Generation and enhancement of surface acoustic waves on a highly doped p-type III-V semiconductor substrate
11211913 · 2021-12-28
Assignee
Inventors
Cpc classification
H03H9/6426
ELECTRICITY
H01L29/20
ELECTRICITY
International classification
Abstract
A device employing the generation and enhancement of surface acoustic waves on a highly doped p-type III-V semiconductor substrate (e.g., GaAs, GaSb, InAs, or InGaAs). The device includes two SiO.sub.2/ZnO islands, each including a SiO.sub.2 buffer layer deposited on the doped p-type III-V semiconductor substrate and a ZnO layer deposited on the SiO.sub.2 buffer layer. An input interdigital transducers (IDT) and an output IDT are each patterned on one of the SiO.sub.2/ZnO islands. The IDTs generates surface acoustic waves along an exposed surface of the highly doped p-type III-V semiconductor substrate. The surface acoustic waves improve the photoelectric and photovoltaic properties of the device. The device is manufactured using a disclosed technique for propagating strong surface acoustic waves on weak piezoelectric materials. Also disclosed is a photodetector developed using that technique.
Claims
1. A device, comprising: a doped p-type III-V semiconductor substrate; two silicon dioxide (SiO.sub.2) and zinc oxide (ZnO) islands, each of the SiO.sub.2/ZnO islands comprising a SiO.sub.2 buffer layer deposited on the doped p-type III-V semiconductor substrate and a ZnO layer deposited on the SiO.sub.2 buffer layer; two interdigital transducers (IDTs) each patterned on one of the SiO.sub.2/ZnO islands; and an exposed surface of the doped p-type III-V semiconductor substrate between the two SiO.sub.2/ZnO islands.
2. The device of claim 1, wherein: the IDTs include an input IDT that generates surface acoustic waves and an output IDT that receives the surface acoustic waves.
3. The device of claim 2, wherein the input IDT generates surface acoustic waves along the exposed surface of the doped p-type III-V semiconductor substrate.
4. The device of claim 3, wherein: the doped p-type III-V semiconductor substrate has a (100) surface and a [011] direction; and the input IDT generates surface acoustic waves along the [011] direction of the doped p-type III-V semiconductor substrate.
5. The device of claim 1, wherein the SiO.sub.2 buffer layer of each SiO.sub.2/ZnO island has a thickness of at least 800 nanometers.
6. The device of claim 1, wherein the doped p-type III-V semiconductor substrate is gallium arsenide.
7. The device of claim 1, wherein the doped p-type III-V semiconductor substrate is gallium antimonide, indium arsenide, or indium gallium arsenide.
8. A method of making a device, the method comprising: depositing a silicon dioxide (SiO.sub.2) buffer layer on a doped p-type III-V semiconductor substrate; depositing a zinc oxide (ZnO) layer on the SiO.sub.2 buffer layer; patterning two interdigital transducers (IDTs) on the ZnO layer; and etching a portion of the ZnO layer and the SiO.sub.2 buffer layer between the two IDTs to form two ZnO/SiO.sub.2 islands, each supporting one of the two IDTs, and an exposed surface of the doped p-type III-V semiconductor substrate between the two IDTs.
9. The method of claim 8, wherein: the IDTs include an input IDT that generates surface acoustic waves and an output IDT that receives the surface acoustic waves.
10. The method of claim 9, wherein the input IDT is patterned such that it generates surface acoustic waves along the exposed surface of the doped p-type III-V semiconductor substrate.
11. The method of claim 10, wherein: the doped p-type III-V semiconductor substrate has a (100) surface and a [011] direction; and the input IDT is patterned such that it generates surface acoustic waves along the [011] direction of the doped p-type III-V semiconductor substrate.
12. The method of claim 8, wherein the SiO.sub.2 buffer layer is deposited such that it has a thickness of at least 800 nanometers.
13. The method of claim 8, wherein the doped p-type III-V semiconductor substrate is gallium arsenide.
14. The method of claim 8, wherein the doped p-type III-V semiconductor substrate is gallium antimonide, indium arsenide, or indium gallium arsenide.
