Recycled PET foam material and method for manufacturing the same

Abstract

A recycled PET foam material and a manufacturing method thereof are characterized in that a recycled material can be used. The manufacturing method includes the following steps: uniformly mixing PET resin, chain extender, antioxidant, flame retardant and heat stabilizer, and then mixing with a twin-screw extruder to obtain a foam PET resin. The PET foaming material obtained is a material having the advantages of light weight, large rigidity, high specific strength, good electrical insulation, good sound insulation and the like, low raw material cost, simple manufacturing process and environmental protection.

Claims

1. A recycled PET foam material, comprising: 1) 86 to 98.3 wt % of a recycled PET; 2) 1 to 10 wt % of chain extender which is 2,2,4,4-diphenyltetracarboxylic acid; 3) 0.1 to 1.0 wt % of antioxidant; 4) 0.5 to 2.0 wt % of nucleating agent; and 5) 0.1 to 1.0 wt % of heat stabilizer.

2. The recycled PET foam material according to claim 1, wherein the recycled PET has a relative density of 1.35 to 1.40 g/cm.sup.3, a melting point of 250 to 260° C., and an intrinsic viscosity of 0.55 to 0.95 dL/g.

3. The recycled PET foam material according to claim 1, wherein the antioxidant is selected from one or any combination of pentaerythritol tetrakis(3,5-di-tert-butyl-4-hydroxy)phenylpropionate, phenyl tris(2,4-di-tert-butyl)phosphite and 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoic acid stearyl alcohol ester.

4. The recycled PET foam material according to claim 1, wherein the nucleating agent is selected from one or any combination of barium sulfate, calcium citrate, calcium carbonate and talcum powder.

5. The recycled PET foam material according to claim 4, wherein the calcium citrate has an average particle diameter from 3 μm to 8 μm, and the talcum powder has an average particle diameter from 1 μm to 4 μm.

6. The recycled PET foam material according to claim 1, wherein the heat stabilizer is a phosphorus compound stabilizer.

7. A method for manufacturing a recycled PET foam material, comprising: Step 1: weighing 86 to 98.3 wt % of a recycled PET, 1 to 10 wt % of 2,2,4,4-diphenyltetracarboxylic acid being a chain extender, 0.1 to 1.0 wt % of antioxidant, 0.1 to 1.0 wt % of a heat stabilizer, and 0.5 to 2.0 wt % of nucleating agent, and the total of each component is 100% by weight; Step 2: vacuum drying the PET at 140° C. for 12 hours, and drying the chain extender, the antioxidant, the nucleating agent, and the heat stabilizer in the vacuum at 80° C. for 8 hours; Step 3: mixing the in portion recycled PET, the chain extender, the antioxidant, the nucleating agent, and the heat stabilizer, stirring in a high-speed mixer for 10 minutes, and then putting into a foaming extruder; and Step 4: controlling heating conditions of the foaming extruder, a temperature in a first zone at 290-300° C., a temperature in a second zone at 280-300° C., a temperature in a third zone at 275-295° C., and a temperature in a fourth zone at 275-295° C., a temperature in a fifth zone at 260-280° C., a die temperature at 250-280° C., a screw speed is 30-100 rpm, and a foaming gas is fed at a rate of 0.5 to 3 kg/hr for foaming.

8. The method for manufacturing a recycled PET foam material according to claim 7, wherein the foaming gas is selected from one or any combination of nitrogen, carbon dioxide, hydrocarbons, and fluorocarbons.

Description

DETAILED DESCRIPTION OF THE EXEMPLARY EMBODIMENTS

(1) The present disclosure is more particularly described in the following examples that are intended as illustrative only since numerous modifications and variations therein will be apparent to those skilled in the art. Like numbers in the drawings indicate like components throughout the views. As used in the description herein and throughout the claims that follow, unless the context clearly dictates otherwise, the meaning of “a”, “an”, and “the” includes plural reference, and the meaning of “in” includes “in” and “on”. Titles or subtitles can be used herein for the convenience of a reader, which shall have no influence on the scope of the present disclosure.

(2) The terms used herein generally have their ordinary meanings in the art. In the case of conflict, the present document, including any definitions given herein, will prevail. The same thing can be expressed in more than one way. Alternative language and synonyms can be used for any term(s) discussed herein, and no special significance is to be placed upon whether a term is elaborated or discussed herein. A recital of one or more synonyms does not exclude the use of other synonyms. The use of examples anywhere in this specification including examples of any terms is illustrative only, and in no way limits the scope and meaning of the present disclosure or of any exemplified term. Likewise, the present disclosure is not limited to various embodiments given herein. Numbering terms such as “first”, “second” or “third” can be used to describe various components, signals or the like, which are for distinguishing one component/signal from another one only, and are not intended to, nor should be construed to impose any substantive limitations on the components, signals or the like.

Embodiment 1

(3) The recycled PET foam material of the embodiment 1 is made by the following raw materials and the total of each component is 100% by weight:

(4) 96.5 wt % of recycle PET, 2.0 wt % of chain extender, 0.5 wt % of antioxidant, 0.5 wt % of nucleating agent, and 0.5 wt % of heat stabilizer.

