not intended to conclusively limit the scope of protection.
[0030]
[0031] As further shown in
[0032] Nip rollers 108 are also shown in
[0033] Internal fluid pressure within each bubble 110o and 110i applies outward pressure on each plastic film tube 106o and 106i, leading to the diameter of each bubble 110o and 110i expanding. As each plastic film tube 106o and 106i rises, it cools, solidifying from a molten state to a solid state as it expands to its final diameter and thickness. As used throughout this disclosure, the term tube typically refers to the tubular shaped film extruded from each die lip and the term bubble typically refers to the tubular structure of film and the volume encased by the tubular structure between the corresponding die lip and nip rollers. However, the terms tube and bubble may be used interchangeably throughout the disclosure due to the close inter-relationship between the two terms in the blown film extrusion process.
[0034] As further shown in
[0035] Shown in
[0036] Shown in
[0037] As the molten material is extruded from each die lip 104o and 104i, separate molten plastic film tubes 106o and 106i emerge. Outer die lip 104o extrudes outer plastic or polymer film tube 106o and inner die lip 104i extrudes inner polymeric film tube 106i. Since inner die lip 104i is within outer die lip 104o, inner tube 106i is located within outer tube 106o.
[0038] In at least one embodiment, one or both of film tubes 106o and 106i may comprise multiple discrete layers of polymeric resin formed by a coextrusion process as known in the art where multiple layers are combined in the die prior to exiting from the die. Since the layers are extruded together in a molten state, the layers are bonded to adjacent layers, presuming that adjacent layers comprise compatible resins.
[0039] The height or location at which each tube transitions from a molten polymer to a solid polymer is typically referred to as a frost line. Since the polymer is solidified once above the frost line, the film typically fails to expand any further above the frost line. The frost line for a given blown film extrusion process can vary depending upon process conditions. Hence, the relative desired range of the frost line contemplated by the invention is shown by frost line regions 112o and 112i in
[0040] Outer frost line region 112o corresponds to outer tube 106o and outer bubble 110o. Inner frost line region 112i corresponds to inner tube 106i and inner bubble 110i. The lower portion of each plastic film tube below frost line regions 112o and 112i is generally molten while the upper portion of each plastic film tube above each corresponding frost line region is generally solid. The inner frost line region 112i is shown at a relatively lower height in
[0041] The invention contemplates that outer tube 106o transitions from a molten polymer to a solid polymer at a different height than inner tube 106i and prior to coming into contact with inner tube 106i. Hence, as shown in
[0042] The frost line of inner tube 106i is ideally controlled so that frost line of inner tube 106i is at or just below the contact point 140 as shown by
[0043] As the film of a blown film bubble approaches closer to the frost line, the film gradually transitions from a molten to a solid state. Hence, the invention contemplates that even if the contact point 140 is reached prior to the inner bubble becoming fully solidified as shown in
[0044] In at least one embodiment of the invention, inner tube 106i may not expand to the same or a substantially similar diameter for the inner tube 106i to come into contact with the outer tube 106o when expanded. However, the two tubes will still come into contact with each when they pass through nip rollers 108 and are collapsed on to each other. Such an arrangement ensures that inner tube 106i has fully transitioned to solid film prior to coming into contact with outer tube 106o. Once passing through the nip rollers 108, the film of the two tubes will be placed in intimate contact with each other, but the outer edges of flattened inner tube 106i will be slightly recessed from the outer edges of flattened outer tube 106o.
[0045] Depending upon the resin composition of the inner and outer tubes and process conditions, the two films may experience a certain amount of blocking, but the invention contemplates that the two adjacent films do not bond to each other. Whether the films of the inner and outer tubes bond to each other is partly dependent upon the material of the two films and, in particular, each film's crystallinity. Thus, the invention contemplates that in one preferred embodiment, use of a linear low-density polyethylene (LLDPE) or low-density polyethylene (LDPE) polymer for the outer tube 106o and a high-density polyethylene (HDPE) polymer for the inner tube 106i may be used to assist in preventing the film of the two tubes from bonding to each other.
[0046] Other polymers, such as nylon or polypropylene, may be used in conjunction with each other or with polyethylene polymers, which may also provide for non-adherence between the individual tubes. In conjunction with incompatible polymers or standing alone, one or more additives may be used to prevent the film of the tubes from adhering to each other. For instance, calcium carbonate (CaCO.sub.3) may be added to the polymer of one or both tubes during the extrusion process to assist in preventing the film of the two tubes from adhering to each other. Use of CaCO.sub.3 may also be used in one of the tubes or to a greater extent in the polymer of one of the tubes, such as the outer tube, to lower the frost line of the tube since CaCO.sub.3 increases the cooling rate for a given molten polymer.
[0047] Rather than varying the composition of individual tubes to prevent bonding between adjacent surfaces of the outer and inner tubes 106o and 106i, materials may be injected between the bubbles of the two tubes to prevent bonding of the adjacent surfaces. For instance, a vaporized or atomized liquid may be injected between the two bubbles 110o and 110i of the outer and inner tubes 106o and 106i during the blown film extrusion process. Such a liquid can be utilized to accelerate the cooling of the adjacent surfaces of the outer and inner bubbles 110o and 110i by lowering each surface's temperature. Furthermore, the injected liquid could include a volatile scented compound to add a pleasing scent to the final product. Adding a scented compound in between the layers may be an alternative to adding a scented compound to the molten polymers as is commonly known in the art for forming scent polymeric bags. The liquid could also include anti-blocking agents to prevent the layers from adhering or blocking with each other.