15. A photodetector, comprising: a III-V semiconductor substrate; a silicon dioxide (SiO.sub.2) buffer layer deposited on the doped p-type III-V semiconductor substrate; a two-dimensional (2D) material comprising a single layer of atoms on the III-V semiconductor substrate; two zinc oxide (ZnO) islands deposited on the SiO.sub.2 buffer layer on either side of the 2D material; two interdigital transducers (IDTs) patterned on each of the two ZnO islands, the two IDTs including an input IDT that generates surface acoustic waves and an output IDT that receives the surface acoustic waves, a source electrode; a drain electrode; and a gate electrode.
16. The photodetector of claim 15, wherein the input IDT generates surface acoustic waves along the surface of the 2D material.
17. The photodetector of claim 15, wherein a current between the source electrode and the drain electrode varies in response to visible or infrared light that is incident to the 2D material.
18. The photodetector of claim 15, wherein transmission characteristics of the surface acoustic waves vary in response to visible or infrared light that is incident to the 2D material.
19. The photodetector of claim 15, wherein the III-V semiconductor substrate is gallium antimonide.
20. The photodetector of claim 15, wherein the doped p-type III-V semiconductor substrate is gallium arsenide, indium arsenide, or indium gallium arsenide.
21. A device, comprising: a doped p-type III-V semiconductor substrate with a crystalline surface; a piezoelectric coupling layer that increases the intensity of surface acoustic waves on the doped p-type III-V semiconductor substrate; a buffer layer, deposited on the doped p-type III-V semiconductor substrate below the piezoelectric coupling layer, that masks the crystalline surface of the doped p-type III-V semiconductor substrate and increases the piezoelectricity of the piezoelectric coupling layer; two interdigital transducers (IDTs), each patterned on piezoelectric coupling layer and the buffer layer, that increases the intensity of surface acoustic waves on the doped p-type III-V semiconductor substrate; an exposed surface of the doped p-type III-V semiconductor substrate, between the two IDTs.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The accompanying drawings are incorporated in and constitute a part of this specification. It is to be understood that the drawings illustrate only some examples of the disclosure and other examples or combinations of various examples that are not specifically illustrated in the figures may still fall within the scope of this disclosure. Examples will now be described with additional detail through the use of the drawings, in which:
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DETAILED DESCRIPTION
(12) In describing the illustrative, non-limiting embodiments illustrated in the drawings, specific terminology will be resorted to for the sake of clarity. However, the disclosure is not intended to be limited to the specific terms so selected, and it is to be understood that each specific term includes all technical equivalents that operate in similar manner to accomplish a similar purpose. Several embodiments are described for illustrative purposes, it being understood that the description and claims are not limited to the illustrated embodiments and other embodiments not specifically shown in the drawings may also be within the scope of this disclosure.
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(14) As shown in
(15) According to the literature, SAWs propagating along the [011] direction on (100) GaAs are piezoelectric, while along directions like [001] or [010] are not piezoelectric. Therefore, if the p-type GaAs substrate 190 is a p-type (100) GaAs substrate 190, the metal IDTs 120 in the SAW delay line may be oriented along the [011] direction on the p-type (100) GaAs substrate 190. Alternatively, if the GaAs substrate 190 is a (001) GaAs substrate 190, the metal IDTs 120 in the SAW delay line may be oriented along the [110] direction on the (001) GaAs substrate 190. The SAW is generated through the input IDT 110, which are carried on the ZnO/SiO.sub.2 island 150 with the RF signals applied by the source 170. The SAW then propagates along the delay line (varied from 500 μm to 2 mm) on the exposed surface 192 of the p-type GaAs substrate 190. The output IDT 130 is used to receive the incoming SAW and to calculate the power transmission ratio.
(16) The metal IDTs 120 may be conventional, single-finger IDTs. The spacing between each IDT finger may be the same as the finger width. In this case, according to the concept and theory of SAW, the wavelength of SAW is equal to four times of the width of an IDT finger when the SAW is launched with the fundamental frequency of the IDT. As the propagating speed of the SAW in each specific material is known, the center frequency of the SAW can be determined. According to literature, the SAW velocity in ZnO varies from 2600 m/s to 5000 m/s depending on the thickness and structure, and the SAW velocity in GaAs is approximately 2700 m/s to 2900 m/s. Because the SAW completely propagates on the exposed surface 192 of the p-type GaAs substrate 190 along the delay line, the center frequency may be determined by the finger widths of the IDTs 130 and the SAW velocity in the GaAs substrate 190.