(5) The manufacturing method is as follows:

(6) 1. The recycle PET material is vacuum dried at 140° C. for 12 hours.

(7) 2. The chain extender, antioxidant, nucleating agent, heat stabilizer are vacuum dried at 80° C. for 8 hours.

(8) 3. The above raw materials are mixed in proportion according to the parts by weight, placed in a high-speed mixer for 10 minutes, and then put into a twin-screw foaming extruder.

(9) Foaming gas: nitrogen, fed at a rate of 1 kg/hr.

(10) Extrusion temperature of extrusion machine: 295° C. in a first zone, 290° C. in a second zone, 285° C. in a third zone, 285° C. in a fourth zone, and 270° C. in a fifth zone.

(11) Screw speed: 45 rpm.

(12) Die temperature: 265° C.

Embodiment 2

(13) The recycled PET foam material of the embodiment 2 is made by the following raw materials and the total of each component is 100% by weight:

(14) 91.5 wt % of recycle PET, 7.0 wt % of chain extender, 0.5 wt % of antioxidant, 0.5 wt % of nucleating agent, and 0.5 wt % of heat stabilizer.

(15) The manufacturing method is as follows:

(16) 1. The recycle PET material is vacuum dried at 140° C. for 12 hours.

(17) 2. The chain extender, antioxidant, nucleating agent, heat stabilizer are vacuum dried at 80° C. for 8 hours.

(18) 3. The above raw materials are mixed in proportion according to the parts by weight, placed in a high-speed mixer for 10 minutes, and then put into a twin-screw foaming extruder.

(19) Foaming gas: nitrogen, fed at a rate of 1 kg/hr.

(20) Extrusion temperature of extrusion machine: 295° C. in a first zone, 290° C. in a second zone, 285° C. in a third zone, 285° C. in a fourth zone, and 270° C. in a fifth zone.

(21) Screw speed: 45 rpm.

(22) Die temperature: 265° C.

Embodiment 3

(23) The recycled PET foam material of the embodiment 3 is made by the following raw materials and the total of each component is 100% by weight:

(24) 90.0 wt % of recycle PET, 7.0 wt % of chain extender, 0.5 wt % of antioxidant, 0.2 wt % of nucleating agent, and 0.5 wt % of heat stabilizer.

(25) The manufacturing method is as follows:

(26) 1. The recycle PET material is vacuum dried at 140° C. for 12 hours.

(27) 2. The chain extender, antioxidant, nucleating agent, heat stabilizer are vacuum dried at 80° C. for 8 hours.

(28) 3. The above raw materials are mixed in proportion according to the parts by weight, placed in a high-speed mixer for 10 minutes, and then put into a twin-screw foaming extruder.

(29) Foaming gas: nitrogen, fed at a rate of 1 kg/hr.

(30) Extrusion temperature of extrusion machine: 295° C. in a first zone, 290° C. in a second zone, 285° C. in a third zone, 285° C. in a fourth zone, and 270° C. in a fifth zone.

(31) Screw speed: 45 rpm.

(32) Die temperature: 265° C.

Embodiment 4

(33) The recycled PET foam material of the embodiment 4 is made by the following raw materials and the total of each component is 100% by weight:

(34) 96.5 wt % of recycle PET, 2.0 wt % of chain extender, 0.5 wt % of antioxidant, 0.5 wt % of nucleating agent, and 0.5 wt % of heat stabilizer.

(35) The manufacturing method is as follows:

(36) 1. The recycle PET material is vacuum dried at 140° C. for 12 hours.

(37) 2. The chain extender, antioxidant, nucleating agent, heat stabilizer are vacuum dried at 80° C. for 8 hours.

(38) 3. The above raw materials are mixed in proportion according to the parts by weight, placed in a high-speed mixer for 10 minutes, and then put into a twin-screw foaming extruder.

(39) Foaming gas: carbon dioxide, fed at a rate of 1.2 kg/hr.

(40) Extrusion temperature of extrusion machine: 295° C. in a first zone, 290° C. in a second zone, 285° C. in a third zone, 285° C. in a fourth zone, and 270° C. in a fifth zone.

(41) Screw speed: 45 rpm.

(42) Die temperature: 265° C.

Embodiment 5

(43) The recycled PET foam material of the embodiment 5 is made by the following raw materials and the total of each component is 100% by weight:

(44) 91.5 wt % of recycle PET, 7.0 wt % of chain extender, 0.5 wt % of antioxidant, 0.5 wt % of nucleating agent, and 0.5 wt % of heat stabilizer.

(45) The manufacturing method is as follows:

(46) 1. The recycle PET material is vacuum dried at 140° C. for 12 hours.

(47) 2. The chain extender, antioxidant, nucleating agent, heat stabilizer are vacuum dried at 80° C. for 8 hours.

(48) 3. The above raw materials are mixed in proportion according to the parts by weight, placed in a high-speed mixer for 10 minutes, and then put into a twin-screw foaming extruder.