[0048] Rather than a liquid, dry materials such as a finely granulated or powder-like substance may be injected between the two bubbles. Such a dry material may be injected between the layers with the use of the cooling fluid of the intermediate cooling source as a carrier of the powder-like substance. The powder-like substance may have anti-blocking or scented properties as discussed above regarding an injected liquid material.
[0049] The rate at which the film of the outer and inner tubes 106o and 106i cool and hence the height of their frost lines may be controlled by additional methods. For instance, the film of the outer tube 106o may be formed thinner than the film of the inner tube 106i; and hence encourage cooling of outer tube 106o at a faster rate since less material per a given length will require cooling. Furthermore, the amount of cooling fluid delivered to the outer tube 106o may be greater than the amount of cooling fluid delivered to the inner tube 106i. A greater amount of cooling fluid delivered to the outer tube 106o than to inner tube 106i will encourage cooling of the outer tube at a faster rate and hence assist in moving its frost line lower in relation to the frost line of the inner tube 106i. The temperature of the cooling fluid deliverer to the outer tube 106o can also be lower, or its cooling capacity increased, to also encourage faster cooling of the outer bubble 106o.
[0050] Controlling the final diameter and film thickness of each plastic film tube 106o and 106i are, among other factors, the air pressure within the interior of each plastic film tube or bubble, the cooling rate provided by cooling system 114, the speed of the nip rollers 108, and the amount of resin pushed through each extrusion die lip 102o and 102i by the one or more extruders. Most importantly in the present invention, embodiments of cooling system 114 are disclosed to facilitate the forming of outer tube 106o and inner tube 106i within desired dimensions, process conditions, and at commercially reasonable throughput rates.
[0051] As shown in
[0052] As previously mentioned,
[0053] Shown furthest from the center of the polymeric tubes in
[0054] As further shown in
[0055] As shown best by
[0056] Returning to
[0057] As also shown in
[0058] As shown in
[0059] Further shown in
[0060] Prior to the cooling fluid entering common exhaust 124, the cooling fluid may pass through an exhaust shroud 126 covering the common exhaust 124 as shown in
[0061] In an alternative embodiment to the blown film extrusions system shown in
[0062] Further shown in
[0063] Further shown in
[0064] As further shown in
[0065] As further illustrated in
[0066] In at least one embodiment, the formation of inner film tube 106i with a high-stalk bubble may be aided with the use of a high molecular weight (HMW) polymeric resin. Furthermore, due to the relative small initial diameter of the inner film tube 106i, the blow up ratio (BUR) of the tube may be considerably larger, as shown in
[0067] Now turning to
[0068] One alternative is illustrated by
[0069] Once divided into two separate streams, each polymer stream 505a and 505b is shown passing through a corresponding gear pump 506a or 506b, or similar pump device, to increase each polymer stream's pressure. Once each polymer stream exits one of the gear pumps, it is shown passing through a corresponding static mixer, a first static mixer 508a or second static mixer 508b.
[0070] Prior to entering each gear pump or static mixer, one or more additives or resin modifiers may be added to each polymer stream. The one or more additives may consist of a colorant, another resin modifier such as a slip agent, or a combination of additives. The addition of the one or more additives may be used to modify a characteristic of one of the polymer streams 505a and 505b such that one polymer stream has at least one characteristic different from the other polymer stream. Since the disclosure, in at least a preferred embodiment, contemplates the use of a gear pump and static mixer, the one or more additives or resin modifiers would preferably be in the form of a liquid supplied by a liquid pump. In an alternative embodiment, a dedicated extruder may be used to supply modifiers in solid form to the extruder and then supplied to the resin stream at the same location in molten form.
[0071] When each polymer stream 505a and 505b pass through a corresponding static mixer, the one or more additives are distributed throughout each flow of molten polymer. Once the two separate polymer streams 505a and 505b pass through a corresponding static mixer, the separate polymer streams are shown in
[0072] Rather than the flow being split from a single extruder as discussed above in regards to
[0073] As shown by
[0074] Dual extruder blown film extrusion system 600 provides a simpler system with greater flexibility in material selection in comparison to single extruder extrusion system 500. However, single extruder extrusion system 500 provides a more efficient system in comparison to system 500 since only one extruder is required. Hence, system 500 allows more efficient transition from a typical mono-extrusion blown film process to a bubble-in-bubble extrusion system as contemplated by the disclosed invention. System 500 also allows for formation of a multilayer web from a bubble-in-bubble process with each web or flattened tube having differing properties, such as each layer comprising a different color when at least one colorant agent is added to one of the independent polymer streams 505a and 505b.
[0075] As previously noted, the specific embodiments depicted herein are not intended to limit the scope of the present invention. Indeed, it is contemplated that any number of different embodiments may be utilized without diverging from the spirit of the invention. Therefore, the appended claims are intended to more fully encompass the full scope of the present invention.