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(18) In step 202, process 200 starts with the highly doped p-type (100) GaAs wafer 190 as substrate. The doping concentration of the substrate may range from 5×10.sup.18 cm.sup.−3 to 3×10.sup.19 cm.sup.−3. The GaAs wafer 190 may be cleaned, for example by applying acetone and isopropyl alcohol (IPA) as well as using a sonicator if necessary. The wafer 190 has a wafer top surface and a wafer bottom surface.
(19) A SiO.sub.2 buffer layer 160 is deposited on the wafer top surface in step 204. For example, a plasma-enhanced chemical vapor deposition (PECVD) method may be used, with an optimized recipe to deposit on top of GaAs substrate at a rate of 120 nanometers/minute. The buffer layer 160 has a buffer top surface and a buffer bottom surface, and in the embodiment shown the buffer bottom surface contacts the wafer top surface.
(20) A thin ZnO layer 140 is deposited on top of the SiO.sub.2 buffer layer 160 in step 206. For example, a radio frequency (RF) magnetron sputtering system may be used to deposit the thin ZnO layer 140. The ZnO layer 140 has a ZnO top surface and a ZnO bottom surface, and in the embodiment shown the ZnO bottom surface contacts the buffer top surface. Accordingly, the buffer layer 140 is sandwiched between the wafer 190 and the ZnO layer 140.
(21) Metal IDTs 120 are patterned on the ZnO top surface of the ZnO layer 140 in step 208. As described above, the input IDT 110 may be patterned to generate SAWs propagating along the [011] direction of the GaAs wafer 190. To transfer the pattern, a polymethyl methacrylate (PMMA) A4 photoresist may be spin coated on top of the ZnO layer 140 (for example, with a speed of 3000 rpm for two minutes). The device 100 may be baked, for example on hotplate with temperature of 180° C. for 2 minutes. The spin-coating and heating process may be repeated (e.g., once more). A process of e-beam exposure (for example, with a Raith Voyager Electron Beam Lithography (EBL) system) may be used to transfer the pattern onto the surface. The patterned photoresist may be developed, for example in a methyl isobutyl ketone (MIBK) solution for 90 seconds. Aluminum IDT 120 electrode fingers are formed, for example using metallization with an e-beam evaporator. The unwanted photoresist structure may then be lifted off, for example with acetone for 20 minutes, to get the IDT 120 electrode fingers on the ZnO top surface of the ZnO layer 140.
(22) The center portion of the SiO.sub.2 buffer layer 160 and the ZnO layer 140 are etched to expose a portion of the p-type GaAs substrate 190 and form the exposed surface 192 (which is a portion of the wafer top surface) between the two ZnO/SiO.sub.2 islands 150 in step 210. For example, another layer of photoresist may be spin coated on top of the ZnO layer 140 using the same method described above. The e-beam exposure process may then be conducted again, for example with the Raith Voyager EBL system, to transfer the second pattern on top center of the device 100. The second pattern may be used to etch the SiO.sub.2 buffer layer 160 and the ZnO layer 140 and expose the exposed surface 192 of the p-type GaAs substrate 190 as shown in
(23) As mentioned above, the ZnO layer 140 has a strong piezoelectric coupling effect that efficiently converts the electrical energy into mechanical energy and increases the intensity of the SAWs on the GaAs substrate 190. For a stronger piezoelectric effect, the ZnO layer 140 should preferably be deposited with a high quality c-plane facing up, as SAW cannot be generated and transmitted strongly on a low quality ZnO surface. The recipe of RF magnetron sputtering system includes many parameters—such as plate temperature, gas flow ratio, VAT pressure, time length, pre-sputter and sputter power—that each have its impact on the deposition results. Through experiments, it has been determined that a high quality ZnO layer 140 may be deposited using a RF magnetron sputtering method with a sputtering condition that includes power (P) of 400 Watts (W), a temperature (T) of 250° C., argon and oxygen (Ar/O.sub.2) of 50 standard cubic centimeters per minute (sccm) and 11 sccm, pressure of 8 millitorr (mtorr), and a time of 2 hours. That optimized sputtering condition may be used to grow a high-quality c-axis oriented ZnO film 140 (with a thickness of 1100 nanometers) on the p-type GaAs substrate 190.