(49) Foaming gas: carbon dioxide, fed at a rate of 1.2 kg/hr.

(50) Extrusion temperature of extrusion machine: 295° C. in a first zone, 290° C. in a second zone, 285° C. in a third zone, 285° C. in a fourth zone, and 270° C. in a fifth zone.

(51) Screw speed: 45 rpm.

(52) Die temperature: 265° C.

Embodiment 6

(53) The recycled PET foam material of the embodiment 6 is made by the following raw materials and the total of each component is 100% by weight:

(54) 90.0 wt % of recycle PET, 7.0 wt % of chain extender, 0.5 wt % of antioxidant, 2.0 wt % of nucleating agent, and 0.5 wt % of heat stabilizer.

(55) The manufacturing method is as follows:

(56) 1. The recycle PET material is vacuum dried at 140° C. for 12 hours.

(57) 2. The chain extender, antioxidant, nucleating agent, heat stabilizer are vacuum dried at 80° C. for 8 hours.

(58) 3. The above raw materials are mixed in proportion according to the parts by weight, placed in a high-speed mixer for 10 minutes, and then put into a twin-screw foaming extruder.

(59) Foaming gas: carbon dioxide, fed at a rate of 1.2 kg/hr.

(60) Extrusion temperature of extrusion machine: 295° C. in a first zone, 290° C. in a second zone, 285° C. in a third zone, 285° C. in a fourth zone, and 270° C. in a fifth zone.

(61) Screw speed: 45 rpm.

(62) Die temperature: 265° C.

Comparative Example 1

(63) A foamable PET resin of the comparative example 1 is made by the following raw materials and the total of each component is 100% by weight:

(64) 90.0 wt % of general PET, 7.0 wt % of chain extender, 0.5 wt % of antioxidant, 2.0 wt % of nucleating agent, and 0.5 wt % of heat stabilizer.

(65) The manufacturing method is as follows:

(66) 1. A general PET material is vacuum dried at 140° C. for 12 hours.

(67) 2. The chain extender, antioxidant, nucleating agent, heat stabilizer are vacuum dried at 80° C. for 8 hours.

(68) 3. The above raw materials are mixed in proportion according to the parts by weight, placed in a high-speed mixer for 10 minutes, and then put into a twin-screw foaming extruder.

(69) Foaming gas: carbon dioxide, fed at a rate of 1.2 kg/hr.

(70) Extrusion temperature of extrusion machine: 295° C. in a first zone, 290° C. in a second zone, 285° C. in a third zone, 285° C. in a fourth zone, and 270° C. in a fifth zone.

(71) Screw speed: 45 rpm.

(72) Die temperature: 265° C.

(73) Table 1 lists embodiments and comparative example of the recycled PET foam material of the present disclosure. Comparative analyses are carried out on the foaming materials prepared in embodiments 1-6 and comparative example 1:

(74) Compared with embodiment 4, in comparative example 1, the general PET material is used and a large amount of nucleating agent is added therein, such that the average size of cells can be effectively reduced, and a specific gravity after foaming is much better than that of embodiment 4.

(75) Compared with comparative example 1, in embodiment 6 the recycle PET material is used and a large amount of chain extenders is added therein, such that the melting strength of PET resin can be effectively increased, and a specific gravity after foaming is much better than that of comparative example 1.

(76) TABLE-US-00001 TABLE 1 weight composition and material properties of the materials of embodiments 1-6 and comparative example 1 Comparative Composition Embodiment example (wt %) 1 2 3 4 5 6 1 Recycle PET 96.5 91.5 90.0 96.5 91.5 90.0 General PET 95.0 Chain extender 2.0 7.0 7.0 2.0 7.0 7.0 2.0 Antioxidant 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Nucleating 0.5 0.5 2.0 0.5 0.5 2.0 2.0 agent Heat stabilizer 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Foaming gas Nitrogen Nitrogen Nitrogen Carbon Carbon Carbon Carbon dioxide dioxide dioxide dioxide Thickness(mm) 2.2 2.3 2.2 2.3 2.3 2.4 2.3 Specific 0.521 0.388 0.320 0.508 0.137 0.123 0.121 gravity (g/cm.sup.3) Average size of 223 125 72 232 134 62 67 cells (μm)

(77) According to Table 1, adding more nucleating agents can effectively reduce the average size of cells, and adding more chain extenders can effectively increase the melting strength of PET resin, so that the specific gravity of PET foaming products reduces.

(78) The foregoing description of the exemplary embodiments of the disclosure has been presented only for the purposes of illustration and description and is not intended to be exhaustive or to limit the disclosure to the precise forms disclosed. Many modifications and variations are possible in light of the above teaching.

(79) The embodiments were chosen and described in order to explain the principles of the disclosure and their practical application so as to enable others skilled in the art to utilize the disclosure and various embodiments and with various modifications as are suited to the particular use contemplated. Alternative embodiments will become apparent to those skilled in the art to which the present disclosure pertains without departing from its spirit and scope.