(24) By contrast, a ZnO film (with a thickness of 1400 nm) grown using a nonoptimized condition (P=350 W, T=130° C., Ar/O.sub.2=69 sccm/0 sccm, pressure=17 mtorr, t=2 hour) is a lower quality ZnO deposition with very rough and cracked surface that cannot be used to generate SAWs because of the difficulty to pattern and deposit metal IDTs 120. The optimized recipe, however, produces a high quality deposited ZnO layer 140 with a smooth and clean surface and small ZnO grain size. The high quality ZnO film 140 grown using the optimized recipe has much higher intensity of (002) peak, less amount of off-oriented crystals, a reduced built-in lattice strain, and reduced full width at half maximum (FWHM) value of the (002) x-ray diffraction (XRD) reflection line. Therefore, with the optimized recipe, a highly textured and highly c-axis oriented ZnO layer 140 may be grown on the p-type GaAs substrate 190.
(25) Growing the high-quality ZnO layer 140 described above on the SiO.sub.2 buffer layer 160 described above also improves the crystal orientation of the high-quality ZnO layer 140 along the c-axis direction. Deposited ZnO film 140 on a sample with the added SiO.sub.2 buffer layer 160 using the same optimized RF sputtering recipe produces a more visible hexagonal crystal structure with increased grain size, a higher intensity of (002) peak, a reduced built-in lattice strain, and a reduced FWHM value of the (002) XRD reflection line. Therefore, a high-quality ZnO layer 140 can be formed with a SiO.sub.2 buffer layer 160 added between the ZnO film 140 and the p-type GaAs substrate 190.
(26) The layers 140, 160, and 190 of the device 100 may have any shape, though in the embodiment shown in step 210 the top and bottom surfaces of each of the layers 140, 160, 190 can be substantially flat (i.e., thin and planar) and formed as a square or rectangle. As further illustrated at step 206, the ZnO layer 140 may have the same area as the SiO.sub.2 buffer layer 160 so that the ZnO layer 140 fully covers the SiO.sub.2 buffer layer 160. However, in other embodiments, the ZnO layer 140 can have larger or smaller area than the SiO.sub.2 buffer layer 160. Because the GaAs substrate 190 is larger than the ZnO/SiO.sub.2 islands 150, the ZnO/SiO.sub.2 islands 150 only partially cover the GaAs substrate 190 and leave an exposed surface 192 of the GaAs substrate 190 between the ZnO/SiO.sub.2, islands 150. The width of the exposed surface 192 between the ZnO/SiO.sub.2 islands 150 may vary depending on the desired characteristics of the SAWs generated by the IDTs 120.
(27) While the process 200 is described above with reference to a p-type GaAs substrate 190, the same process may be used to generate and enhance SAWs on other III-V semiconductor materials that have good photoelectric properties but weak piezoelectricity, such as gallium antimonide (GaSb), indium arsenide (InAs), and indium gallium arsenide (InGaAs). The process 200 provides the foundation for using SAWs to improve a variety of III-V semiconductor-based optoelectronic devices 100, such as photocathodes, photomultipliers, photodetectors, etc.
(28) Additionally, while the process 200 is described above with reference to a ZnO layer 140, the same process may be used to deposit another piezoelectric material—such as lithium niobite (LiNbO3) and aluminum nitrate (AlN), etc.—to form a piezoelectric coupling layer with a strong piezoelectric coupling effect that increases the intensity of surface acoustic waves on the III-V semiconductor surface.
(29) Finally, while the process 200 is described above with reference to a SiO.sub.2 buffer layer 160, the same process may be used to deposit another material that masks the crystalline surface of the III-V semiconductor substrate and increases the quality of the piezoelectric coupling layer.
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(33) All of the test results shown in
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(35) As discussed above, the center frequency of a SAW is determined by the dimensions of the IDTs 120 and the SAW velocity in the specific material (in this instance, the GaAs substrate 190). As shown in
(36) This center frequency shift with the change of finger widths of the IDTs 120 (from 0.9 μm to 2.3 μm) is consistent with the theory that smaller finger widths of IDTs 120 leads to a proportionally higher center frequency of SAW resonance in a specific piezoelectric material (the GaAs substrate 190). The results show the capability of the device 100 in propagating SAWs with different frequencies on the highly doped p-type GaAs substrate 190. In addition, by comparing the two cases, we can see that a SAW with a higher frequency has a better transmission performance on the p-type GaAs surface 190 with the help of the ZnO/SiO.sub.2 islands 150.
(37) As mentioned above, the application of dynamic strain and electric fields of surface acoustic waves has been used as a successful tool for industrial applications such as filters, resonators and sensors. As a result, many electronic systems currently available incorporate SAW-based signal processing devices. SAWs also have many advantages in other research fields, such as being able to manipulate optically generated electronic excitations in semiconductors and to improve the quantum efficiency (QE) of optoelectronic devices. However, in most cases, SAWs can only be generated and propagated along piezoelectric materials. This greatly limits the utilization of SAWs for optoelectronic and acoustoelectric hybrid applications because most commonly used piezoelectric materials—including ZnO (3.1 eV-3.4 eV), AlN (6.0 eV-6.2 eV) and LiNbO.sub.3 (3.5 eV-4.7 eV)—have wide band-gap that limits their applications in photoelectric devices.
(38) Two-dimensional (2D) materials, sometimes referred to as single-layer materials, are crystalline materials consisting of a single layer of atoms. The nanostructures of 2D materials have been studied and used for the transistor-based photodetection, due to their unique optoelectronic properties.
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(40) A bias voltage is applied between the source electrode 542, the drain electrode 544, and the gate electrode 546. The photodetector 500 is then able to detect light applied onto the 2D material film 520, whether the light is visible or IR. The current I.sub.SD flowing between the source electrode 542 and the drain electrode 544 increases when the photodetector 500 detects visible light and decreases when the photodetector 500 detects IR light as shown in the current v. time graph of
(41) The key factor to extend the photodetection spectrum of the photodetector 500 to IR range is the substrate material that has a small band gap to absorb photons in IR range, and then to modulate the band diagram of 2D material. Therefore, in addition the GaSb substrate 560 shown in
(42) In addition to the transistor-based photodetection (measuring source-drain current) described above, the transmission characteristics (S.sub.21, S.sub.11) of the SAW may also independent provide good sensing information. SAW sensors have been widely used for photodetection because of their advantages such as small size, low cost, fast response, and high sensitivity. When the 2D material film 520 and the surface of the GaSb (or InAs or InGaAs) substrate 560 is illuminated by the incident light, the photo-excited carriers inside the surface materials will interact with the piezoelectric field induced by the propagating SAW, which will result in change of the SAW amplitude, phase and velocity. Therefore, by using the output IDT 130 to receive and measure the SAW signal on the other side of the photodetector 500, the SAW-based photodetection (measuring SAW transmission characteristics) may be simultaneously achieved and utilized to provide additional sensing information. As shown in the amplitude v. frequency graph in
(43) The photodetector 500, which developed using the technique of propagating strong SAWs on weak piezoelectric materials (such as the highly doped p-type GaAs substrate 190 described above) has a number of advantages. Unlike conventional single layer two-dimensional material photodetectors, the detection range of the two-dimensional material photodetector 500 is extended to IR spectrum. Also, the IR photodetection performance, such as the light-to-dark current ratio and the minimum detection limit of the IR intensity, is improved by the SAW for over an order of magnitude. In addition to the transistor-based photodetection (measuring source-drain current), the SAW-based photodetection by the output IDT 130 (measuring SAW transmission characteristics) may be utilized simultaneously to provide additional detection information to further increase the sensitivity and selectivity of the photodetection device 500. This unique advantage makes it possible to build a multi-sensory IR photodetector 500 on one single surface.
(44) The foregoing description and drawings should be considered as illustrative only of the principles of the disclosure, which may be configured in a variety of shapes and sizes and is not intended to be limited by the embodiment herein described. Numerous applications of the disclosure will readily occur to those skilled in the art. Therefore, it is not desired to limit the disclosure to the specific examples disclosed or the exact construction and operation shown and described. Rather, all suitable modifications and equivalents may be resorted to, falling within the scope of the disclosure.